期刊
MACROMOLECULAR REACTION ENGINEERING
卷 10, 期 4, 页码 389-405出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/mren.201500036
关键词
acrylic acid; method of double moments; Monte Carlo; polymerization; polymer properties
资金
- European Community
A complete mathematical model of the free-radical copolymerization of acrylic acid in an aqueous solution, taking place in a pilot-scale tubular reactor equipped with static mixers, is presented. The developed kinetic/reactor model is numerically integrated in terms of a coupled deterministic-stochastic numerical approach that combines the advantages of speed, efficiency, and increased predictive capabilities. A series of experimental measurements on the monomer conversion and the molecular weight characteristics of the produced copolymer, under a wide range of process conditions, are used for the identification of the kinetic model parameters while a thorough analysis of the compositional characteristics of the produced copolymers is also carried out in terms of a series of bivariate distributed properties.
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