3.8 Article

Synthesis, crystal structure and Hirshfeld surface analysis of the orthorhombic polymorph of 4-bromo-N-(4-bromobenzylidene)aniline

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INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S2056989023001111

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crystal structure; N-benzylideneaniline; polymorphism; Hirshfeld surface; fluorescence; two-photon absorption

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The crystal structure of the compound C13H9Br2N has been determined. It exists in two polymorphs, with Form II crystallizing in the orthorhombic space group Pccn and Form I crystallizing in the monoclinic space group P21/c. The molecules are disordered about an inversion center and show stacking along the b-axis in the crystal. Form II exhibits fluorescence and optical limiting behavior.
The crystal structure of the title compound, C13H9Br2N [systematic name: (E)N,1-bis(4-bromophenyl)methanimine], is a second polymorph (Form II) crystallizing in the orthorhombic space group Pccn. The first polymorph (Form I) crystallizes in the monoclinic space group P21/c [Bernstein & Izak (1975). J. Cryst. Mol. Struct. 5, 257-266; Marin et al. (2013). J. Mol. Struct. 1049, 377-385]. The molecule is disordered about an inversion center situated in the middle of the C N bond, similar to the situation in the monoclinic polymorph: the C N bond length is 1.243 (7) A degrees. In the crystal, molecules stack along the b-axis direction and are linked by C-H center dot center dot center dot pi interactions. The interatomic contacts in the crystal for both polymorphs were studied by Hirshfeld surface analysis and have notable differences. The solid-state fluorescence spectrum of Form II shows an emission peak at ca 469 nm. The two-photon absorption coefficient measured from the open aperture Z-scan technique is 1.3 x 10(-1)1 m W-1, hence, Form II shows optical limiting behaviour.

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