期刊
SURFACES AND INTERFACES
卷 38, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.surfin.2023.102814
关键词
Column experiments; FeS@h-BN; Heavy metal; Breakthrough curve; Dynamic models
The study focuses on the removal of selenium (IV) from aqueous solutions using a new type of composite adsorbent called FeS@h-BN nanocomposite. SEM, FTIR, XRD, and XPS analyses were conducted to investigate the surface properties of the coated layer. The effectiveness of different adsorbent materials in removing Se(IV) in dynamic water was examined using the Adams-Bohart, Thomas, and Yoon-Nelson models.
The removal of selenium (IV) from aqueous solutions was the focus of research that led to the discovery of a novel type of composite adsorbent called FeS@h-BN nanocomposite. This adsorbent was studied, characterized, and put to use in a fixed bed column. SEM, FTIR, XRD, and XPS analyses were conducted to learn more about the coated layer's surface properties. The effect of several adsorbent materials on the remediation of Se(IV) in dy-namic water was examined. The Adams-Bohart model, the Thomas model, and the Yoon-Nelson model were all utilized to get optimal fits to the kinetic data obtained from the adsorption process. Moreover, the Adams-Bohart model was only applicable to the beginning portion of the dynamic behavior of the FeS and FeS@h-BN columns. The Thomas and Yoon-Nelson models were sufficient for describing the breakthrough curve under all experi-mental conditions. For this dynamic process, the theoretical breakthrough curve profile was compared to an experimentally derived profile. It was discovered that FeS@h-BN nanocomposites are the most effective at removing Se(IV), and the adsorption of Se(IV) by a variety of adsorbent materials is enough for all three dynamic models.
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