Oxygen-vacancy europium-doped MnO2 ultrathin nanosheets used as asymmetric supercapacitors

Article Chemistry, Physical

Organic-inorganic hybrid electrode engineering for high-performance asymmetric supercapacitor based on WO3-CeO2 nanowires with oxygen vacancies

Yao He et al.

Summary: An innovative electrode structure design utilizing PEDOT and PEDOT:PSS to assemble with WO3 and WO3-CeO2 nanowires has shown promising results in improving capacitance performance in the field of energy storage.

APPLIED SURFACE SCIENCE (2022)

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Review Chemistry, Multidisciplinary

Rare-Earth Doping in Nanostructured Inorganic Materials

Bingzhu Zheng et al.

Summary: Rare-earth doping is a promising method to enhance the properties of materials, such as optical, electronic, catalytic, and magnetic properties. It can improve energy harvesting and conversion efficiency. Understanding the critical role of rare-earth doping is essential for the development of functional nanomaterials and their applications in various fields.

CHEMICAL REVIEWS (2022)

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Review Thermodynamics

Laser processing of graphene and related materials for energy storage: State of the art and future prospects

Rajesh Kumar et al.

Summary: This review summarizes recent studies on laser-assisted synthesis and modification of graphene-based materials, as well as their application as electrodes for supercapacitors and batteries. It provides an overview of the physical properties of graphene and different types of laser processing operations, with a detailed discussion on the practical uses of laser techniques for fabricating electrode materials.

PROGRESS IN ENERGY AND COMBUSTION SCIENCE (2022)

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Article Engineering, Environmental

Oxygen vacancy inducing phase transition during charge storage in MnOx@rGO supercapacitor electrode

Fengyang Jing et al.

Summary: In this study, in-situ Raman and electrochemical quartz crystal microbalance techniques combined with density functional theory (DFT) calculations were employed to investigate the charge storage mechanism of MnOx@graphene microspheres electrode in alkaline electrolyte. The results revealed the transformation of layered MnO(2) into spinel Mn3O4 phase during the discharge process, accompanied by the insertion of potassium ions. Moreover, it was found that the presence of potassium ions contributed to the stability of the MnO structure. Additionally, the MnOx@graphene microspheres electrode demonstrated excellent cyclic stability.

CHEMICAL ENGINEERING JOURNAL (2022)

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Review Chemistry, Multidisciplinary

Rare Earth-Based Nanomaterials for Supercapacitors: Preparation, Structure Engineering and Application

Yao He et al.

Summary: Supercapacitors can effectively address the problems of energy shortage and greenhouse effect. Rare earth (RE) elements or compounds added to electrode materials greatly enhance their electrochemical performance. However, comprehensive surveys on RE-based nanomaterials for supercapacitors are lacking. This review provides a comprehensive overview of RE-based nanomaterials, including preparation methods, nanostructure engineering, compounds, and composites, along with their capacitance performances. The structure-activity relationships are discussed, and future challenges and perspectives are highlighted. This review not only guides the further development of supercapacitors but also sparks interest in RE-based nanomaterials in other research fields.

CHEMSUSCHEM (2022)

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Article Chemistry, Physical

Coupling structural evolution and oxygen-redox electrochemistry in layered transition metal oxides

Donggun Eum et al.

Summary: This study explores the close interplay between the local structural change and oxygen electrochemistry during short- and long-term battery operation for layered transition metal oxides (TMOs). The evolution of oxygen-redox activity and reversibility is found to be closely related to cation-migration mechanisms.

NATURE MATERIALS (2022)

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Article Materials Science, Multidisciplinary

In situ construction of heterostructured bimetallic sulfide/phosphide with rich interfaces for high-performance aqueous Zn-ion batteries

Fang Yang et al.

Summary: A phosphating-assisted interfacial engineering strategy was developed to convert NiCo2S4 nanosheets into heterostructured NiCoP/NiCo2S4 cathodes for aqueous Zn-ion batteries, showing high specific capacity and excellent cycling stability. This work provides a promising approach for constructing high-performance energy storage devices in the future.

