☆ 4.5 Review

Research Progress on Chiral Supramolecular Sensors for Enantiomer Detection

CHEMOSENSORS (2023)

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Article Engineering, Multidisciplinary

A high-performance optical trace oxygen sensor based on the room-temperature phosphorescence from palladium (II) octaethylporphyrin

Yongda Wang et al.

Summary: A high-performance oxygen sensor is developed using room temperature phosphorescence. The sensor probe is made of Sol-gel matrix doped with Palladium (II) octaethylporphyrin (PdOEP) and has a sensitivity of 29.23 kPa(-1). The sensor incorporates a dual-channel structure to eliminate excitation source fluctuations and uses a photomultiplier tube equipped photon counter to enhance the signal-to-noise ratio. The detection limit of the system is 0.1 Pa with an indication error of +/- 1.5%.

MEASUREMENT (2023)

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Article Chemistry, Analytical

A renewable electrochemical sensor based on a self-assembled framework of chiral molecules for efficient identification of tryptophan isomers

Tao Gong et al.

Summary: In this study, a chiral sensor was designed and constructed using molecular self-assembly method, which could effectively recognize tryptophan isomers. The sensor exhibited good linearity and renewable ability, and could be used for qualitative and quantitative determination of Trp isomers. Its feasibility in actual sample detection was verified through successful application in rat serum.

ANALYTICA CHIMICA ACTA (2022)

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Review Chemistry, Multidisciplinary

Electrochemiluminescence with semiconductor (nano)materials

Yiran Zhao et al.

Summary: This paper reviews the combination of electrochemiluminescence (ECL) with semiconductor (SC) materials, which has provided new applications and opportunities in (bio)sensing and imaging. The recent advances in generating ECL in original configurations are highlighted, from utilizing bulk SC as electrode materials to using SC nanocrystals or quantum dots as bright ECL nano-emitters. The challenges and future prospects in designing new detection strategies in (bio)analytical chemistry, light-addressable systems, imaging, and infrared devices are also discussed.

CHEMICAL SCIENCE (2022)

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Review Environmental Sciences

Enantioselective behavior of environmental chiral pollutants: A comprehensive review

Marina Arenas et al.

Summary: The enantiomeric profiling of chiral environmental contaminants is a significant and complex issue, influenced by factors such as the compound itself, environmental conditions, and microbial activities. Investigating the environmental fate of enantiomers requires thorough research and discussion.

CRITICAL REVIEWS IN ENVIRONMENTAL SCIENCE AND TECHNOLOGY (2022)

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Article Chemistry, Analytical

A near-infrared fluorescence capillary imprinted sensor for chiral recognition and sensitive detection of L-histidine

Sisi Tang et al.

Summary: This study developed a near-infrared fluorescence capillary imprinted sensor with high selectivity and sensitivity for chiral recognition of L-histidine. The sensor exhibited superior stability, reproducibility, and reusability, displaying high selectivity towards L-histidine in micro-volume samples.

ANALYTICA CHIMICA ACTA (2022)

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Review Biochemical Research Methods

Electrochemical sensing of macromolecules based on molecularly imprinted polymers: challenges, successful strategies, and opportunities

Elisabetta Mazzotta et al.

Summary: In recent years, there has been a significant increase in research on the use of MIPs for proteins, with a threefold increase in the number of works. The technology has been successfully applied in the assembly of electrochemical sensors, showing great potential in the field of sensor design.

ANALYTICAL AND BIOANALYTICAL CHEMISTRY (2022)

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Article Chemistry, Analytical

Polarization-Multiplexed Incoherent Broadband Surface Plasmon Resonance: A New Analytical Strategy for Plasmonic Sensing

Jayeta Banerjee et al.

Summary: This article presents the development of a new incoherent broadband (IBB)-Surface Plasmon Resonance (SPR) probe and explores the link between plasmonic resonance and polarization modulation. The study paves the way for the development of a new analytical technique to track real-time chemical and biological molecular interactions occurring at interfaces.

ANALYTICAL CHEMISTRY (2022)

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Review Chemistry, Multidisciplinary

Circular Dichroism Based Chirality Sensing with Supramolecular Host-Guest Chemistry

Mao Quan et al.

Summary: Optical methods, particularly Circular dichroism-based chiroptical sensing, show great potential in high-throughput screening for chirality analysis in drug discovery. This emerging field explores molecular recognition, chirality transfer, classification of chirality sensors, and applications in asymmetric reactions and reaction kinetics monitoring. Challenges and research directions in this area are also emphasized.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Article Chemistry, Analytical

Enantioselective recognition of esomeprazole with a molecularly imprinted sol-gel-based electrochemical sensor

Leyla Karadurmus et al.

Summary: A simple, selective, and accurate electrochemical chiral sensor based on molecularly imprinted polymer (MIP) was developed for sensitive and selective detection of esomeprazole. The sensor's response to the target molecule was observed using differential pulse voltammetry and cyclic voltammetry with a redox probe. The structure of the sensor was characterized, and complementary electrochemical characterization was performed using electrochemical impedance spectroscopy. The developed sensor showed high specificity towards esomeprazole and successfully detected it in tablets and human serum samples.

MICROCHIMICA ACTA (2022)

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Article Chemistry, Applied

Simultaneous electrochemical recognition of tryptophan and penicillamine enantiomers based on MOF-modified ?-CD

Ying Hou et al.

