Facile Aqueous Solution-Gel Route toward Thin Film CuBi2O4 Photocathodes for Solar Hydrogen Production

A new benign aqueous route toward bismuth-containing photoelectrodes is proposed to eliminate the need for harmful organic solvents and/or acids. A CuBi2O4 photocathode is prepared by stabilizing the metal ions through complexation in pH neutral aqueous solutions. Merits of the proposed approach are elemental homogeneity (with unique doping possibilities) and ease of fabrication (e.g., high scalability). The prepared aqueous CuBi2O4 precursor forms a nearly phase-pure kusachiite crystalline phase free of organics residuals and capable of water reduction due to its sufficiently negatively positioned conduction band at -0.4 V versus RHE. Deposition on fluorine doped tin oxide coated glass (FTO/glass) substrates and thermal treatment leads to uniform but granular films of CuBi2O4 with excellent control over stoichiometry and thickness, owing to the facile and non-destructive synthesis conditions. Ultimately, the optimized CuBi2O4 photocathodes produce AM1.5G photocurrent densities of up to -1.02 mA cm(-2) at 0.4 V versus RHE with H2O2 as an electron scavenger, competing with bare CuBi2O4 prepared through less benign non-aqueous organic synthesis routes.

Automated summary

A benign aqueous route for bismuth-containing photoelectrodes using CuBi2O4 as a photocathode is proposed. The method offers advantages of elemental homogeneity, ease of fabrication, and production of phase-pure kusachiite crystalline phase. The fabricated CuBi2O4 photocathodes demonstrate competitive photocurrent densities, comparable to non-aqueous organic synthesis routes.