期刊
MATERIALS RESEARCH BULLETIN
卷 84, 期 -, 页码 218-224出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2016.08.014
关键词
Nanostructures; Chemical synthesis; Microstructure; Electron microscopy; Energy storage
资金
- National Natural Science Foundation of China [21203168, 11574273]
- Natural Science Foundation of Zhejiang Province [LY15B030003, LY16B030003]
A freestanding nitrogen-doped graphene functional interlayer placed between the sulfur cathode and the separator has been investigated to enhance the electrochemical performance for lithium-sulfur (Li-S) batteries. The interlayer with three-dimensional porous structure and abundant of N-doping active sites, not only can increase electron transport pathway and the storage capacity of liquid electrolyte, but also can physically and chemically adsorb the highly soluble lithium polysulfides to reduce the loss of active material. With a pure sulfur electrode (high sulfur content of 70 wt%), the as-assembled Li-S battery delivers a high initial discharge capacity up to 1481 mAh g(-1) at a rate of 0.1C, and maintains a reversible capacity of 956 mAh g(-1) after 50 cycles of charge/discharge. Comparing with conventional cells, we have highly improved the electrochemical performance for Li-S batteries. (C) 2016 Elsevier Ltd. All rights reserved.
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