期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 37, 期 18, 页码 1527-1532出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201600281
关键词
cellular polymers; interfacial tension; poly-HIPE; reactive blending; solid emulsions
资金
- European Research Council (ERC) under the European Union [307280-POMCAPS]
Macrocellular silicone polymers are obtained after solidification of the continuous phase of a poly(dimethylsiloxane) emulsion, which contains poly(ethylene glycol) drops of sub-millimetric dimensions. Coalescence of the liquid template emulsion is prohibited by a reactive blending approach. The relationship is investigated in detail between the interfacial properties and the emulsion stability, and micro- and millifluidic techniques are used to generate macro cellular polymers with controlled structural properties over a wider range of cell sizes (0.2-2 mm) and volume fractions of the continuous phase (0.1%-40%). This approach could easily be transferred to a wide range of polymeric systems.
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