Single and multilayer composite electrolytes for enhanced Li-ion conductivity with restricted polysulfide diffusion for lithium-sulfur battery

Article Multidisciplinary Sciences

Self-assembled monolayers direct a LiF-rich interphase toward long-life lithium metal batteries

Yujing Liu et al.

Summary: In this study, self-assembled monolayers (SAMs) were utilized to control electrolyte degradation and solid-electrolyte interphase (SEI) formation in lithium metal batteries (LMBs), resulting in improved cycling performance and lifespan.

SCIENCE (2022)

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Article Chemistry, Physical

Acceleration of selective lithium ion transport of PAES-g-2PEG self-assembled flexible solid-state electrolytes for lithium secondary batteries

Anh Le Mong et al.

Summary: The study demonstrates the enhancement of ionic conductivity in solid-state lithium secondary batteries by synthesizing PAES-g-2PEG electrolytes, showcasing excellent mechanical flexibility and thermal stability.

ENERGY STORAGE MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Electron and Ion Co-Conductive Catalyst Achieving Instant Transformation of Lithium Polysulfide towards Li2S

Xiaoge Hao et al.

Summary: A unique electron and ion co-conductive catalyst of carbon-coated Li1.4Al0.4Ti1.6(PO4)(3) (C@LATP) has been developed, which not only possesses strong adsorption to LiPSs but also promotes the instantaneous conversion reaction of LiPSs to Li2S. This catalyst effectively suppresses the shuttle effect of LiPSs and improves the utilization of sulfur in Li-S batteries.

ADVANCED MATERIALS (2021)

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Review Chemistry, Multidisciplinary

Tough and Flexible, Super Ion-Conductive Electrolyte Membranes for Lithium-Based Secondary Battery Applications

Anh Le Mong et al.

Summary: Recent developments in solid electrolytes as replacements for conventional liquid electrolytes in lithium-based batteries face challenges due to low Li-ion conductivity and poor mechanical properties. Hierarchitectural and composite polymer separators based on electrolyte membranes are seen as promising solutions to achieve high ionic conductivity and mechanical stability in this field.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Analytical

Study of solid polyurethane electrolytes synthesized from HDI and PEO of different molecular weight

Qian Zhang et al.

Summary: The development of solid polymer electrolyte (SPE) based on polyurethanes (PUs) shows promising potential for safe and high performance lithium ion batteries. Higher molecular weight of PEG leads to increased conductivity, but the addition of LiClO4 at a certain concentration can decrease the conductivity. Furthermore, there is a correlation between molecular weight and performance in PU-based SPEs.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Transport Properties of Flexible Composite Electrolytes Composed of Li1.5Al0.5Ti1.5(PO4)3 and a Poly(vinylidene fluoride-co-hexafluoropropylene) Gel Containing a Highly Concentrated Li[N(SO2CF3)2]/Sulfolane Electrolyte

Ji-Young Ock et al.

Summary: A flexible composite electrolyte was prepared by combining a Lit-ion-conducting solid electrolyte LATP and a PVDF-HFP gel containing LiTFSA/sulfolane electrolyte, showing that Li-ion conduction mainly occurred in the gel phase. However, the interfacial resistance between LATP and the PVDF-HFP gel was high, leading to a reduced contribution of LATP particles to Li-ion conduction in the composite electrolyte.

ACS OMEGA (2021)

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Article Engineering, Chemical

A sandwich-type composite polymer electrolyte for all-solid-state lithium metal batteries with high areal capacity and cycling stability

Zhengkun Xie et al.

JOURNAL OF MEMBRANE SCIENCE (2020)

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Article Chemistry, Physical

Garnet Si-Li7La3Zr2O12 electrolyte with a durable, low resistance interface layer for all-solid-state lithium metal batteries

Xiaoning Ma et al.

JOURNAL OF POWER SOURCES (2020)

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Article Multidisciplinary Sciences

An ultrastable lithium metal anode enabled by designed metal fluoride spansules

Huadong Yuan et al.

SCIENCE ADVANCES (2020)

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Article Chemistry, Multidisciplinary

A New Class of Ionically Conducting Fluorinated Ether Electrolytes with High Electrochemical Stability

Chibueze Amanchukwu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Physical

A Metal Organic Framework Derived Solid Electrolyte for Lithium-Sulfur Batteries

Poramane Chiochan et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Multidisciplinary Sciences

Direct observation of lithium metal dendrites with ceramic solid electrolyte

Maryam Golozar et al.

SCIENTIFIC REPORTS (2020)

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Article Nanoscience & Nanotechnology

Polyoxyethylene (PEO)|PEO-Perovskite|PEO Composite Electrolyte for All-Solid-State Lithium Metal Batteries

Ke Liu et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Chemistry, Physical

All-in-one improvement toward Li6PS5Br-Based solid electrolytes triggered by compositional tune

Zhixia Zhang et al.

JOURNAL OF POWER SOURCES (2019)

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Article Chemistry, Physical

LiNi0.8Co0.15Al0.05O2 as both a trapper and accelerator of polysulfides for lithium-sulfur batteries

Kai Shi et al.

ENERGY STORAGE MATERIALS (2019)

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Article Chemistry, Physical

Substitutional disorder: structure and ion dynamics of the argyrodites Li6PS5Cl, Li6PS5Br and Li6PS5I

I. Hanghofer et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2019)

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Article Chemistry, Physical

Solid Electrolyte Membrane Prepared from Poly(arylene ether sulfone)-g- Poly(ethylene glycol) for Lithium Secondary Battery

Le Mong Anh et al.

