相关参考文献
注意：仅列出部分参考文献，下载原文获取全部文献信息。
Article
Chemistry, Physical
Xuan Zhou et al.
Summary: In aqueous Zn-ion batteries (AZBs), the use of Zn metal as an anode has advantages of high energy density, inherent safety, and low cost. However, direct contact between electrolytes and Zn metal leads to corrosion and dendrite growth, compromising the calendar life and Coulombic efficiency (CE) of AZBs. A novel hydrophobic-zincophilic bifunctional layer (HZBL-Zn) is introduced on the Zn surface to provide hydrophobic and uniform pathways for zinc ions.
ENERGY STORAGE MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Lu Wang et al.
Summary: The deposition behavior of Zn metal anodes in aqueous Zn batteries can be regulated using an aminosilane molecular layer, resulting in dendrite-free Zn metal anodes. This is achieved through a capture-diffusion-deposition process of Zn ions, induced by the aminosilane molecular layer, which promotes reversible Zn stripping/plating and leads to smooth and compact Zn electrodeposited layers. The aminosilane-modified Zn anode exhibits high Coulombic efficiency, long lifespan, and high capacity retention in full cells, making it a promising solution for practical Zn batteries and providing insights into interface modification for other metallic anodes at the molecular level.
Review
Chemistry, Multidisciplinary
Jin Cao et al.
Summary: This paper reviews the strategies of regulating Zn2+ solvation shells in electrolytes based on electrolyte engineering for dendrite-free and side reaction-suppressed aqueous zinc-ion batteries. Fruitful achievements have been made by controlling Zn2+ solvation shells through high-concentration electrolytes, deep eutectic solvents, ionic liquids, functional additives, etc.
ENERGY & ENVIRONMENTAL SCIENCE
(2022)
Article
Green & Sustainable Science & Technology
Daliang Han et al.
Summary: Aqueous zinc batteries are safer than lithium-ion batteries, but their anodes are susceptible to dendrite failure and side reactions. The authors demonstrate a low-cost electrolyte that involves hydrate salt and organic solvent, proving to be non-flammable. The zinc battery cell delivers excellent performance even at low temperatures of -30 degrees Celsius.
NATURE SUSTAINABILITY
(2022)
Article
Chemistry, Multidisciplinary
Yinxiang Zeng et al.
Summary: The study developed a 3D multifunctional host consisting of N-doped carbon fibers embedded with Cu nanoboxes for stable Zn-metal anodes. The host's structure alleviates volume change during cycling and enables uniform and dense Zn deposition, resulting in high Coulombic efficiency and long cycling life for the electrode.
ADVANCED MATERIALS
(2022)
Review
Chemistry, Multidisciplinary
Zhi Chang et al.
Summary: To address the solvent decomposition issue in rechargeable batteries, researchers have introduced porous materials at the electrode front-faces, which effectively reduces the decomposition problems and improves the stability of batteries.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Haixia Cai et al.
Summary: This paper investigates a lattice-matching strategy for designing high-performance Cu-metal anodes. By selecting Ni substrates with high lattice matching, the Cu anodes exhibit good reversibility and uniform electrodeposition. This work provides a pathway for designing high-performance Cu electrodes in aqueous rechargeable batteries.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Kang Zhao et al.
Summary: This study demonstrates the potential of cyclodextrins (CDs) as electrolyte additives for rechargeable Zn batteries. The addition of alpha-CD improves the stability and kinetics of Zn plating and stripping by adsorbing on the Zn surface and suppressing water-induced side reactions. This finding provides insight into the use of supramolecular macrocycles for enhancing the performance of aqueous battery chemistry.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Xiaofeng He et al.
Summary: The study introduces a concept of constructing an anion concentration gradient-assisted solid-electrolyte interphase for metal anodes, which enhances ionic conductivity and suppresses dendritic growth and side reactions. This new approach enables stable plating/stripping of zinc metal and shows improved cycling stability in various types of batteries and supercapacitors.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Multidisciplinary Sciences
Lin Ma et al.