Summary: Chiral recognition plays a significant role in chemical asymmetric synthesis and biological pharmaceutical research. In this study, an electrochemical chiral sensor was developed with two types of chiral sites, which allowed the simultaneous recognition of tryptophan and penicillamine enantiomers. The sensor exhibited a wide linear range, low detection limits, high repeatability, and stability.

CARBOHYDRATE POLYMERS (2022)

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Article Chemistry, Analytical

Highly enantioselective electrochemical sensing based on helicoid Au nanoparticles with intrinsic chirality

Fenghua Li et al.

Summary: Chiral discrimination is crucial in various scientific fields, and the design of electrochemical chiral sensors with high discrimination ability and service life is highly desired. In this study, helicoid Au nanoparticles with intrinsic chirality were synthesized and utilized to construct an electrochemical chiral sensor for the first time. The sensor showed excellent performance in detecting tyrosine enantiomers, enabling accurate determination of their purity and composition. Additionally, the sensor was successfully applied in the determination of L-Tyr contents in various samples, indicating its potential for practical applications in chiral recognition.

SENSORS AND ACTUATORS B-CHEMICAL (2022)

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Article Chemistry, Analytical

Ultrasensitive sensor for L-penicillamine with chirality-induced amplification of benzo[3]uril electrochemiluminescence via supramolecular interactions

Xiao-Fan Wu et al.

Summary: Utilizing a novel concept of chiral amplification induced by host-guest interactions, a new macrocyclic compound BU[3] was formed in a chiral microenvironment, and a highly sensitive chiral sensor based on its electrochemiluminescence properties was constructed to recognize the enantiomer of penicillamine.

SENSORS AND ACTUATORS B-CHEMICAL (2022)

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Article Chemistry, Analytical

Electrochemical chiral sensor based on molecularly imprinted polymer for determination of (1S,2S)-pseudoephedrine in dosage forms and biological sample

Leyla Karadurmus et al.

Summary: In this study, a simple, eco-friendly, highly sensitive, and selective electrochemical chiral sensor based on molecularly imprinted polymer (MIP) was fabricated for the detection of Pseudoephedrine enantiomers. The MIP modified sensor demonstrated a linear response to (1S,2S)-PSDO and high recovery rates in pharmaceutical dosage forms and human serum samples.

MICROCHEMICAL JOURNAL (2022)

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Article Chemistry, Applied

An electrochemical chiral sensor for amino acids based on cyclodextrin modified thiophene-based copolymer

Haotian Gao et al.

Summary: In this study, two series of thiophene-based copolymers with cyclodextrins (CDs) grafted on the side chain were synthesized to achieve efficient enantio-recognition of amino acids. The copolymers showed a reverse interaction preference for D- and L-isomers due to the different interaction modes of native and substituted CDs. The content of the CD block in the copolymer was found to affect the sensitivity and chiral selectivity of the electrochemical sensor.

CARBOHYDRATE POLYMERS (2022)

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Article Chemistry, Multidisciplinary

A chiral binaphthyl-based coordination polymer as an enantioselective fluorescence sensor

Shannon Thoonen et al.

Summary: A fluorescent, chiral coordination polymer (CP) with a unique topology has been synthesized using a dipyridyl ligand derived from 1,1'-bi-2-naphthol (BINOL). High enantioselectivity ratios up to 2.61 were achieved in fluorescence sensing studies with chiral analytes.

CHEMICAL COMMUNICATIONS (2022)

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Article Chemistry, Multidisciplinary

Biomimetic Recognition and Optical Sensing of Carboxylic Acids in Water by Using a Buried Salt Bridge and the Hydrophobic Effect

Xuan Huang et al.

Summary: By designing and synthesizing endo-functionalized macrocyclic hosts with buried salt bridges, selective recognition of specific compounds can be achieved in water, which can be used for optical chirality sensing and fluorescent sensing. This demonstrates the effective use of buried salt bridges in molecular recognition in water.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Review Chemistry, Analytical

Recognition and Sensing of Chiral Organic Molecules by Chiral Porphyrinoids: A Review

Gabriele Travagliante et al.

Summary: Porphyrinoids are attractive for their electronic, optical, and coordination properties, which allow them to behave as chiroptical hosts for chiral recognition. Research has shown that through various spectroscopic techniques and chiral molecules, chiral discrimination of a multitude of chiral organic guests can be achieved.

CHEMOSENSORS (2021)

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Review Chemistry, Multidisciplinary

Supramolecular Chirality in Metal-Organic Complexes

Jinqiao Dong et al.

Summary: Chirality is a pervasive structural feature in nature and essential for the organization and function of biological systems. Researchers have explored the translation of chirality towards synthetic systems through constructing homochiral metal-organic complexes (MOCs) to investigate key asymmetric processes at the molecular level.

ACCOUNTS OF CHEMICAL RESEARCH (2021)

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Article Chemistry, Multidisciplinary

Pillar[5]arene-functionalized nanochannel platform for detecting chiral drugs

Sheng Yu et al.

Summary: The research demonstrated the enantioselective recognition of the chiral drug propranolol through an electrochemical method in a nanochannel platform, showcasing its potential applications in the recognition of chiral molecules.

CHINESE CHEMICAL LETTERS (2021)

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Article Chemistry, Inorganic & Nuclear

Novel aspartic chiral optical sensor based on 13-cyclodextrin-functionalized CdTe nanoparticles

Bui The Huy et al.

Summary: A novel aspartic chiral assay based on CdTe nanoparticles coated with 13-cyclodextrin was proposed, showing high selectivity and good detection performance.

