Bicyclic alkanes in source rocks of the Triassic Yanchang Formation in the Ordos Basin and their inconsistency in oil-source correlation

The Triassic Yanchang Formation is the main source rocks for Mesozoic oil in Ordos Basin. The formation includes 10 oil-bearing beds (Ch 1 Ch 10), that each can be further divided into two to three intervals. Abundant C-12-O-14 and C-15-C-16 bicyclic alkanes have been detected in the formation in the Xifeng oilfield, Ordos Basin. The C-12-C-14 group is dominated by C-12 and C-13, and the C-15-C-16 group contains abundant C-15. The groups show three distribution patterns: A) the C-12-C-14 group is the major component in the non-source rocks of the Ch 7-1 and Ch 8-1 intervals; B) both groups are abundant and are common in source rocks of the Ch 7-3 interval; and C) the C-15-C-16 group is the major component in source rocks of the Ch 7-3 interval and also in sediments that contain type I or partial sapropel type II1 organic matter (OM) in the Ch 7-2 and Ch 8-1 intervals. Although thermal maturities of the source rocks in the Ch 7 section are similar, they show significant differences with respect to the drimane isomerisation index, which indicates that the drimane rearrangement is controlled by thermal evolution of the sediments, but may also be closely related to the depositional environment. This study determined that reducing environments are more conducive to preservation of drimane than oxic environments. The drimane isomerisation index and the value of the hopane parameter Tm/Ts are positively correlated. The parameter Tm/Ts varies over a wide range within the sequence, and the large variations may be a result of terrigenous OM input by turbidity currents and/or gravity flows, mixed with the autochthonous sediments. Abundant homodrimane in both source rocks may reflect reducing environments in deep lakes and major input of higher plant OM. Organic-rich shale and oil shale in the Ch 7-3 interval of the Yanchang Formation are the primary sources of oil in reservoirs in the Xifeng area. The crude oil is rich in bicyclic alkanes that are dominated by C-15-C-16 as source rocks with pattern C for bicyclic alkanes, which indicates an origin mainly from the Ch 7-3 interval. The main peaks in all of the crude oils are associated with 8 beta(H)-drimane and lower abundance of rearranged drimane. However, most of the source rocks have a main peak associated with 8 beta(H)-homodrimane or rearranged drimane. Weak microbial action, selective degradation and water washing may be the cause of the significant difference in bicyclic sesquiterpane composition between the crude oil and the source rocks. The result suggests that oil-source correlations based on the bicyclic sesquiterpanes are questionable. (C) 2016 Elsevier Ltd. All rights reserved.