ACS APPLIED ENERGY MATERIALS (2019)

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Article Chemistry, Physical

Polysulfide diffusion controlled, non-shrinkable, porous, PAN/PES electrospun membrane for high energy Li-S battery application

R. Aswathy et al.

MATERIALS TODAY ENERGY (2019)

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Article Engineering, Multidisciplinary

Electrospun polymer electrolyte nanocomposites for solid-state energy storage

Kihyon Hong et al.

COMPOSITES PART B-ENGINEERING (2018)

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Article Chemistry, Physical

Interfacial reactivity and interphase growth of argyrodite solid electrolytes at lithium metal electrodes

Sebastian Wenzel et al.

SOLID STATE IONICS (2018)

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Article Chemistry, Physical

Controlling the polysulfide diffusion in lithium-sulfur batteries with a polymer membrane with intrinsic nanoporosity

Xingwen Yu et al.

MATERIALS TODAY ENERGY (2018)

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Article Chemistry, Physical

Hybrid solid electrolytes with excellent electrochemical properties and their applications in all-solid-state cells

Shaojie Chen et al.

IONICS (2017)

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Article Chemistry, Multidisciplinary

Influence of Lattice Polarizability on the Ionic Conductivity in the Lithium Superionic Argyrodites Li6PS5X (X = Cl, Br, I)

Marvin A. Kraft et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Article Chemistry, Physical

High-voltage and free-standing poly(propylene carbonate)/Li6.75La3Zr1.75Ta0.25O12 composite solid electrolyte for wide temperature range and flexible solid lithium ion battery

Jianjun Zhang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

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Article Nanoscience & Nanotechnology

Suppression of Lithium Dendrite Formation by Using LAGP-PEO (LiTFSI) Composite Solid Electrolyte and Lithium Metal Anode Modified by PEO (LiTFSI) in All-Solid-State Lithium Batteries

Chunhua Wang et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

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Article Chemistry, Multidisciplinary

A gel-ceramic multi-layer electrolyte for long-life lithium sulfur batteries

Qingsong Wang et al.

CHEMICAL COMMUNICATIONS (2016)

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Article Electrochemistry

A new composite solid electrolyte PEO/Li10GeP2S12/SN for all-solid-state lithium battery

Bo Chen et al.

ELECTROCHIMICA ACTA (2016)

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Article Chemistry, Multidisciplinary

Plating a Dendrite-Free Lithium Anode with a Polymer/Ceramic/Polymer Sandwich Electrolyte

Weidong Zhou et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

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Article Chemistry, Physical

A promising PEO/LAGP. hybrid electrolyte prepared by a simple method for all-solid-state lithium batteries

Yanran Zhao et al.

SOLID STATE IONICS (2016)

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Article Energy & Fuels

Metal-organic framework-based separator for lithium-sulfur batteries

Songyan Bai et al.

NATURE ENERGY (2016)

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Article Electrochemistry

Direct observation of lithium dendrites inside garnet-type lithium-ion solid electrolyte

Yaoyu Ren et al.

ELECTROCHEMISTRY COMMUNICATIONS (2015)

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Article Chemistry, Physical

Enhanced rate capability and cycle stability of lithium-sulfur batteries with a bifunctional MCNT@PEG-modified separator

Guanchao Wang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2015)

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Review Chemistry, Physical

Poly(ethylene oxide)-based electrolytes for lithium-ion batteries

Zhigang Xue et al.

JOURNAL OF MATERIALS CHEMISTRY A (2015)

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Review Chemistry, Multidisciplinary

25th Anniversary Article: Polymer-Particle Composites: Phase Stability and Applications in Electrochemical Energy Storage

Samanvaya Srivastava et al.

ADVANCED MATERIALS (2014)

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Article Chemistry, Multidisciplinary

Suppression of Lithium Dendrite Growth Using Cross-Linked Polyethylene/Poly(ethylene oxide) Electrolytes: A New Approach for Practical Lithium-Metal Polymer Batteries

Rachna Khurana et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

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Article Chemistry, Physical

Molecular structure and stability of dissolved lithium polysulfide species

M. Vijayakumar et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2014)

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Article Polymer Science

Preparation and Characterization of Composite Microporous Gel Polymer Electrolytes Containing SiO2(Li+)

Wei-li Li et al.

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS (2013)

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Article Chemistry, Physical

Composite Cathodes Containing SWCNT@S Coaxial Nanocables: Facile Synthesis, Surface Modification, and Enhanced Performance for Li-Ion Storage

Shu-Mao Zhang et al.

PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION (2013)

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Article Electrochemistry

Resolution of the Modulus versus Adhesion Dilemma in Solid Polymer Electrolytes for Rechargeable Lithium Metal Batteries

G. M. Stone et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2012)

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Article Chemistry, Physical

Mechanochemical synthesis of Li-argyrodite Li6PS5X (X = Cl, Br, I) as sulfur-based solid electrolytes for all solid state batteries application

Sylvain Boulineau et al.

SOLID STATE IONICS (2012)

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Article Electrochemistry

Measurement of transference numbers for lithium ion electrolytes via four different methods, a comparative study

S. Zugmann et al.

ELECTROCHIMICA ACTA (2011)

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Article Materials Science, Multidisciplinary

Studies of lithium argyrodite solid electrolytes for all-solid-state batteries

R. P. Rao et al.

PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE (2011)

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Article Electrochemistry

The impact of elastic deformation on deposition kinetics at lithium/polymer interfaces

C Monroe et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2005)

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Article Chemistry, Physical

The effect of plasticizers on transport and electrochemical properties of PEO-based electrolytes for lithium rechargeable batteries

YT Kim et al.

SOLID STATE IONICS (2002)

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Single and multilayer composite electrolytes for enhanced Li-ion conductivity with restricted polysulfide diffusion for lithium-sulfur battery

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