SCIENCE CHINA-MATERIALS (2022)

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Article Energy & Fuels

Electrochemical deposition of uniform and porous Co–Ni layered double hydroxide nanosheets on nickel foam for supercapacitor electrode with improved electrochemical efficiency

Sally M. Youssry et al.

Journal of Energy Storage (2022)

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Article Nanoscience & Nanotechnology

Spectroscopic Monitoring of the Electrode Process of MnO2@rGO Nanospheres and Its Application in High-Performance Flexible Micro-Supercapacitors

Jinghao Zhao et al.

Summary: A stable MnO2@rGO core-shell nanosphere was synthesized, and its structural transformation and performance during electrochemical reactions were investigated. The material showed high specific capacitance, excellent cycling stability, and mechanical flexibility.

ACS APPLIED MATERIALS & INTERFACES (2022)

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Article Chemistry, Physical

High surface area of crystalline/amorphous ultrathin MnO2 nanosheets electrode for high-performance flexible micro-supercapacitors

Zhipeng Ma et al.

Summary: Ultrathin MnO2 nanosheets with high specific surface area were prepared via a simple reaction with surfactant assistance. They exhibited remarkable electrochemical performance and mechanical flexibility. In a three-electrode system with NaSO4 electrolyte, the nanosheets showed significant specific capacitance and long-term stability. In a flexible all-solid-state MnO2 symmetry micro-supercapacitor with sodium alginate bio-hydrogel as electrolyte, the nanosheets demonstrated high areal capacitance and energy density.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

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Review Chemistry, Applied

A review on the current research on microwave processing techniques applied to graphene-based supercapacitor electrodes: An emerging approach beyond conventional heating

Rajesh Kumar et al.

Summary: This article introduces the advantages of microwave heating in the processing of graphene-based electrode materials and provides a systematic overview of recent research on microwave-assisted processing, focusing on the preparation and modification of graphene derivatives for supercapacitors. Finally, the major challenges and future perspectives for microwave-assisted processing of graphene-based materials are summarized.

JOURNAL OF ENERGY CHEMISTRY (2022)

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Article Energy & Fuels

Co(OH)F@CoP/CC core-shell nanoarrays for high-performance supercapacitors

Didi Liu et al.

Summary: The novel composite Co(OH)F@CoP/CC was synthesized through hydrothermal method and phosphating process, and showed excellent electrochemical performance and cycling stability, making it a promising electrode material for supercapacitors.

JOURNAL OF ENERGY STORAGE (2022)

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Article Energy & Fuels

Facile synthesis and incomplete sulfidation of nickel-cobalt-aluminum ternary layered hydroxide binder-free electrode with enhanced supercapacitor properties

Kailin Li et al.

Summary: Layered transition metal hydroxide is a potential energy storage material with large specific surface area, adjustable composition, and abundant active components. The performance of the binder-free electrodes in the study showed that the ternary LDH electrode had better electrochemical properties than the binary one, and the partially sulfide Ni1Co2S/Ni electrode exhibited the optimal performance. The hybrid supercapacitor device assembled with Ni1Co2S as the positive electrode and active graphene as the negative electrode displayed high energy density, good rate capability, and cycling stability.

JOURNAL OF ENERGY STORAGE (2022)

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Article Energy & Fuels

Engineering active sites on nitrogen-doped carbon nanotubes/cobaltosic oxide heterostructure embedded in biotemplate for high-performance supercapacitors

Kailin Li et al.

Summary: The easy agglomeration of carbon nanotubes and the waste generated by chemical vapor deposition pose great pollution risks and hinder the usage of CNTs. In this study, a novel environmental-friendly electrode material was successfully fabricated, which exhibited excellent electrochemical performance and potential application in supercapacitors.

JOURNAL OF ENERGY STORAGE (2022)

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Article Chemistry, Physical

On-chip high-energy interdigital micro-supercapacitors with 3D nanotubular array electrodes

Fei Li et al.

