期刊
ACS APPLIED ENERGY MATERIALS
卷 6, 期 9, 页码 -出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsaem.3c00422
关键词
aramid nanofibers; polyvinyl alcohol; solid-state polymer electrolyte; Li metal battery; ionic conductivity
A solid polymer electrolyte (SPE) composed of polyvinyl alcohol (PVA), reactive aramid nanofibers (RANFs), and lithium bistrifluoromethanesulfonimide (LiTFSI) was developed. It exhibits high mechanical properties, thermal stability, and efficient lithium-ion migration, enabling stable cycling of high-performance Li metal batteries.
Solid polymer electrolytes (SPEs) with high ionic conductivity and strong mechanical properties are preconditions for the stable cycling of high-performance Li metal batteries. However, single-polymer SPEs often have low ionic conductivity, which greatly limits their further application. Herein, a SPE composed of polyvinyl alcohol (PVA), reactive aramid nanofibers (RANFs), and lithium bistrifluoromethanesulfonimide (LiTFSI) is prepared using a simple solution-casting method. After introducing the RANFs, the SPE of RANFs/PVAcontaining LiTFSI not only exhibits high mechanical properties but also has good thermal stability. The RANFs/PVA SPE constructed from the strong hydrogen bond interaction between rigid RANFs and flexible PVA shows high migration efficiency of lithium ions. When the loading amount of RANFs is 2 wt %, the ionic conductivity of RANFs/PVA reaches similar to 7.7 x 10(-4) S center dot cm(-1), and the lithium-ion migration number is similar to 0.54 at 60 degrees C. Toward the Li|RANFs/ PVA-2 wt %|LiFePO4 full cell, the discharge specific capacity could reach 162.5 mA h center dot g(-1) at 60 degrees C and 0.1 C. Meanwhile, the Li|RANFs/PVA-2 wt %|LiFePO4 battery also shows outstanding long-term cycling performance and could maintain 81% of the initial capacity after 1200 cycles at 1 C. The solid-state Li|RANFs/ PVA|LiFePO4 cell also exhibits excellent resilience in destructive tests such as cell bending, piercing, and cutting.
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