Carbon and nitrogen co-doped In2O3 porous nanosheets with oxygen vacancies for remarkable photocatalytic CO2 conversion

Article Engineering, Environmental

Construction of dual vacancies to regulate the energy band structure of ZnIn2S4 for enhanced visible light-driven photodegradation of 4-NP

Guanhua Zhang et al.

Summary: In this study, ZnIn2S4 with Zn vacancy and S vacancy was prepared and showed enhanced photocatalytic performance due to the regulation of energy band structure and improved carrier separation efficiency.

JOURNAL OF HAZARDOUS MATERIALS (2023)

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Article Chemistry, Multidisciplinary

Sulfur Vacancy and Ti3C2Tx Cocatalyst Synergistically Boosting Interfacial Charge Transfer in 2D/2D Ti3C2Tx/ZnIn2S4 Heterostructure for Enhanced Photocatalytic Hydrogen Evolution

Tongming Su et al.

Summary: An ultrathin 2D/2D Ti3C2Tx/ZnIn2S4 heterostructure was designed with larger contact area and strong electronic interaction to promote charge carrier transfer, leading to enhanced photocatalytic hydrogen evolution. The synergistic effect of sulfur vacancy and Ti3C2Tx cocatalyst greatly improves electron transfer and separation of photogenerated charge carriers, increasing the efficiency of photocatalytic hydrogen evolution.

ADVANCED SCIENCE (2022)

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Article Chemistry, Multidisciplinary

Ultrahigh Photocatalytic CO2 Reduction Efficiency and Selectivity Manipulation by Single-Tungsten-Atom Oxide at the Atomic Step of TiO2

Yibo Feng et al.

Summary: The photocatalytic CO2 reduction reaction is a sustainable route to convert greenhouse gases into chemicals. Inorganic photocatalysts, like titanium dioxide (TiO2), have been extensively studied due to their stability and low cost. However, a more efficient TiO2 photocatalyst without noble metals is desired for CO2 reduction. In this study, a novel strategy of anchoring a single tungsten (W) atom site with oxygen-coordination at the intrinsic steps of TiO2 nanoparticles is developed. This strategy allows for the control of active sites composition, resulting in significantly improved CO2 reduction efficiency and methane selectivity.

ADVANCED MATERIALS (2022)

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Article Engineering, Environmental

Facile synthesis of three-dimensional hollow porous carbon doped polymeric carbon nitride with highly efficient photocatalytic performance

Dong Liu et al.

Summary: Developing a highly efficient metal-free catalyst with a fast H-2 evolution rate and efficient pollutant degradation efficiency is of great importance. In this study, a novel and feasible strategy to develop a highly efficient three-dimensional hollow porous C-doped polymeric carbon nitride (CPCN) catalyst based on morphological controls and in situ C doping was reported. The as-synthesized CPCN catalysts showed outstanding H-2 production activity and high degradation rate of diclofenac under visible light.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Chemistry, Physical

Multi-channel charge transfer of hierarchical TiO2 nanosheets encapsulated MIL-125(Ti) hollow nanodisks sensitized by ZnSe for efficient CO2 photoreduction

Yuzhen Jiao et al.

Summary: In this study, ZnSe-sensitized hierarchical TiO2 nanosheets encapsulated MIL-125 (Ti) hollow nanodisks were successfully prepared and their applications in CO2 photocatalytic reduction were investigated. The ternary hybrid exhibited enhanced light utilization efficiency and abundant active sites, and the multi-channel charge transfer routes contributed to the improved CO2 photocatalytic performance.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

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Article Chemistry, Physical

Efficient charge transfer and CO2 photoreduction of hierarchical CeO2@SnS2 heterostructured hollow spheres with spatially separated active sites

Zefeng Guan et al.

Summary: This study demonstrates the design and fabrication of hierarchical double-shelled CeO2@SnS2 hollow spheres with spatially separated active sites for efficient CO2 photoreduction. The unique structure of the catalyst provides abundant active sites, enhanced light absorption, and accelerated charge separation, resulting in remarkable CO2 photoreduction activity.

