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Article
Multidisciplinary Sciences
Zhoudong Yang et al.
Summary: This study investigates the reversible nature of the sulfur oxidation reaction (SOR) in sulfur-based aqueous batteries (SABs) by activating the elaborate mesocrystal NiS2 (M-NiS2). By utilizing a unique 6e(-) solid-to-solid conversion mechanism, an unprecedented SOR efficiency of ca. 96.0% is achieved. The research reveals the importance of the kinetics and thermodynamics in determining the SOR efficiency, and provides insights for the development of high-energy aqueous batteries.
NATIONAL SCIENCE REVIEW
(2023)
Article
Chemistry, Physical
Qiang Hu et al.
Summary: The addition of additives such as hexanehexol (Hex) can enhance the reversibility of Zn-metal aqueous batteries by regulating the solvation shell and electrode interface. Experimental results show that Hex, with 6 hydroxyls, is the most effective additive as it forms more hydrogen bonds with active H2O molecules and achieves stronger adsorption energy with Zn metal. This hydroxyl chemistry strategy can be applied to screening other electrolyte additives, indicating its practical universality.
ENERGY STORAGE MATERIALS
(2023)
Article
Nanoscience & Nanotechnology
Ying Zhang et al.
Summary: The researchers improve the cycling lifespan and electrochemical performance of aqueous zinc-ion batteries (AZIBs) by constructing an artificial protective interface layer on the zinc metal. A dense and uniform complex coating layer of phytic acid (PA) and zinc is formed on the zinc anodes, effectively inhibiting corrosion reactions and enhancing the deposition and stripping of zinc. Under experimental conditions, the PA-Zn metal anode exhibits low overpotential and long lifespan.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Review
Chemistry, Multidisciplinary
Jin Cao et al.
Summary: This paper reviews the strategies of regulating Zn2+ solvation shells in electrolytes based on electrolyte engineering for dendrite-free and side reaction-suppressed aqueous zinc-ion batteries. Fruitful achievements have been made by controlling Zn2+ solvation shells through high-concentration electrolytes, deep eutectic solvents, ionic liquids, functional additives, etc.
ENERGY & ENVIRONMENTAL SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Zhixiao Xu et al.
Summary: An ultrafast, stable, and high-loading polymer anode for aqueous Zn-ion batteries and capacitors has been developed through the engineering of both the electrode and electrolyte. This polymer anode exhibits a low discharge potential, near-theoretical capacity, ultrahigh-loading capability, ultrafast rate, and ultralong lifespan.
ADVANCED MATERIALS
(2022)
Article
Engineering, Environmental
Wenchao Shi et al.
Summary: By constructing a dense phytic acid conversion film on the surface of zinc metal, the issues of zinc dendrites and side reactions in aqueous zinc ion batteries (ZIBs) can be effectively addressed, resulting in significantly prolonged cycle lifespan of the battery.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Hongpeng Li et al.
Summary: A hierarchical confinement strategy using porous Co-embedded carbon cages is proposed to address the kinetics and stability issues of Zn capture in aqueous batteries. This strategy enables dendrite-free behavior with excellent kinetics and stable cycle life, pushing forward the next-generation high-performance ZABs.
Article
Chemistry, Physical
Guoqiang Ma et al.
Summary: In this study, the stability of metallic zinc anode in aqueous batteries was significantly improved by using a non-concentrated aqueous zinc trifluoromethanesulfonate electrolyte with 1,2-dimethoxyethane additive. The introduction of DME disrupted the original hydrogen-bond network of water and created a unique Zn2+-solvation structure, effectively suppressing water-induced side reactions. The in-situ formation of an organic-inorganic hybrid interphase on the zinc anode further prevented water penetration and dendrite growth. This novel electrolyte enabled the zinc anodes to achieve unprecedented cycling stability and high reversibility.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Physical
Yongfeng Huang et al.
Summary: This study investigates the stripping/plating behaviors and dendrite growth of metallic zinc anodes in aqueous electrolytes. It is found that the addition of Mn2+ can suppress zinc dendrite growth, and the use of Zn(CF3SO3)(2) as an electrolyte can achieve dendrite-free anodes.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Physical
Tongtong Yuan et al.
Summary: This article reports the successful synthesis of phytic acid coated/inserted V2O5 nano-composites by one-step hydrothermal method, which exhibits excellent stability and diffusion kinetics, leading to significantly improved electrochemical performance. This work paves the way for the design and fabrication of stable cathodes with excellent performance for AZIBs.
APPLIED SURFACE SCIENCE
(2022)
Article
Chemistry, Physical
Fangjia Zhao et al.