INORGANIC CHEMISTRY COMMUNICATIONS (2021)

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Article Chemistry, Analytical

Electrochemical enantioselective sensor for effective recognition of tryptophan isomers based on chiral polyaniline twisted nanoribbon

Shaoying He et al.

Summary: Chiral nanomaterials are still a challenge in achieving effective enantioselective recognition in the field of chemistry and biology. Through the synthesis of left- and right-handed polyaniline, this study successfully constructed electrochemical chiral sensors for discrimination of tryptophan isomers, showing high enantioselectivity.

ANALYTICA CHIMICA ACTA (2021)

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Article Chemistry, Physical

Achiral double-decker phthalocyanine assemble into helical nanofibers for electrochemically chiral recognition of tryptophan

Yuying Jiang et al.

Summary: Efficient sensing of chiral biomolecules is crucial for human health due to the unique role of homochirality. A new approach has been developed for electrochemically chiral recognition of tryptophan based on the co-assembly of achiral double-decker phthalocyanines with poly-L-lysine at the air/water interface, allowing for discrimination of enantiomers even quantitatively. The nanostructures and properties of the co-assemblies have been thoroughly characterized, demonstrating potential for developing efficient and low-cost chiral sensors.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2021)

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Review Polymer Science

Recent Advances of Porous Materials Based on Cyclodextrin

Jun-Feng Feng et al.

Summary: Porous materials have been increasingly used in various fields, with cyclodextrins being suitable building units due to their nanoporous structure, ease of modification, and biocompatibility. This review focuses on the recent progress in the fabrication and applications of CD-based porous materials, including CD-MOFs, CD-COFs, and hybrid porous materials.

MACROMOLECULAR RAPID COMMUNICATIONS (2021)

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Review Chemistry, Analytical

An overview of analytical methods for enantiomeric determination of chiral pollutants in environmental samples and biota

Marina Arenas et al.

Summary: Chirality is an important topic in the pharmaceutical, food, and agrochemical fields due to the potential differences in properties of enantiomers despite their similar physical-chemical properties. Determining enantiomers poses an analytical challenge due to their identical properties except for light rotation. This review provides an overview of recent analytical methods for determining chiral pollutants and discusses future trends and challenges in this area.

TRAC-TRENDS IN ANALYTICAL CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Supramolecular Chirality Transfer toward Chiral Aggregation: Asymmetric Hierarchical Self-Assembly

Shuai Huang et al.

Summary: This paper summarizes recent studies on chirality transfer induced self-assembly based on various supramolecular interactions, and discusses the impact of different environments and system states on the expression of chirality, as well as the driving forces that facilitate chiral bias and the role of supramolecular interactions.

ADVANCED SCIENCE (2021)

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Article Chemistry, Analytical

Enantiomeric fraction determination of chiral drugs in environmental samples using chiral liquid chromatography and mass spectrometry

Yandi Fu et al.

Summary: This review discusses the determination and analysis of enantiomeric fractions of chiral drugs in environmental matrices using chiral liquid chromatography coupled with mass spectrometry. It provides a comprehensive overview and comparison of various techniques, addresses advancements and limitations, and explores the impact of the mobile phase composition on enantioseparation and MS detection. Various applications of chiral LC and MS for enantiomeric fraction determination of chiral drugs in environmental samples are also discussed in depth.

TRENDS IN ENVIRONMENTAL ANALYTICAL CHEMISTRY (2021)

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Review Chemistry, Analytical

Fluorogenic Aptasensors with Small Molecules

Eun-Song Lee et al.

Summary: This review discusses recent advances in fluorogenic aptasensors and their applications in in vitro diagnosis and cellular imaging. These sensors, modulated by small molecules, show rapid fluorescence turn-on signals with high target specificity and low background noise, making them valuable tools in biosensing and bioimaging.

CHEMOSENSORS (2021)

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Article Chemistry, Multidisciplinary

Synthetic Semiconductor Photoelectrochemistry

Yohei Okada

Summary: In the field of synthetic organic chemistry, photochemical and electrochemical approaches are often considered as competing technologies. However, recently, the fusion of these approaches into photoelectrochemical methods has gained attention. By creatively combining solar and electrical energy, semiconductor photocatalysts are being reexamined for their applications in synthetic organic chemistry.

CHEMICAL RECORD (2021)

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Article Chemistry, Multidisciplinary

Selection of Planar Chiral Conformations between Pillar[5,6]arenes Induced by Amino Acid Derivatives in Aqueous Media

Yuan Chen et al.

Summary: This study identified the alpha-side chain and ethyl ester moieties of l-alpha-amino acid ethyl ester hydrochlorides by observing the selection of planar chiral conformations between water-soluble pillar[5]arene WP5 and pillar[6]arene WP6. This provides a rare example of detecting the chiral region around the alpha-carbon of a chiral alpha-amino acid molecule.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

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Review Chemistry, Inorganic & Nuclear

Fluorescent sensors: A bright future for cages

Anna Brzechwa-Chodzynska et al.

Summary: This review gives a general overview of the development of fluorescent chemosensors based on closed three-dimensional architectures, highlighting examples from research groups that have made significant contributions to this field. It discusses the basic principles and challenges in designing cage-like fluorescence chemosensors for various guest molecules, with particular emphasis on the use of molecular and supramolecular fluorescent architectures for detecting explosives/hazardous substances, aromatics, and biologically active compounds.