APPLIED SURFACE SCIENCE (2022)

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Review Chemistry, Inorganic & Nuclear

Defect engineering of BiOX (X = Cl, Br, I) based photocatalysts for energy and environmental applications: Current progress and future perspectives

S. Vinoth et al.

Summary: This article summarizes the importance of BiOX materials in energy and environmental applications. BiOX has a layered structure and high photocatalytic activity, and its physical and chemical properties and photocatalytic activity can be enhanced by controlling defects. The article also discusses the role of defect engineering in improving the performance of BiOX and prospects the future research opportunities.

COORDINATION CHEMISTRY REVIEWS (2022)

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Review Environmental Sciences

Two-dimensional ultrathin metal-based nanosheets for photocatalytic CO2 conversion to solar fuels

Maansi Aggarwal et al.

Summary: Artificially simulated photosynthesis has attracted great interest in increasing solar fuel efficiencies, and layered inorganic 2D nanosheets offer higher tunability. However, the applications of metal-based materials in photocatalytic CO2 reduction are still limited.

JOURNAL OF ENVIRONMENTAL MANAGEMENT (2022)

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Article Materials Science, Multidisciplinary

Oxygen vacancies induced narrow band gap of BiOCl for efficient visible-light catalytic performance from double radicals

Changyan Chen et al.

Summary: In this study, a high-efficiency photocatalytic BiOCl material with visible light absorption range was successfully synthesized using a one-pot molecular self-assembly and particle recrystallization method. The hierarchical structure and oxygen vacancies in the material improved its photocatalytic performance and enabled effective degradation of organic pollutants.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2022)

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Article Engineering, Environmental

Defect engineering in polymeric carbon nitride with accordion structure for efficient photocatalytic CO2 reduction and H2 production

Jianhua Hou et al.

Summary: In this study, N-vacancy defect containing and C-doped graphitic carbon-nitride nanosheets were synthesized for the first time, with a precisely tunable band-gap energy to enhance visible light absorption. The optimized catalyst showed impressive hydrogen evolution rate and CO production rate. Theoretical calculations demonstrated the importance of defect engineering in achieving highly efficient and multi-functional photocatalysis.

CHEMICAL ENGINEERING JOURNAL (2022)

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Review Chemistry, Multidisciplinary

The integration of bio-catalysis and electrocatalysis to produce fuels and chemicals from carbon dioxide

Xinyi Tan et al.

Summary: The dependence on fossil fuels has led to excessive greenhouse gas emissions, causing climate changes and global warming. Biotechnology offers a promising solution for producing high-density liquid transportation fuels that can reduce emissions. Additionally, developing technologies to convert atmospheric CO2 into fossil fuel replacements is urgently needed.

CHEMICAL SOCIETY REVIEWS (2022)

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Review Chemistry, Physical

Shining light on ZnIn2S4 photocatalysts: Promotional effects of surface and heterostructure engineering toward artificial photosynthesis

Valerie Bei-Yuan Oh et al.

Summary: This review discusses the limitations and modification strategies of ZnIn2S4 as a semiconductor photocatalyst, as well as its performance in hydrogen evolution, overall water splitting, and CO2 reduction reactions. This is of great significance for promoting the sustainable utilization of renewable fuels.

ECOMAT (2022)

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Article Engineering, Chemical

An overview on polymeric carbon nitride assisted photocatalytic CO2 reduction: Strategically manoeuvring solar to fuel conversion efficiency

Abhinandan Kumar et al.

Summary: The conversion of CO2 into hydrocarbon fuels using visible light driven photocatalysis is effective, but strategic modulations are necessary to overcome the drawbacks and complexity associated with PCN. The review comprehensively explores the factors influencing photocatalytic CO2 reduction and highlights useful approaches to enhance material efficiency by modulating major photocatalysis steps.