Summary: Micro-supercapacitors (MSCs) assembled with intersecting nanoflake-built MnO2 NTAs exhibit high energy density, excellent cycling stability, and desirable flexibility due to their large electroactive surface area, structural stability, wettability, and short transport path of ions and electrons. The output voltage and capacitance of the MSCs can be easily controlled by rational interconnection for practical use. This novel strategy for fabricating high-energy and flexible 3D NTA-based MSCs opens up a new avenue for portable and wearable electronic devices.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

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Article Chemistry, Multidisciplinary

In situ growth of laser-induced graphene micro-patterns on arbitrary substrates

Ednan Joanni et al.

Summary: In this article, we present a new laser processing method that combines in situ graphitization of polyimide with simultaneous transfer of graphene patterns onto various substrates. The synthesis conditions are similar to those of the well-known laser-induced graphene method. This approach involves enclosing polyimide sheets between microscope glass slides and has successfully generated graphene patterns on glass and PDMS substrates, as well as graphene decorated with metals and oxides. To illustrate its usefulness, this method was applied to the fabrication of hybrid supercapacitors which exhibited excellent electrochemical performance.

NANOSCALE (2022)

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Article Chemistry, Physical

Defective mesoporous carbon/MnO2 nanocomposite as an advanced electrode material for supercapacitor application

Nourali Mohammadi et al.

Summary: A novel nanocomposite based on DMC and MnO2 exhibited high specific capacitance, good rate performance, and cycling stability. Structural analyses confirmed the excellent performance of the nanocomposite material.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

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Article Chemistry, Physical

Electrochemical and magnetic properties of perovskite type RMnO3 (R = La, Nd, Sm, Eu) nanofibers

Quanli Hu et al.

Summary: Perovskite type rare earth manganates RMnO3 (LaMnO3, NdMnO3, SmMnO3, and EuMnO3) nanofibers were fabricated via electrospinning process, showing different crystal structures and optical properties. As supercapacitor electrode materials, RMnO3 nanofibers demonstrated good electrochemical performance, indicating feasible applications in supercapacitor field.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

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Article Chemistry, Multidisciplinary

Constructing Co(OH)F Nanorods@NiCo-LDH Nanocages Derived from ZIF-67 for High-Performance Supercapacitors

Yezeng He et al.

Summary: A multi-dimensional Co(OH)F@NiCo-LDH composite with layered nanocages has been successfully synthesized, exhibiting excellent performance in supercapacitors due to its subtle structural design, including high specific capacitance, desirable rate performance, and outstanding cycling stability.

ADVANCED MATERIALS INTERFACES (2021)

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Article Energy & Fuels

Carbon-coated NiMn layered double hydroxides/Ni3S2 nanocomposite for high performance supercapacitors

Yezeng He et al.

Summary: The study successfully prepared C/NiMn-LDH/Ni3S2 electrode material, which maintained a high capacitance even after 5000 cycles, and the two-electrode device assembled with activated carbon showed excellent specific energy.

JOURNAL OF ENERGY STORAGE (2021)

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Article Materials Science, Multidisciplinary

Copper-doped α-MnO2 nano-sphere: metamaterial for enhanced supercapacitor and microwave shielding applications

Dheeraj Mondal et al.

Summary: Alpha-MnO2 nanoparticles doped with increasing copper concentration showed a significant dielectric constant and strong electromagnetic interference shielding effectiveness. Additionally, cyclic voltammetry and galvanostatic charge-discharge measurements demonstrated high charge retention and enhanced capacitance value.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

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Review Materials Science, Multidisciplinary

A review on mechanistic understanding of MnO2 in aqueous electrolyte for electrical energy storage systems

Jaewook Shin et al.

