期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 5, 页码 911-913出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07962k
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资金
- Swedish Research Council
- Crafoord Foundation
- Knut and Alice Wallenberg Foundation
- Royal Physiographic Society in Lund
Cyclometallation of 2-(1-naphthyl)-pyridine is described. While cyclopalladation results in a five-membered metallacycle, cycloauration displays a completely orthogonal regioselectivity, resulting in the six-membered ring analogue. Bromination of the gold metallacycle results in the new C-H functionalisation product 2-(8-bromonaphth-1-yl)-pyridine.
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