期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 2, 页码 380-383出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc08034c
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资金
- [24590016]
- Grants-in-Aid for Scientific Research [24590016] Funding Source: KAKEN
An asymmetric synthesis of highly substituted indenes 3, bearing a quaternary stereogenic carbon center, has been developed via the central-axial-central chirality transfer from optically active propargyl alcohols 1. This transformation involves the addition/rearrangement of 1 and ynamides 2 to give tetra-substituted allenes 4 and further cyclization of 4.
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