COORDINATION CHEMISTRY REVIEWS (2021)

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Review Polymer Science

Recent Advances of Molecularly Imprinted Polymers Based on Cyclodextrin

Xiaoyue Zhao et al.

Summary: This review summarizes recent advances in the application of cyclodextrin-based molecular imprinting polymers (MIPs) in sample preparation, detection, sensing, and drug delivery over the past five years. It also discusses the specific roles of cyclodextrins in MIPs and elaborates on the challenges and future prospects in the application of cyclodextrins in MIPs.

MACROMOLECULAR RAPID COMMUNICATIONS (2021)

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Article Chemistry, Analytical

An electrochemical chiral sensor based on the synergy of chiral ionic liquid and 3D-NGMWCNT for tryptophan enantioselective recognition

Nijuan Liu et al.

Summary: A facile chiral composite (3D-NGMWCNT@(S,S)-CIL) with excellent electrochemical performance was prepared by integrating 3D-NGMWCNT and (S,S)-CIL. The constructed sensor showed high sensitivity and stability for enantioselective recognition of Trp enantiomers. This novel sensor provides an efficient and convenient strategy for chiral enantioselective recognition.

MICROCHIMICA ACTA (2021)

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Review Chemistry, Analytical

Advances in Chirality Sensing with Macrocyclic Molecules

Xiaotong Liang et al.

Summary: The construction of chemical sensors that can distinguish molecular chirality has attracted increasing attention in recent years. The supramolecular chirality sensing strategy has shown promising potential due to advantages of high throughput, sensitivity, and fast chirality detection. This review focuses on chirality sensors based on macrocyclic compounds, summarizing recent advances and the unique advantages they offer compared to traditional chiral sensors.

CHEMOSENSORS (2021)

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Article Chemistry, Organic

Electrochemiluminescent Chiral Discrimination with a Pillar[5]arene Molecular Universal Joint-Coordinated Ruthenium Complex

Chunhong Liu et al.

Summary: A bicyclic pillar[5]arene derivative fused with a bipyridine side ring, named a molecular universal joint (MUJ), was synthesized and the pair of enantiomers was resolved using high-performance liquid chromatography. The electrochemiluminescent detection based on the ruthenium complex of enantiopure MUJ demonstrated excellent chiral discrimination towards certain amino acids.

ORGANIC LETTERS (2021)

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Article Spectroscopy

Fluorescent DNA-templated silver nanoclusters for highly sensitive detection of D-penicillamine

Lingyuan Liu et al.

Summary: Fluorescent DNA-templated silver nanoclusters were synthesized and used as a novel probe for detecting D-penicillamine for the first time, showing high sensitivity and fast preparation process.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2021)

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Article Chemistry, Analytical

Engineering Homochiral MOFs in TiO2 Nanotubes as Enantioselective Photoelectrochemical Electrode for Chiral Recognition

Shanshan Zhou et al.

Summary: Enantioselective sensing is achieved through the integration of TiO2 nanotubes with metal-organic frameworks to form a chiral photoelectrochemical sensor, demonstrating excellent discrimination ability for the chiral recognition of enantiomers. This platform provides a stable, simplified, and low-cost sensing device for enantiomer recognition.

ANALYTICAL CHEMISTRY (2021)

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Article Chemistry, Analytical

Electrochemical Polymerization Induced Chirality Fixation of Crystalline Pillararene-Based Polymer and Its Application in Interfacial Chiral Sensing

Jie Yang et al.

Summary: A new strategy has been developed for direct chirality fixation of macrocyclic hosts pillar[5]arene using electrochemical polymerization. The resulting chiral nanofiber-like crystalline pillar[5]arene-based polymers show significant circular dichroism signals and have been used as a photoelectrochemical chiral sensor for identifying and determining L- and D-ascorbic acid. This work provides a promotional strategy for building a PEC chiral recognition platform based on pillararenes, demonstrating a broad chiral detection range for L-AA.

ANALYTICAL CHEMISTRY (2021)

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Review Biochemical Research Methods

Supramolecular Click Chemistry for Targeting in the Body

Christopher J. Addonizio et al.

Summary: The fields of precision imaging and drug delivery have introduced various tools to enhance target specificity and efficacy in diagnosing and treating diseases. Biological molecules and molecular recognition motifs play key roles in ensuring active targeting and specificity, while bioorthogonal covalent conjugations and supramolecular motifs offer possibilities for in situ complexation under physiological conditions.

BIOCONJUGATE CHEMISTRY (2021)

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Article Chemistry, Analytical

An ultrasensitive photoelectrochemical sensor with layer-by-layer assembly of chiral multifarene[3,2,1] and g-C3N4 quantum dots for enantiorecognition towards thyroxine

Yong-Yi Zhao et al.

Summary: A sensitive photoelectrochemical sensor was developed to detect thyroxine enantiomers using graphitic carbon nitride quantum dots and chiral multifarene[3,2,1]. The sensor showed low detection limits, good stability, and potential for quantitative determination of L/D-T4 in various samples.

SENSORS AND ACTUATORS B-CHEMICAL (2021)

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Review Chemistry, Analytical

A disposable dual-signal enantioselective electrochemical sensor based on stereogenic porous chiral carbon nanotubes hydrogel

Yang Yang et al.

Summary: A disposable dual-signal enantioselective platform was fabricated based on stereoscopic porous chiral carbon nanotubes hydrogel modified screen printed electrode for discriminating enantiomers efficiently and practically.