CHEMICAL ENGINEERING SCIENCE (2021)

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Review Chemistry, Multidisciplinary

Inorganometallic Photocatalyst for CO2 Reduction

Ho-Jin Son et al.

Summary: In the past few decades, the design of catalytic systems for CO2 reduction has been extensively researched, with a focus on multicomponent hybrid systems to lower energy barriers and increase reaction efficiency. The interface electron transfer efficiency between components plays a significant role in the overall photochemical reaction kinetics and mechanism.

ACCOUNTS OF CHEMICAL RESEARCH (2021)

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Article Chemistry, Physical

Defect engineering in polymeric carbon nitride photocatalyst: Synthesis, properties and characterizations

Longbo Jiang et al.

Summary: This review discusses the effects of vacancy defects on CN photocatalysts, highlighting the tuning of photoelectric properties and photocatalytic performance. Various characterization methods are summarized, providing a basis for further research and development in this field.

ADVANCES IN COLLOID AND INTERFACE SCIENCE (2021)

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Article Green & Sustainable Science & Technology

Fast preparation of oxygen vacancy-rich 2D/2D bismuth oxyhalides-reduced graphene oxide composite with improved visible-light photocatalytic properties by solvent-free grinding

Jianhua Hou et al.

Summary: Bismuth oxyhalides (BiOX, X = Cl, Br, I) with two-dimensional/two-dimensional (2D/2D) heterostructures have been successfully prepared without using any solvent recently. The BiOX/RGO heterostructures exhibit oxygen-rich vacancies and a short fabrication time of 15 min, promoting carrier separation efficiency and visible-light absorption. The photocatalytic performance of BiOX/RGO composites in degrading organic pollutants was significantly enhanced, showing improved degradation rates compared to pure BiOX.

JOURNAL OF CLEANER PRODUCTION (2021)

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Article Chemistry, Multidisciplinary

Printing High-Efficiency Perovskite Solar Cells in High-Humidity Ambient Environment-An In Situ Guided Investigation

Patrick Wai-Keung Fong et al.

Summary: This study focuses on the fabrication of perovskite solar cells (PSCs) in an air-knife-assisted high-humidity environment, achieving high performance. In-depth spectroscopy allows accurate determination of precursor film thickness, improving the precision of device fabrication.

ADVANCED SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Rational Design of High-Concentration Ti3+ in Porous Carbon-Doped TiO2 Nanosheets for Efficient Photocatalytic Ammonia Synthesis

Qing Han et al.

Summary: The study presents porous carbon-doped anatase TiOx (C-TiOx) nanosheets with high-concentration active sites of Ti3+ obtained through a reproducible bottom-up approach. It demonstrates that the high-concentration Ti3+ sites play a vital role in enhancing N-2 photoreduction activity. Combined with the morphology of porous nanosheets and the loading of a Ru/RuO2 cocatalyst, the optimized C-TiOx shows a high NH3 production rate and remarkable quantum efficiency under visible-light irradiation, outperforming current TiO2-based photocatalysts.

ADVANCED MATERIALS (2021)

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Article Green & Sustainable Science & Technology

Variable dimensional structure and interface design of g-C3N4/BiOI composites with oxygen vacancy for improving visible-light photocatalytic properties

Jianhua Hou et al.

Summary: This study demonstrated the preparation of variable dimensional structured BiOI with surface oxygen vacancies, forming the p-n heterojunction necessary for high-performance photocatalysis. Different dimensional structures of BiOI composites with g-C3N4 were investigated, revealing the optimized combination with 2D/2D structure showed the best photocatalytic performance.

JOURNAL OF CLEANER PRODUCTION (2021)

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Article Chemistry, Multidisciplinary

Fabrication of Black In2O3 with Dense Oxygen Vacancy through Dual Functional Carbon Doping for Enhancing Photothermal CO2 Hydrogenation

Yuhang Qi et al.

