4.6 Article

Metal-Semiconductor-Metal Photodetectors Based on ?-MgGaO Thin Films

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ACS APPLIED ELECTRONIC MATERIALS
卷 -, 期 -, 页码 -

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AMER CHEMICAL SOC
DOI: 10.1021/acsaelm.3c00035

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ultrawide-bandgap semiconductors; magnesium gallium oxide; single crystal; molecular beam epitaxy; photodetector

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In this study, deep-ultraviolet fi-MgGaO metal-semiconductor-metal photodetectors were fabricated and their responsivity was investigated. The results showed that these detectors have potential for deep-ultraviolet photodetection and other photonic device applications.
Ultrawide-bandgap (UWBG) deep-ultraviolet photodetectors have received great attention due to their versatile applications in the fields of scientific research, civilian infrastructure, military defense, etc. In this perspective, we fabricated deep-ultraviolet fi-MgGaO metal-semiconductor-metal photodetectors with inter-digital Pt/Au metal contacts. fi-Phase MgGaO ternary alloy thin films of different Mg atomic percentages were grown using oxygen plasma-assisted molecular beam epitaxy. Ultrawide bandgaps of 5.03, 5.09, 5.15, and 5.22 eV were achieved for thin films with and without Mg2+ incorporation, and light transmittances of all samples were around 90% in the visible region. Raman spectra indicate that Mg2+ atoms have replaced the position of Ga3+ ions in both octahedral and tetrahedral chains. The responsivity of the detectors was investigated. The irradiation wavelength-, temperature-, and power-dependent I-V curves, photocurrent spectra, and dynamics of the photocurrents were measured. This work suggests that UWBG fi-MgGaO semiconductors have a potential for deep-ultraviolet photodetectors and other photonic device applications.

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