Summary: Research shows that using methanol as an electrolyte solvent in rechargeable zinc metal batteries improves performance and stability, effectively solving issues in the battery, and has good cycle life at extreme temperatures.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
(2022)
Article
Multidisciplinary Sciences
Ruirui Zhao et al.
Summary: Researchers propose a new electrolyte formulation for aqueous zinc batteries, which involves the addition of lanthanum nitrate to improve the surface morphology of the electrode, enhancing the battery performance and cycle life.
NATURE COMMUNICATIONS
(2022)
Article
Chemistry, Physical
Meijia Qiu et al.
Summary: This article introduces a method to improve the long-term reversible plating/stripping of zinc anodes by introducing sorbitol as an additive. The research found that sorbitol can promote the preferred (002) orientation growth on the zinc anode surface, which facilitates stable inversion of the zinc deposition. Additionally, sorbitol modulates the solvation structure of Zn2+ and reduces common side reactions. Experimental results demonstrate the excellent stability of the zinc anode in zinc-zinc symmetric cells and other types of full cells.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Fuhua Yang et al.
Summary: It is demonstrated that H-2 evolution in aqueous zinc-ion batteries primarily originates from solvated water and can be suppressed by additives, leading to improved cycle stability and electrochemical performance.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Yao Qin et al.
Summary: A chemical welding strategy to in situ construct a gel electrolyte enables Zn-ion batteries with a well-bonded and water-poor electrode-electrolyte interface, alleviating side reactions and enabling preferential Zn deposition. This approach leads to ultralong lifespan and reversibility in Zn-ion batteries.
ADVANCED MATERIALS
(2022)
Article
Multidisciplinary Sciences
Wenyao Zhang et al.
Summary: This study reports a highly reversible aqueous zinc battery with a dynamic and self-repairing protective interphase formed by the addition of graphitic carbon nitride quantum dots. The system exhibits single Zn2+ conduction, dendrite-free Zn plating/stripping, and impressive cyclability, making it a promising alternative to lithium batteries in low-cost, large-scale applications.
NATURE COMMUNICATIONS
(2022)
Article
Chemistry, Physical
Feifei Wang et al.
Summary: By using a U-shaped deposition configuration and a nanoarray of 2D MOF flakes, the issue of zinc dendrite growth in zinc batteries is effectively solved, achieving uniform deposition of zinc metal and prolonging the cycling stability of the batteries.
ENERGY STORAGE MATERIALS
(2022)
Article
Electrochemistry
Mingming Wang et al.
Summary: This study constructs a Zn/Bi electrode by in-situ growth of a Bi-based energizer upon the Zn metal surface using a replacement reaction. Experimental and theoretical calculations demonstrate that the Bi-based energizer composed of metallic Bi and ZnBi alloy contributes significantly to Zn plating/stripping due to strong adsorption energy and fast ion transport rates. The Zn/Bi electrode not only avoids Zn dendrite growth but also improves Zn anode anti-corrosion performance.
Article
Chemistry, Multidisciplinary
Huanyan Liu et al.
Summary: This research proposes a novel metal-organic complex interphase strategy to address the corrosion and dendrite issues in aqueous Zn metal batteries. By forming complex interphases between metal Zn and phytic acid, the deposition of Zn is made more uniform and the Coulombic efficiency is significantly improved, leading to enhanced stability and cycling lifetime of Zn metal batteries.
ENERGY & ENVIRONMENTAL SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Junnan Hao et al.
Summary: A similar antisolvent strategy has been used to enhance Zn reversibility and suppress dendrite growth in Zn plating/stripping, with promising results shown in 50% methanol electrolyte. This low-cost strategy can be easily applied to other solvents, demonstrating practical universality and potential for enhancing performance in electrochemistry and energy storage research.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Review
Chemistry, Multidisciplinary
Yiming Sui et al.
Summary: Aqueous electrolytes are a promising candidate for safe and low-cost storage batteries, but the narrow electrochemical stability window of water poses challenges for the development of high-energy aqueous batteries. Electrolysis of water leads to HER and OER, causing inefficiency, short device lifespan, and safety issues. Understanding the mechanisms of HER and OER and addressing water electrolysis suppression are critical for the future advancement of aqueous battery technology.
