期刊
MACROMOLECULAR CHEMISTRY AND PHYSICS
卷 217, 期 10, 页码 1191-1196出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.201600011
关键词
disulfide exchange; polyurethanes; self-healing; shape memory
资金
- Program of Introducing Talents of Discipline to Universities [111-2-04]
Polymeric materials with intrinsic self-healing ability that can restore from mechanical injury autonomously have attracted great research efforts recently. Disulfide bonds, which become dynamic upon exposure to heat, UV light, or redox conditions, can be used to introduce healable properties to polymer network. Shape memory effect is a kind of auxiliary recovery force that can accelerate healing process. In this work, a polyurethane material combines disulfide link and shape memory effect is synthesized. Autonomous healing of a crack takes place upon heating above 80 degrees C and leads to almost fully recovery of mechanical properties. This healing is achieved by activating shape memory effect and disulfide exchange reaction simultaneously.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据