期刊
NANOSYSTEMS-PHYSICS CHEMISTRY MATHEMATICS
卷 14, 期 1, 页码 112-119出版社
ST PETERSBURG NATL RESEARCH UNIV INFORMATION TECHNOLOGIES, MECH & OPTICS
DOI: 10.17586/2220-8054-2023-14-1-112-119
关键词
cerium; potassium; polyphosphate; channel; hydrothermal
Hydrothermal treatment of nanoscale amorphous ceric phosphate gel in KOH aqueous solutions forms a new KCe2(PO4)3 phase. The structure of KCe2(PO4)3 is isostructural to (NH4)Ce2(PO4)3. The thermal decomposition of KCe2(PO4)3 at 800 degrees C results in a mixture of crystalline CePO4 and KPO3.
Hydrothermal treatment of nanoscale amorphous ceric phosphate gel in KOH aqueous solutions was found to result in a new KCe2(PO4)3 phase. The refinement of the KCe2(PO4)3 structure showed that it was isostructural to recently reported (NH4)Ce2(PO4)3. For the KCe2(PO4)3 phase, the unit cell parameters Z = 4. The thermal decomposition of KCe2(PO4)3 at 800 degrees C resulted in the mixture of crystalline CePO4 and KPO3.
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