TALANTA (2021)

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Article Chemistry, Analytical

Electrochemiluminescent chiral discrimination with chiral Ag2S quantum dots/few-layer carbon nitride nanosheets

Qianqian Zhao et al.

Summary: Chiral Ag2S quantum dots were synthesized using N-acetyl-L-cysteine as the chiral ligand and loaded onto nanosheets of few-layer carbon nitride, resulting in enhanced electrochemiluminescence while maintaining chirality. The developed ECL chiral sensor can discriminate between enantiomers of tyrosine with high stability and reproducibility, and is only effective for chiral aromatic amino acids according to the study.

ANALYST (2021)

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Review Chemistry, Multidisciplinary

Recent advances in chiral discrimination on host-guest functionalized interfaces

Weiwei Xu et al.

Summary: Chiral discrimination is an important process in supramolecular chemistry, playing a key role in biological systems and biochemical sensors. Currently, enantioselective identification of chiral molecules in artificial systems remains a challenging topic.

CHEMICAL COMMUNICATIONS (2021)

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Review Chemistry, Multidisciplinary

Electrogenerated chemiluminescence detection of single entities

Wei Zhao et al.

Summary: Electrogenerated chemiluminescence (ECL) is a process in which light is produced by excited luminophores generated during redox reactions induced by electrochemistry. Analyzing single entities such as molecules, micro/nanoparticles, and cells using ECL can provide insights into new truths of nature that may be hidden in complex systems or averaged out in ensemble assays.

CHEMICAL SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Adaptive chirality of achiral tetraphenylethene-based tetracationic cyclophanes with dual responses of fluorescence and circular dichroism in water

Haiyang Zhang et al.

Summary: Two tetraphenylethene-based tetracationic cyclophanes 1 and 2 were synthesized via a one-step S(N)2 reaction without using any template. These water-soluble cyclophanes exhibited adaptive chirality with dual responses of turn-on fluorescence and induced circular dichroism when combined with nucleotides and DNA in water.

CHEMICAL COMMUNICATIONS (2021)

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Article Chemistry, Analytical

Fabrication of a turn-on-type enantioselective fluorescence sensor via a modified achiral MOF: applications for synchronous detection of phenylalaninol enantiomers

Jiannan Xiao et al.

Summary: Homochiral metal-organic frameworks (HMOFs) have been studied extensively for their unique chiral properties and applications in chiral recognition. The pair of homochiral UiO-66 analogues, S-1 and R-1, show high enantioselectivity in fluorescence enhancement towards l/d-phenylalaninol (l/d-PA), demonstrating remarkable differences in fluorescence response and excellent enantioselective behavior. Measurements and simulations were used to explain the observed high enantioselectivity for l/d-PA, highlighting the potential of these HMOFs as enantioselective sensors.

ANALYST (2021)

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Article Chemistry, Physical

Induced VCD and conformational chirality in host-guest complexes of a chiral ammonium salt with crown ethers

Luisa Weirich et al.

Summary: The study investigates the effect of host-guest complex formation on the conformational preferences of macrocycles by using hydrogen bonded complexes of chiral ammonium salt and achiral crown ethers as model systems. The results demonstrate that a small chiral guest molecule can affect the conformational preferences of a macrocyclic host, with contributions from induced VCD and conformational chirality. VCD spectroscopy is proven to be suitable for characterizing analogous supramolecular host-guest complexes.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2021)

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Article Chemistry, Analytical

An Electrochemiluminesence Chiral Sensor for Propranolol Enantiomers Based on Functionalized Graphite-like Carbon Nitride Nanosheets

Shu Zhu et al.

ELECTROANALYSIS (2020)

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Article Chemistry, Organic

Competitive Selection of Conformation Chirality of Water-Soluble Pillar[5]arene Induced by Amino Acid Derivatives

Yuan Chen et al.

ORGANIC LETTERS (2020)

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Review Chemistry, Analytical

Detection, identification and determination of chiral pharmaceutical residues in wastewater: Problems and challenges

Aysegul Dogan et al.

TRAC-TRENDS IN ANALYTICAL CHEMISTRY (2020)

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Article Chemistry, Multidisciplinary

Pillararene Host-Guest Complexation Induced Chirality Amplification: A New Way to Detect Cryptochiral Compounds

Zhu Huangtianzhi et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Biochemistry & Molecular Biology

Synthesizing Chiral Drug Intermediates by Biocatalysis

Wei Jiang et al.

APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY (2020)

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Article Chemistry, Analytical

Gold nanodendrite-based differential potential ratiometric sensing strategy for enantioselective recognition of DOPA

Huiting Lian et al.

TALANTA (2020)

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Article Chemistry, Analytical

Ionic Current Rectification Triggered Photoelectrochemical Chiral Sensing Platform for Recognition of Amino Acid Enantiomers on Self-Standing Nanochannel Arrays

Jiayi Liu et al.

ANALYTICAL CHEMISTRY (2020)

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Article Environmental Sciences

Enantiospecific behaviour of chiral drugs in soil

Sophie Bertin et al.

ENVIRONMENTAL POLLUTION (2020)

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Article Biophysics

Enantioselective sensing of (S)-Thalidomide in blood plasma with a chiral naphthalene diimide derivative

Agata Kowalczyk et al.

BIOSENSORS & BIOELECTRONICS (2020)

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Article Chemistry, Multidisciplinary

Sequential Chiral Induction and Regulator-Assisted Chiral Memory of Pillar[5]arenes

Shixin Fa et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Review Clinical Neurology

Hormonal responses in gambling versus alcohol abuse: A review of human studies

Yansong Li et al.