Summary: In this study, carbon-doped In2O3 was shown to possess full-spectral and high-intensity light absorption, achieving effective light-to-thermal conversion for CO2 reduction with high gas generation rate and stability.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Localized thermal spike driven morphology and electronic structure transformation in swift heavy ion irradiated TiO2 nanorods

Sutapa Dey et al.

Summary: The irradiation of TiO2 nanorods by 100 MeV Ag ions results in structural distortion and corrugated surface due to the rapid quenching of thermal spikes. The optical absorption study reveals changes in bandgap values with different fluences, and first principles calculations confirm the direct-to-indirect transition attributed to structural distortion at the highest fluence. This work demonstrates a unique technique to selectively tune the properties of nanorods for various applications.

NANOSCALE ADVANCES (2021)

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Review Chemistry, Multidisciplinary

Defect Engineering in 2D Photocatalytic Materials for CO2 Reduction

Rongrong Pan et al.

Summary: This review succinctly outlines the recent progress in designing and controlling defects in 2D photocatalysts, introduces characterization techniques for unveiling defect atomic arrangement and electronic structure, and discusses the impacts of defects on the functions of 2D photocatalysts during the CO2 reduction process.

CHEMNANOMAT (2021)

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Review Chemistry, Multidisciplinary

A Critical Review on Black Phosphorus-Based Photocatalytic CO2 Reduction Application

Guo-Qing Zhao et al.

Summary: This article reviews recent advances in the synthesis, structure, properties, and applications of photocatalytic reduction of CO2, with a focus on black phosphorus-based photocatalysts. The review discusses the advantages, influencing factors, and possible future perspectives of black phosphorus-based photocatalysts for CO2 reduction.

SMALL (2021)

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Article Multidisciplinary Sciences

Synergy of ferroelectric polarization and oxygen vacancy to promote CO2 photoreduction

Hongjian Yu et al.

Summary: In this study, significantly enhanced photocatalytic CO2 reduction activity is achieved through the synergy of surface oxygen vacancies and ferroelectric polarization over the Bi3TiNbO9 photocatalyst. This highlights the importance of ferroelectric properties and controlled surface defect engineering in enhancing the CO2 photoreduction performance.

NATURE COMMUNICATIONS (2021)

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Article Multidisciplinary Sciences

Sustained CO2-photoreduction activity and high selectivity over Mn, C-codoped ZnO core-triple shell hollow spheres

Mahmoud Sayed et al.

Summary: The photoreduction of CO2 into energy-rich products is a sustainable solution for global energy and environmental crisis with the use of Mn ions as ionized cocatalyst to promote the process. The design of core-triple shell Mn, C-codoped ZnO hollow spheres as efficient photocatalysts demonstrates promising CO2 conversion performance, highlighting the importance of ionized cocatalyst in sustainable energy production.

NATURE COMMUNICATIONS (2021)

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Article Materials Science, Multidisciplinary

MOF-derived hexagonal In2O3 microrods decorated with g-C3N4 ultrathin nanosheets for efficient photocatalytic hydrogen production

Liujun Hu et al.

Summary: This study reported the successful establishment of a highly efficient In2O3@g-C3N4 heterostructure for photocatalyzed H-2 evolution. The heterostructure exhibited significantly improved photocatalytic performance in the water-splitting process compared to pure g-C3N4 and In2O3 photocatalysts.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

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Review Chemistry, Multidisciplinary

Construction of a Z-scheme heterojunction for high-efficiency visible-light-driven photocatalytic CO2 reduction

Guoqiang Zhang et al.

Summary: The article introduces the research progress and advantages of using Z-scheme heterojunction photocatalysts to convert CO2, pointing out its great potential in improving efficiency, stability, and light responsiveness.

NANOSCALE (2021)

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Article Energy & Fuels

Bi/BiOCl Nanosheets Enriched with Oxygen Vacancies to Enhance Photocatalytic CO2 Reduction

Shuqi Wu et al.

