期刊
MACROMOLECULES
卷 49, 期 14, 页码 5179-5189出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.6b00205
关键词
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资金
- NIST, U.S. Department of Commerce [70NANB12H239, 70NANB15H260]
- National Science Foundation [1247394]
- U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering [DE-FG02-09ER46626]
The self-assembly of an end-functionalized PEO106-PPO70-PEO106 triblock copolymer (BCP) with acrylic end groups (Pluronic F127 diacrylate or FDA) in a protic ionic liquid (deuterated ethylammonium nitrate, dEAN) is studied using small-angle neutron scattering, shear rheology, and dielectric spectroscopy. This functionalization constitutes less than 1 wt % of the copolymer and has no effect on micelle formation in dEAN. The sol gel transition and the supra molecular crystal structure of the concentrated FDA/dEAN solutions are also found to be unaffected by the acrylation of the end groups. Photo-cross-linking results in viscoelasticity enhancement of the FDA/dEAN solutions with FDA contents below the gel point. Cross-linking gels produces soft elastomers with exceptional elasticity and conductivity comparable to the un-cross-linked solutions. Tuning BCP microstructure via self-assembly in ionic liquids followed by chemical cross-linking is shown to be a promising route for the design of materials with specific mechanical properties and ionic conductivities.
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