PROGRESS IN NEURO-PSYCHOPHARMACOLOGY & BIOLOGICAL PSYCHIATRY (2020)

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Article Chemistry, Analytical

In -situ dynamic reaction of Ag NPs: Strategy for the construction of a sensitive electrochemical chiral sensor

Haifeng Zhou et al.

SENSORS AND ACTUATORS B-CHEMICAL (2020)

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Article Chemistry, Analytical

Immobilization of 6-O-α-maltosyl-β-cyclodextrin on the surface of black phosphorus nanosheets for selective chiral recognition of tyrosine enantiomers

Jiao Zou et al.

MICROCHIMICA ACTA (2020)

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Article Chemistry, Analytical

Chiral molecular imprinted sensor for highly selective determination of D-carnitine in enantiomers via dsDNA-assisted conformation immobilization

Lianming Zhang et al.

ANALYTICA CHIMICA ACTA (2020)

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Review Chemistry, Multidisciplinary

Self-assembly of chiral supra-amphiphiles

Guanghui Ouyang et al.

MATERIALS CHEMISTRY FRONTIERS (2020)

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Article Chemistry, Multidisciplinary

Chirality sensing of terpenes, steroids, amino acids, peptides and drugs with acyclic cucurbit[n]urils and molecular tweezers

Amrutha Prabodh et al.

CHEMICAL COMMUNICATIONS (2020)

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Article Chemistry, Multidisciplinary

Enantioselective Recognition of Neutral Molecules in Water by a Pair of Chiral Biomimetic Macrocyclic Receptors

Hongxin Chai et al.

CCS CHEMISTRY (2020)

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Review Chemistry, Multidisciplinary

Molecularly Imprinted Polymers

Joseph J. BelBruno

CHEMICAL REVIEWS (2019)

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Article Biochemistry & Molecular Biology

Graphene-ferrocene functionalized cyclodextrin composite with high electrochemical recognition capability for phenylalanine enantiomers

Xiaohui Niu et al.

BIOELECTROCHEMISTRY (2019)

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Review Pharmacology & Pharmacy

Advances of nanosystems containing cyclodextrins and their applications in pharmaceuticals

Paula dos Passos Menezes et al.

INTERNATIONAL JOURNAL OF PHARMACEUTICS (2019)

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Article Chemistry, Organic

Induced Circular Dichroism of Achiral Cyclic Bisurea via Hydrogen Bonds with Chiral Carboxylates

Kohei Osawa et al.

JOURNAL OF ORGANIC CHEMISTRY (2019)

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Article Chemistry, Analytical

Homoleptic cyclometalated iridium(III) complex nanowires electrogenerated chemiluminescence sensors for high-performance discrimination of proline enantiomers based on the difference of electron transfer capability

Tianhui Wu et al.

TALANTA (2019)

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Article Chemistry, Physical

Chiral colloidal CdSe quantum dots functionalized with cysteine molecules: New optical nanosensor for selective detection and measurement of morphine

M. Masteri-Farahani et al.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2019)

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Article Electrochemistry

A three-dimensional conductive molecularly imprinted electrochemical sensor based on MOF derived porous carbon/carbon nanotubes composites and prussian blue nanocubes mediated amplification for chiral analysis of cysteine enantiomers

Dingding Duan et al.

ELECTROCHIMICA ACTA (2019)

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Article Chemistry, Organic

Late-Stage Functionalization of (R)-BINOL-Based Diazacoronands and Their Chiral Recognition of α-Phenylethylamine Hydrochlorides

Agata Tyszka et al.

JOURNAL OF ORGANIC CHEMISTRY (2019)

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Article Chemistry, Analytical

A chiroptical nanoprobe for highly selective recognition of histidine enantiomers in aqueous media

Keyuan Liu et al.

SENSORS AND ACTUATORS B-CHEMICAL (2019)

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Review Chemistry, Multidisciplinary

Nanowire Photoelectrochemistry

Jiao Deng et al.

CHEMICAL REVIEWS (2019)

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Letter Environmental Sciences

Response to comment on Chiral pharmaceuticals: Environment sources, potential human health impacts, remediation technologies and future perspective

Shikang Wu et al.

ENVIRONMENT INTERNATIONAL (2019)

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Article Chemistry, Analytical

Electrochemical chiral sensing of tryptophan enantiomers by using 3D nitrogen-doped reduced graphene oxide and self-assembled polysaccharides

Xiaohui Niu et al.

MICROCHIMICA ACTA (2019)

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Article Nanoscience & Nanotechnology

Supramolecular Nanopumps with Chiral Recognition for Moving Organic Pollutants from Water

Sihan Bao et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Electrochemistry

A chiral electrochemical system based on L-cysteine modified gold nanoparticles for propranolol enantiodiscrimination: Electroanalysis and computational modelling

Ioan-Adrian Stoian et al.

ELECTROCHIMICA ACTA (2019)

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Article Chemistry, Organic

Enantioselective Solid-Liquid Extraction of Native Saccharides with Chiral BINOL-Based Pyridine-Phenol Type Macrocycles

Yuki Ohishi et al.

ORGANIC LETTERS (2019)

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Article Chemistry, Multidisciplinary

Construction of Chiral Nanoassemblies Based on Host-Guest Complexes and Their Responsive CD and CPL Properties: Chirality Transfer From 2,6-helic[6]arenes to a Stilbazolium Derivative

Yan Guo et al.