Summary: In this study, BiOCl nanosheets were enriched with oxygen vacancies by in situ reduction and deposition of Bi on the surface, leading to significantly enhanced photocatalytic activity for CO2 reduction.

TRANSACTIONS OF TIANJIN UNIVERSITY (2021)

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Article Chemistry, Multidisciplinary

Air atmospheric photocatalytic oxidation by ultrathin C,N-TiO2 nanosheets

Xiuyan Cheng et al.

Summary: This study demonstrates the highly efficient photocatalytic sulfide oxidation reaction using ultrathin C,N-TiO2 nanosheets as a photocatalyst under mild conditions, such as in air and at room temperature, without the need for a sacrificial reagent, co-catalyst, or redox mediator.

GREEN CHEMISTRY (2021)

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Review Materials Science, Multidisciplinary

Product selectivity of photocatalytic CO2 reduction reactions

Junwei Fu et al.

MATERIALS TODAY (2020)

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Article Multidisciplinary Sciences

Cooperation of oxygen vacancies and 2D ultrathin structure promoting CO2 photoreduction performance of Bi4Ti3O12

Lizhen Liu et al.

SCIENCE BULLETIN (2020)

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Article Chemistry, Multidisciplinary

Defect Rich Hierarchical Porous Carbon for High Power Supercapacitors

Peng Cai et al.

FRONTIERS IN CHEMISTRY (2020)

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Article Multidisciplinary Sciences

Atomically dispersed Ni in cadmium-zinc sulfide quantum dots for high-performance visible-light photocatalytic hydrogen production

D. W. Su et al.

SCIENCE ADVANCES (2020)

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Review Chemistry, Multidisciplinary

Quantum Dot Assembly for Light-Driven Multielectron Redox Reactions, such as Hydrogen Evolution and CO2 Reduction

Xu-Bing Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Physical

C,N-Codoped TiO2 with a Nitrogen-Doped Carbon Coating Derived from 2,6-Diaminopyridine for Visible Light-Induced Photocatalytic Hydrogen Evolution

Xing Xu et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2019)

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Article Engineering, Chemical

Enhanced photocatalytic reduction of CO2 by fabricating In2O3/CeO2/HATP hybrid multi-junction photocatalyst

Jingru Guan et al.

JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS (2019)

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Article Chemistry, Multidisciplinary

A Polymer-Oriented Self-Assembly Strategy toward Mesoporous Metal Oxides with Ultrahigh Surface Areas

Hailong Xiong et al.

ADVANCED SCIENCE (2019)

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Article Chemistry, Multidisciplinary

Bio-inspired hierarchical hetero-architectures of in-situ C-doped g-C3N4 grafted on C, N co-doped ZnO micro-flowers with booming solar photocatalytic activity

Mohamad Azuwa Mohamed et al.

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY (2019)

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Article Multidisciplinary Sciences

Double-shelled hollow rods assembled from nitrogen/sulfur-codoped carbon coated indium oxide nanoparticles as excellent photocatalysts

Liming Sun et al.

NATURE COMMUNICATIONS (2019)

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Article Chemistry, Physical

Perylene-3,4,9,10-tetracarboxylic acid accelerated light-driven water oxidation on ultrathin indium oxide porous sheets

Ruijin Zheng et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2019)

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Article Chemistry, Physical

Porous nitrogen-rich g-C3N4 nanotubes for efficient photocatalytic CO2 reduction

Zhao Mo et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2019)

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Article Chemistry, Multidisciplinary

Ultrathin Visible-Light-Driven Mo Incorporating In2O3-ZnIn2Se4 Z-Scheme Nanosheet Photocatalysts

Yuguang Chao et al.

ADVANCED MATERIALS (2019)

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Article Chemistry, Physical

Single-step rapid aerosol synthesis of N-doped TiO2 for enhanced visible light photocatalytic activity

Panagiotis G. Smirniotis et al.

CATALYSIS COMMUNICATIONS (2018)

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Review Chemistry, Multidisciplinary

Artificial photosynthesis by light absorption, charge separation, and multielectron catalysis

Milos Dokic et al.

