4.7 Review

Hot electron chemistry in catalytic reactions

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Relaxation Dynamics of Enhanced Hot-Electron Flow on Perovskite-Coupled Plasmonic Silver Schottky Nanodiodes

Yujin Park et al.

Summary: This study demonstrates that depositing a MAPbI(3) thin film on plasmonic Ag nanodiode enhances hot-electron flow and prolongs relaxation time, potentially improving internal photoemission. Comparison with a plasmonic Au structure shows that the former combination exhibits enhanced hot-electron transfer and increased hot-electron flow. The suggested structure in this work could provide a useful alternative model for designing sensitive hot-electron-based photovoltaics.

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Controlling hot electron flux and catalytic selectivity with nanoscale metal-oxide interfaces

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Summary: The interaction between metal and oxides is a crucial factor influencing the selectivity of a desirable reaction. Designing a well-formed metal-oxide interface in a heterogeneous catalyst is important for understanding selectivity and surface electronic excitation at the interface. The study demonstrates the real-time detection of hot electron flow and impact of metal-oxide interface on catalytic selectivity in a nanoscale catalytic Schottky diode.

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Summary: Research indicates that the size of metallic nanostructures is crucial for the injection of plasmonic hot holes, with smaller Au nanoprisms showing higher quantum efficiencies and significant enhancement of photoelectrocatalytic reactions.

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Surface chemistry of hot electron and metal-oxide interfaces

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Summary: Fundamental mechanisms for energy conversion and dissipation on surfaces and at interfaces have been significant issues in surface science. Charge transfer through metal oxide interfaces has a significant impact on catalytic performance. Various detection schemes for hot electrons have been developed to understand their influence on surface reactions.

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The nature of hot electrons generated by exothermic catalytic reactions

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Hot-Electron-Mediated Surface Chemistry: Toward Electronic Control of Catalytic Activity

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Chemical-Reaction-Induced Hot Electron Flows on Platinum Colloid Nanoparticles under Hydrogen Oxidation: Impact of Nanoparticle Size

Hyosun Lee et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

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Role of Hot Electrons and Metal-Oxide Interfaces in Surface Chemistry and Catalytic Reactions

Jeong Young Park et al.

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Plasmon-Induced Hot Carriers in Metallic Nanoparticles

Alejandro Manjavacas et al.

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Direct Control of Electron Transfer to the Surface-CO Bond on a Pt/TiO2 Catalytic Diode

Prashant Deshlahra et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

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Hydrogen Oxidation-Driven Hot Electron Flow Detected by Catalytic Nanodiodes

Antoine Hervier et al.

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Non-adiabaticity in surface chemical reactions

Eckart Hasselbrink

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Molecular Factors of Catalytic Selectivity

Gabor A. Somorjai et al.

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Interfacial and chemical properties of Pt/TiO2, Pd/TiO2, and Pt/GaN catalytic nanodiodes influencing hot electron flow

Jeong Young Park et al.

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Electronic excitation and dynamic promotion of a surface reaction

DN Denzler et al.

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Chemically induced electronic excitations at metal surfaces

B Gergen et al.

SCIENCE (2001)

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Vibrational promotion of electron transfer

YH Huang et al.

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