4.6 Article

Microwave-assisted synthesis of porous nickel cobaltite with different morphologies in ionic liquid and their application in supercapacitors

期刊

MATERIALS CHEMISTRY AND PHYSICS
卷 176, 期 -, 页码 6-11

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2016.04.019

关键词

Nanostructures; Chemical synthesis; Heat treatment; Electron microscopy; Electrochemical properties

资金

  1. National Research Foundation of Korea (NRF) - Ministry of Education [2014R1A6A1031189]

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A facile and one-step strategy was used to synthesize one-dimensional (1D) and 2D mesoporous nickel cobaltite (NiCo2O4) rods and sheets, which are conducted in a mixture of ionic liquid and water under microwave irradiation. The as-prepared product electrode exhibited high specific capacitance (879 F g(-1) at 0.5 A g(-1)) and excellent cycling stability (only ca. 4.7% loss after 1500 cycles), suggesting its promising application as an efficient electrode material for supercapacitors. The high performance capacitance is mainly attributed to its binary electroactive surface area of Co and Ni species, and its fast electron and ion transport of the mesoporous structure. (C) 2016 Elsevier B.V. All rights reserved.

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