CHEMICAL COMMUNICATIONS (2018)

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Article Chemistry, Multidisciplinary

Construction of ZnIn2S4-In2O3 Hierarchical Tubular Heterostructures for Efficient CO2 Photoreduction

Sibo Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

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Article Chemistry, Multidisciplinary

N- and C-Modified TiO2 Nanotube Arrays: Enhanced Photoelectrochemical Properties and Effect of Nanotubes Length on Photoconversion Efficiency

Ahmed El Ruby Mohamed et al.

NANOMATERIALS (2018)

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Review Chemistry, Physical

Defect engineering in photocatalytic materials

Song Bai et al.

NANO ENERGY (2018)

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Article Chemistry, Multidisciplinary

Facile Strategy for Synthesizing Non-Stoichiometric Monoclinic Structured Tungsten Trioxide (WO3-x,) with Plasma Resonance Absorption and Enhanced Photocatalytic Activity

Shihao Chen et al.

NANOMATERIALS (2018)

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Review Chemistry, Physical

Two-dimensional layered nanomaterials for visible-light-driven photocatalytic water splitting

Xiaorong Gan et al.

MATERIALS TODAY ENERGY (2018)

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Article Chemistry, Physical

A direct Z-scheme g-C3N4/SnS2 photocatalyst with superior visible-light CO2 reduction performance

Tingmin Di et al.

JOURNAL OF CATALYSIS (2017)

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Article Chemistry, Physical

Oxygen vacancies induced exciton dissociation of flexible BiOCl nanosheets for effective photocatalytic CO2 conversion

Zhaoyu Ma et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

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Article Chemistry, Physical

Well-designed 3D ZnIn2S4 nanosheets/TiO2 nanobelts as direct Z-scheme photocatalysts for CO2 photoreduction into renewable hydrocarbon fuel with high efficiency

Guang Yang et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2017)

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Article Chemistry, Multidisciplinary

Surface-Plasmon-Enhanced Photodriven CO2 Reduction Catalyzed by Metal-Organic-Framework-Derived Iron Nanoparticles Encapsulated by Ultrathin Carbon Layers

Huabin Zhang et al.

ADVANCED MATERIALS (2016)

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Article Chemistry, Physical

Zn-Cu promoted TiO2 photocatalyst for CO2 reduction with H2O under UV light

P. N. Paulino et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2016)

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Article Chemistry, Physical

New insight into the enhanced photocatalytic activity of N-, C- and S-doped ZnO photocatalysts

Weilai Yu et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2016)

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Article Engineering, Chemical

Impact of Morphology and Nitrogen and Carbon Codoping on Photocatalytic Activity of TiO2 as Environmental Catalysts

S. Jafari et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2016)

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Article Chemistry, Physical

Mesostructured CeO2/g-C3N4 nanocomposites: Remarkably enhanced photocatalytic activity for CO2 reduction by mutual component activations

Mengli Li et al.

NANO ENERGY (2016)

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Article Chemistry, Multidisciplinary

Defect- Rich Ultrathin ZnAl-Layered Double Hydroxide Nanosheets for Effi cient Photoreduction of CO2 to CO with Water

Yufei Zhao et al.

ADVANCED MATERIALS (2015)

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Article Chemistry, Physical

Mesoporous Biphasic C and N Codoped Anatase Nanocrystal-Carbon Composites and their Derived Doped Anatase Nanoparticles in Phenol Elimination under Visible Light

Xiaojuan Zhu et al.

CHEMCATCHEM (2015)

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Review Chemistry, Multidisciplinary

Steering charge kinetics in photocatalysis: intersection of materials syntheses, characterization techniques and theoretical simulations

Song Bai et al.

CHEMICAL SOCIETY REVIEWS (2015)

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Carbon and nitrogen co-doped In2O3 porous nanosheets with oxygen vacancies for remarkable photocatalytic CO2 conversion

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