Article
Energy & Fuels
Jingxu Zheng et al.
Summary: The study presents a novel approach to control reversible metal electrodeposition by promoting oxygen-mediated chemical bonding, leading to improved reversibility and cycle life of aluminum and zinc anodes, ultimately enhancing battery performance.
Article
Chemistry, Multidisciplinary
Jiahui Zhou et al.
Summary: By synthesizing a nitrogen-doped graphene oxide film on zinc foil, this study effectively suppresses hydrogen evolution reactions and passivation, improving the electrochemical performance of aqueous Zn-ion batteries. This research provides a new method for enhancing the application of high-specific-energy AZIBs.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Lei Ye et al.
Summary: By using graphene quantum dots as a protective layer, the issue of Li-ion depletion caused by high-rate Li deposition has been successfully resolved, allowing for long-term reversible Li plating/stripping and improving battery performance.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Multidisciplinary Sciences
Tianyu Zhang et al.
Summary: Functionalized graphene quantum dots can efficiently convert CO2 to CH4, with the yield of CH4 positively correlated to the electron-donating ability of the functional groups. The electron-donating groups play a significant role in regulating the reactivity of graphene quantum dots in CO2 electro-reduction, providing insight into the design of active carbon catalysts for this process.
NATURE COMMUNICATIONS
(2021)
Article
Electrochemistry
Xiulei Ji
Summary: Molten ZnCl2 hydrates are ionic liquids with intriguing physical and electrochemical properties, suitable for use as electrolytes in Zn metal batteries. Understanding the properties of molten ZnCl2 hydrates is crucial for designing high-performance electrolytes.
Article
Chemistry, Multidisciplinary
Xiaohui Zeng et al.
Summary: Inspired by the bio-adhesion principle, a stable SEI layer of polydopamine was successfully constructed on a Zn anode, offering multifunctional features that regulate Zn nucleation, enhance Zn-ion conductivity, and block interfacial side reactions. This approach significantly improved the performance and stability of rechargeable aqueous zinc-ion batteries.
ENERGY & ENVIRONMENTAL SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Yuzhu Chu et al.
Summary: The in situ construction of a composite SEI mainly composed of Zn-3(PO4)(2) and ZnF2 (ZCS) effectively suppresses Zn dendrite growth and accelerates Zn2+ transference and deposition kinetics in aqueous Zn-ion batteries. By taking advantage of the instability of KPF6 in an aqueous environment, an in situ ZCS is successfully built on the Zn anode through a PF6- anion-induced chemical strategy, showing enhanced reversibility and excellent electrochemical performance. This work not only paves a new way for designing a desirable SEI on the Zn anode, but also may guide the interface engineering of other systems to overcome intrinsic defects in constructing favorable interphases.
ENERGY & ENVIRONMENTAL SCIENCE
(2021)
Review
Energy & Fuels
Yanliang Liang et al.
Article
Energy & Fuels
Lin Ma et al.
Article
Chemistry, Physical
Lele Peng et al.
Article
Chemistry, Multidisciplinary
Xuesong Xie et al.
ENERGY & ENVIRONMENTAL SCIENCE
(2020)
Review
Chemistry, Multidisciplinary
Zhuoxin Liu et al.
CHEMICAL SOCIETY REVIEWS
(2020)
Article
Multidisciplinary Sciences
Jingxu Zheng et al.
Article
Chemistry, Physical
Zhuo Wang et al.
Article
Multidisciplinary Sciences
Jingjie Wu et al.
NATURE COMMUNICATIONS
(2016)
Article
Energy & Fuels
Huilin Pan et al.
Article
Energy & Fuels
Dipan Kundu et al.
Article
Materials Science, Multidisciplinary
Dan Qu et al.
ADVANCED OPTICAL MATERIALS
(2015)
Article
Chemistry, Multidisciplinary
Dan Qu et al.