Summary: Researchers have discovered that adding trace amounts of perfluorooctanoic acid (PFOA) to aqueous zinc-ion batteries (AZIBs) can effectively address issues such as side reactions and poor performance. The PFOA additives reduce the surface tension of electrolytes and improve the wettability of electrolytes on the electrode, thereby enhancing the electrochemical stability and lifespan of the battery.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Physical
Jing Yang et al.
Summary: This study proposes using nicotinamide as an additive to enhance the stability and reversibility of zinc anodes in zinc-iron flow batteries, leading to improved power density, cycling stability, self-discharge resistance, and battery efficiency.
ACS ENERGY LETTERS
(2022)
Article
Chemistry, Physical
Sucheng Liu et al.
Summary: This study proposes a novel aqueous electrolyte to inhibit vanadium dissolution and significantly extend cycling lifespan at low current density by regulating the solvation structure of Zn2+. The optimized electrolyte solvation structure stabilizes the electrolyte/cathode interfaces, inhibits crystalline-to-amorphous transformation, and maintains the integrity of the vanadium oxide host lattice.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Dongdong Wang et al.
Summary: N-methyl pyrrolidone (NMP) is developed as a bifunctional electrolyte additive to improve the electrochemical performance of Zn anode, protecting it from corrosion and facilitating uniform plating/stripping of Zn.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Physical
Jiangfeng He et al.
Summary: By engineering organophosphate superionic nanochannels, the challenge of simultaneously providing durable protection and fast Zn2+ migration in high-rate scenarios has been successfully addressed. The design rich in intrinsic hydrogen bond donors has significantly reduced the Zn2+ migration energy barrier, leading to excellent battery performance.
ADVANCED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Kai Yang et al.
Summary: A triple-functional strategy is proposed to address the key challenges faced by aqueous Zn-ion batteries. By using a polyoxovanadate cluster as a Zn2+ host, the cathode, electrolyte, and metallic Zn anode can be simultaneously stabilized. The Zn//POV battery exhibits excellent cycling stability at high rates.
ADVANCED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Wenjing Deng et al.
Summary: The study proposes a simple strategy to achieve high reversibility of metallic zinc in rechargeable batteries by introducing the organic solvent DMA as an electrolyte additive, which controls water activity, replaces water in Zn2+ solvation sheath, and reshapes the hydrogen-bonding network of water. This strategy enables remarkable suppression of water-involved hydrogen evolution and severe corrosion, leading to uniform deposition of zinc and long cycling life in batteries.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Physical
Chunyan Fu et al.
Summary: This study systematically investigates hydrogel electrolytes for zinc metal anodes (ZMAs) by regulating their crosslinking and grafting structures. The results highlight the importance of network structure and polymeric anions in the hydrogel. The PSX gel, crosslinked by carboxyl-grafted polyvinyl alcohol and xanthan gum, demonstrates superior performance with high ionic conductivity and a considerable Zn2+ transference number. Zn//Zn cells with PSX electrolytes show uniform zinc deposition, minimal by-products, and suppressed hydrogen evolution. The PSX electrolyte also exhibits good compatibility and excellent performance when paired with V2O5 or active carbon cathodes. Flexible pouch cells withstand different deformation and stress conditions.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Physical
Qing Wen et al.
Summary: This study proposes a strategy of interfacial engineering and in situ etching to address the challenges of zinc dendrites and side reactions in aqueous rechargeable zinc ion batteries. By introducing a zinc l-cysteine functional layer, the hydrophobicity of the zinc anode is improved, corrosion is mitigated, and uniform zinc deposition is guided. In addition, in situ etching of the zinc foil increases the electrochemical surface area and reduces interfacial resistance. The experimental results show that the Cys-Zn-coated zinc anode exhibits excellent cycling and rate performance.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Chemistry, Physical
Yuting Li et al.
Summary: This research developed a stable CaF2 protective layer to address the issues of dendritic growth and side reactions in zinc ion batteries. The CaF2 layer exhibited excellent performance, resulting in an ultra-long cycle life and high capacity retention in Zn ion batteries.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Chemistry, Multidisciplinary
Cheng Wang et al.
Summary: By developing ZnCl2-based electrolytes, researchers have successfully improved the energy density and cycling life of zinc ion hybrid capacitors. Through the mechanism of desolvation facilitated by chloride ions and the use of a water-in-salt hydrogel electrolyte, they were able to achieve this goal.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Nannan Zhang et al.
Summary: In this study, an ultrathin and uniform MXene layer was assembled on the surface of zinc anodes using an in situ spontaneously reducing/assembling strategy. The integrated MXene layer reduced the zinc nucleation energy barrier and provided a more uniformly distributed electric field, resulting in low voltage hysteresis and excellent cycling stability with dendrite-free behaviors in zinc-ion batteries.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Yunpei Zhu et al.