FRONTIERS IN CHEMISTRY (2019)

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Article Chemistry, Analytical

Dual-Signal Electrochemical Enantiospecific Recognition System via Competitive Supramolecular Host-Guest Interactions: The Case of Phenylalanine

Yinhui Yi et al.

ANALYTICAL CHEMISTRY (2019)

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Article Chemistry, Analytical

Enantiomers of Single Chirality Nanotube as Chiral Recognition Interface for Enhanced Electrochemical Chiral Analysis

Chunling Pu et al.

ANALYTICAL CHEMISTRY (2019)

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Article Chemistry, Analytical

Nanopaper-based photoluminescent enantioselective sensing of L-Lysine by L-Cysteine modified carbon quantum dots

Funda Copur et al.

SENSORS AND ACTUATORS B-CHEMICAL (2019)

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Article Chemistry, Analytical

Kissing interactions for the design of a multicolour fluorescence anisotropy chiral aptasensor

Benoit Chovelon et al.

TALANTA (2019)

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Review Chemistry, Analytical

Chiral sensors

Erhan Zor et al.

TRAC-TRENDS IN ANALYTICAL CHEMISTRY (2019)

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Article Nanoscience & Nanotechnology

Chiral Selectivity of Porphyrin-ZnO Nanoparticle Conjugates

Manuela Stefanelli et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Chemistry, Analytical

Carbon dot-decorated porous organic cage as fluorescent sensor for rapid discrimination of nitrophenol isomers and chiral alcohols

Zhenyu Lu et al.

ANALYTICA CHIMICA ACTA (2019)

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Article Chemistry, Organic

Guest-mediated chirality transfer in the host-guest complexes of an atropisomeric perylene bisimide cyclophane host

Meike Sapotta et al.

ORGANIC CHEMISTRY FRONTIERS (2019)

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Review Electrochemistry

Review-Recent Advances in Electrochemical Chiral Recognition

Gangbing Zhu et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2019)

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Article Nanoscience & Nanotechnology

Light-Emitting Devices Based on Electrochemiluminescence: Comparison to Traditional Light-Emitting Electrochemical Cells

Seok Hwan Kong et al.

ACS PHOTONICS (2018)

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Article Chemistry, Multidisciplinary

Induction of Chirality in Two-Dimensional Nanomaterials: Chiral 2D MoS2 Nanostructures

Finn Purcell-Milton et al.

ACS NANO (2018)

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Article Chemistry, Analytical

Fluorescence turn-on assay for detection of serum D-penicillamine based on papain@AuNCs-Cu2+ complex

Yifan Chen et al.

ANALYTICA CHIMICA ACTA (2018)

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Article Biochemical Research Methods

Fluorescent MUA-stabilized Au nanoclusters for sensitive and selective detection of penicillamine

Huan Yu et al.

ANALYTICAL AND BIOANALYTICAL CHEMISTRY (2018)

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Article Chemistry, Analytical

Coinduction of a Chiral Microenvironment in Polypyrrole by Overoxidation and Camphorsulfonic Acid for Electrochemical Chirality Sensing

Jiapei Yang et al.

ANALYTICAL CHEMISTRY (2018)

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Article Biophysics

Chiral magnetic-nanobiofluids for rapid electrochemical screening of enantiomers at a magneto nanocomposite graphene-paste electrode

J. Munoz et al.

BIOSENSORS & BIOELECTRONICS (2018)

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Article Materials Science, Paper & Wood

Electrochemical chiral sensor based on cellulose nanocrystals and multiwall carbon nanotubes for discrimination of tryptophan enantiomers

Yahui Zhang et al.

CELLULOSE (2018)

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Review Chemistry, Multidisciplinary

Conducting Polymers in the Fields of Energy, Environmental Remediation, and Chemical-Chiral Sensors

Jorge G. Ibanez et al.

CHEMICAL REVIEWS (2018)

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Review Chemistry, Analytical

The market of chiral drugs: Chiral switches versus de novo enantiomerically pure compounds

Andrea Calcaterra et al.

JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS (2018)

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Review Biochemistry & Molecular Biology

Chiral Drug Analysis in Forensic Chemistry: An Overview

Claudia Ribeiro et al.

MOLECULES (2018)

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Article Spectroscopy

An aptamer-based fluorescence bio-sensor for chiral recognition of arginine enantiomers

Haiyan Yuan et al.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2018)

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Article Chemistry, Analytical

Silver nanoparticles-embedded nanopaper as a colorimetric chiral sensing platform

Erhan Zor

TALANTA (2018)

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Article Multidisciplinary Sciences

Chiral self-sorted multifunctional supramolecular biocoordination polymers and their applications in sensors

Xiaobo Shang et al.

NATURE COMMUNICATIONS (2018)

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Article Chemistry, Multidisciplinary

A novel surface plasmon resonance sensor based on a functionalized graphene oxide/molecular-imprinted polymer composite for chiral recognition of l-tryptophan

Xiaoyan Xu et al.

RSC ADVANCES (2018)

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Review Environmental Sciences

Chiral pharmaceuticals: Environment sources, potential human health impacts, remediation technologies and future perspective

Yaoyu Zhou et al.

ENVIRONMENT INTERNATIONAL (2018)

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Article Materials Science, Multidisciplinary

3D graphene/hydroxypropyl-β-cyclodextrin nanocomposite as an electrochemical chiral sensor for the recognition of tryptophan enantiomers

Wenting Liang et al.

