期刊
MACROMOLECULAR RESEARCH
卷 24, 期 11, 页码 980-985出版社
SPRINGER
DOI: 10.1007/s13233-016-4143-0
关键词
diketopyrrolopyrrole; conjugated copolymer; side chain; miscibility; film morphology; polymer solar cell
资金
- National Research Foundation of Korea [NRF2012R1A2A1A01008797]
- Key Research Institute Program [NRF20100020209]
- National Research Foundation of Korea [2010-0020209, 2015R1A2A1A05001876] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
The new diketopyrrolopyrrole-based copolymer, referred to as PDPPBDTE, bearing linear alkyl ester groups, was synthesized with the objective of improving the miscibility between the donor polymer and [6,6]-phenyl C-71 butyric acid methyl ester (PC71BM). PDPPBDTA bearing ethylhexyl side-chains was also synthesized as a control polymer. The PDPPBDTE:PC71BM blend film showed a relatively small crystalline domain size compared to the PDPPBDTA:PC71BM blend film. A polymer solar cell fabricated with PDPPBDTE and PC71BM exhibited twofold higher power conversion efficiency than that employing PDPPBDTA.
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