Summary: Aqueous Zn-based batteries are promising due to their low cost and high capacity, but existing designs use excess Zn which reduces energy density. A new anode-free design utilizing nanocarbon nucleation layer enables uniform Zn electrodeposition with high efficiency and stability across various current densities. This innovation opens up new possibilities for implementing Zn-based batteries in energy storage systems.
Article
Chemistry, Multidisciplinary
Xiaohui Zeng et al.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Xiaoyong Fan et al.
Summary: By constructing a unique Zn-Sn-Pb alloy anode within 3D Cu foam, the issues of uncontrollable zinc deposition and dendrite growth in aqueous zinc-ion batteries have been successfully tackled, leading to enhanced stability and cycling life of the battery.
ADVANCED MATERIALS INTERFACES
(2021)
Review
Energy & Fuels
Nasr Bensalah et al.
Summary: AZIBs are promising candidates for grid-scale energy-storage systems, with advantages such as potential performance improvements with MnO2 and V2O5-based cathodes; the fast and facile storage mechanism of Zn2+ ions favors layered electrode materials for a more stable structure during charge and discharge cycles.
Article
Chemistry, Multidisciplinary
Xia Wang et al.
Summary: Acid etching can improve the electrodeposition quality and corrosion resistance of zinc metal anodes, enhancing Zn2+ ion kinetics; phosphoric acid etching yields the most compact layer; the zinc phosphate@Zn electrode shows stable cycling and fast kinetics in zinc metal batteries.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Review
Chemistry, Multidisciplinary
Jiahao Liu et al.
Summary: This article focuses on constructing a theory-to-application methodology for aqueous sulfur-based batteries. Research reveals the complexity in the electrochemistry of aqueous sulfur-based batteries, which poses challenges and potential for future development. Further exploration in both theory and practice is needed for the future development direction.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Multidisciplinary
Doudou Feng et al.
Summary: DMSO is demonstrated as an effective additive in ZnSO4 electrolyte for suppressing dendrites growth and improving the performance, stability, and cycling life of aqueous batteries at low temperatures. This work provides a facile and feasible strategy for designing high-performance and dendrite-free aqueous Zn-ion batteries for various temperatures.
Article
Chemistry, Multidisciplinary
Zhisen Zeng et al.
Summary: This study optimized the performance of aqueous Zn-ion batteries by adding sulfuric acid to the ZnSO4 electrolyte and depositing three metallic oxides on the Zn foil, which improved stability and cycling life. Among the three metallic oxides, full cells with Fe2O3@Zn showed the best diffusion of Zn2+ in acidic electrolyte, leading to superior battery capacity and lower overpotential.
Article
Chemistry, Physical
Hao Jia et al.
Summary: This study proposes a method using a liquid metal coating as a protective layer to prevent dendrite growth on the zinc metal anode surface. The liquid metal layer effectively inhibits dendrite formation, accelerates zinc nucleation speed and electron transfer, improves charge transfer efficiency, significantly reduces interfacial resistance, and extends the cycling life of zinc batteries.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Chemistry, Multidisciplinary
Yang Dong et al.
Summary: This study presents a non-concentrated aqueous electrolyte composed of 2m zinc trifluoromethanesulfonate and the organic dimethyl carbonate additive, which can stabilize the zinc electrochemistry and improve the coulombic efficiency of the zinc anode. Furthermore, this electrolyte can sustain stable operation of rechargeable aqueous zinc batteries when paired with various cathode materials. Rational electrolyte design with organic solvent additives could lead to the development of better aqueous batteries.
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Engineering, Environmental
Lu Han et al.
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(2020)
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Sanket Bhoyate et al.
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(2020)
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Yan Jin et al.
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(2020)
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CHEMICAL ENGINEERING JOURNAL
(2020)
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Xuesong Xie et al.
ENERGY & ENVIRONMENTAL SCIENCE
(2020)
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Ahmad Naveed et al.
ADVANCED MATERIALS
(2019)
Article
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Qi Yang et al.
ADVANCED MATERIALS
(2019)
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Youcai Ding et al.
APPLIED SURFACE SCIENCE
(2019)
Article
Electrochemistry
You Xiao et al.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2018)
Article
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Litao Kang et al.
ADVANCED ENERGY MATERIALS
(2018)
Review
Chemistry, Multidisciplinary
Jin Yi et al.
ENERGY & ENVIRONMENTAL SCIENCE
(2018)
Review
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Guozhao Fang et al.
ACS ENERGY LETTERS
(2018)
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Shu Shen et al.
APPLIED SURFACE SCIENCE
(2013)
Article
Agriculture, Multidisciplinary
Lynne Heighton et al.
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
(2008)
Article
Biochemistry & Molecular Biology
UP Rodrigues-Filho et al.
JOURNAL OF INORGANIC BIOCHEMISTRY
(2005)