JOURNAL OF MATERIALS CHEMISTRY C (2018)

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Review Chemistry, Physical

Recent advances in electrochemical sensors based on chiral and nano-sized imprinted polymers

Francesco Canfarotta et al.

CURRENT OPINION IN ELECTROCHEMISTRY (2018)

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Review Chemistry, Physical

Enantioselective selectors for chiral electrochemistry and electroanalysis: Stereogenic elements and enantioselection performance

Serena Arnaboldi et al.

CURRENT OPINION IN ELECTROCHEMISTRY (2018)

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Review Chemistry, Physical

Electrogenerated chemiluminescence: A molecular electrochemistry point of view

A. Fiorani et al.

CURRENT OPINION IN ELECTROCHEMISTRY (2018)

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Review Chemistry, Physical

Interfacial supramolecular electrochemistry

Kang Cui et al.

CURRENT OPINION IN ELECTROCHEMISTRY (2018)

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Review Chemistry, Analytical

Review: Separation and Pharmacology of Chiral Compounds in Traditional Chinese Medicine

Xiong-Fei Wang et al.

ANALYTICAL LETTERS (2017)

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Article Chemistry, Physical

Methods for Electrochemical Synthesis and Photoelectrochemical Characterization for Photoelectrodes

Gokul V. Govindaraju et al.

CHEMISTRY OF MATERIALS (2017)

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News Item Chemistry, Multidisciplinary

SELF-ASSEMBLY Supramolecular basketry

Yi Liu

NATURE CHEMISTRY (2017)

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Article Materials Science, Multidisciplinary

Molecularly imprinted polymer based extended-gate field-effect transistor chemosensors for phenylalanine enantioselective sensing

Z. Iskierko et al.

JOURNAL OF MATERIALS CHEMISTRY C (2017)

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Review Chemistry, Multidisciplinary

Fluorescent chemosensors: the past, present and future

Di Wu et al.

CHEMICAL SOCIETY REVIEWS (2017)

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Review Chemistry, Multidisciplinary

Practical applications of supramolecular chemistry

Igor V. Kolesnichenko et al.

CHEMICAL SOCIETY REVIEWS (2017)

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Article Chemistry, Multidisciplinary

Enantioselective Recognition by Chiral Supramolecular Gels

Li Zhang et al.

CHEMISTRY-AN ASIAN JOURNAL (2016)

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Article Chemistry, Multidisciplinary

Microscopic Mechanism of Chiral Induction in a Metal-Organic Framework

Jack D. Evans et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

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Article Polymer Science

Supramolecular Chirality in Achiral Polyfluorene: Chiral Gelation, Memory of Chirality, and Chiral Sensing Property

Yin Zhao et al.

MACROMOLECULES (2016)

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Review Biochemistry & Molecular Biology

Determination of the Absolute Configurations of Chiral Drugs Using Chiroptical Spectroscopy

Prasad L. Polavarapu

MOLECULES (2016)

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Review Chemistry, Multidisciplinary

Chemiluminescence and electrochemiluminescence applications of metal nanoclusters

Shuang Han et al.

SCIENCE CHINA-CHEMISTRY (2016)

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Review Chemistry, Analytical

Molecularly imprinted polymer based enantioselective sensing devices: A review

Mahavir Prasad Tiwari et al.

ANALYTICA CHIMICA ACTA (2015)

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Review Chemistry, Multidisciplinary

Optical chirality sensing using macrocycles, synthetic and supramolecular oligomers/polymers, and nanoparticle based sensors

Zhan Chen et al.

CHEMICAL SOCIETY REVIEWS (2015)

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Review Polymer Science

Polymer-based supramolecular sensing and application to chiral photochemistry

Gaku Fukuhara

POLYMER JOURNAL (2015)

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Article Chemistry, Multidisciplinary

Host-guest interaction of hemicucurbiturils with phenazine hydrochloride salt

Ding-Ding Xiang et al.

SUPRAMOLECULAR CHEMISTRY (2015)

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Article Chemistry, Multidisciplinary

Noncovalent Chirality Sensing Ensembles for the Detection and Reaction Monitoring of Amino Acids, Peptides, Proteins, and Aromatic Drugs

Frank Biedermann et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

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Review Chemistry, Multidisciplinary

Chiral pharmaceuticals in the environment

Ana R. Ribeiro et al.

ENVIRONMENTAL CHEMISTRY LETTERS (2012)

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Review Chemistry, Analytical

Recent Advances in Paper-Based Sensors

Devi D. Liana et al.

SENSORS (2012)

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Review Chemistry, Multidisciplinary

Pharmacologically active compounds in the environment and their chirality

Barbara Kasprzyk-Hordern

CHEMICAL SOCIETY REVIEWS (2010)

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Review Chemistry, Multidisciplinary

Chirality-sensing supramolecular systems

Guy A. Hembury et al.

CHEMICAL REVIEWS (2008)

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Review Biochemical Research Methods

Environmental fate processes and biochemical transformations of chiral emerging organic pollutants

Charles S. Wong

ANALYTICAL AND BIOANALYTICAL CHEMISTRY (2006)

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Article Clinical Neurology

Single-Isomer Science: The Phenomenon and Its Terminology

Joseph Gal

CNS SPECTRUMS (2002)

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Article Biochemistry & Molecular Biology

Novel biosynthetic routes to non-proteinogenic amino acids as chiral pharmaceutical intermediates

DJ Ager et al.

JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC (2001)

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