INTERNATIONAL MATERIALS REVIEWS (2020)

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Article Chemistry, Physical

Facile synthesis of Eu-doped CaTiO3 and their enhanced supercapacitive performance

S. Anjelin Ursula Portia et al.

IONICS (2020)

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Article Chemistry, Physical

Oxygen-Deficient Blue TiO2 for Ultrastable and Fast Lithium Storage

Zhongkai Hao et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Energy & Fuels

Synthesis of self-assembled micro/nano structured manganese carbonate for high performance, long lifespan asymmetric supercapacitors and investigation of atomic-level intercalation properties of OH- ions via first principle calculation

M. Karuppaiah et al.

JOURNAL OF ENERGY STORAGE (2020)

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Article Chemistry, Physical

Highly efficient mesoporous MnO2 catalysts for the total toluene oxidation: Oxygen-Vacancy defect engineering and involved intermediates using in situ DRIFTS

Shengpeng Mo et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

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Article Energy & Fuels

Honeycomb-like open-edged reduced-graphene-oxide-enclosed transition metal oxides (NiO/Co3O4) as improved electrode materials for high-performance supercapacitor

Rajesh Kumar et al.

JOURNAL OF ENERGY STORAGE (2020)

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Article Nanoscience & Nanotechnology

Activating the Highly Reversible Mo4+/Mo5+ Redox Couple in Amorphous Molybdenum Oxide for High-Performance Supercapacitors

Xiang Cai et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Engineering, Electrical & Electronic

Synthesis of Eu-modified luminescent Titania nanotube arrays and effect of voltage on morphological, structural and spectroscopic properties

Baoze Su et al.

MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING (2020)

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Review Chemistry, Physical

Defect Engineering in Manganese-Based Oxides for Aqueous Rechargeable Zinc-Ion Batteries: A Review

Ting Xiong et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Nanoscience & Nanotechnology

Hierarchical Nickel-Cobalt Phosphide/Phosphate/Carbon Nanosheets for High-Performance Supercapacitors

Xiaolong Zhang et al.

ACS APPLIED NANO MATERIALS (2020)

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Article Chemistry, Physical

Boosting the interface reaction activity and kinetics of cobalt molybdate by phosphating treatment for aqueous zinc-ion batteries with high energy density and long cycle life

Yuenian Shen et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Review Chemistry, Physical

Oxygen Defects in Promoting the Electrochemical Performance of Metal Oxides for Supercapacitors: Recent Advances and Challenges

Xiyue Zhang et al.

SMALL METHODS (2020)

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Review Chemistry, Physical

Strategies and insights towards the intrinsic capacitive properties of MnO2 for supercapacitors: Challenges and perspectives

Wei Guo et al.

NANO ENERGY (2019)

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Article Chemistry, Multidisciplinary

Experimental and Theoretical Investigation of the Effect of Oxygen Vacancies on the Electronic Structure and Pseudocapacitance of MnO2

Lijin Yan et al.

CHEMSUSCHEM (2019)

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Article Electrochemistry

Homogeneous reduced graphene oxide supported NiO-MnO2 ternary hybrids for electrode material with improved capacitive performance

Rajesh Kumar et al.

ELECTROCHIMICA ACTA (2019)

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Article Chemistry, Multidisciplinary

High-Stability MnOx Nanowires@C@MnOx Nanosheet Core-Shell Heterostructure Pseudocapacitance Electrode Based on Reversible Phase Transition Mechanism

Zhipeng Ma et al.

SMALL (2019)

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Article Chemistry, Physical

Facile and fast microwave-assisted formation of reduced graphene oxide-wrapped manganese cobaltite ternary hybrids as improved supercapacitor electrode material

Rajesh Kumar et al.

APPLIED SURFACE SCIENCE (2019)

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Article Chemistry, Physical

Enhanced electrochemical performance of Sn-doped MnO2 and study on morphology evolution

Binbin Lan et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2019)

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Article Engineering, Environmental

Tuning MnO2 to FeOOH replicas with bio-template 3D morphology as electrodes for high performance asymmetric supercapacitors

Kailin Li et al.

CHEMICAL ENGINEERING JOURNAL (2019)

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Article Chemistry, Physical

All ternary metal selenide nanostructures for high energy flexible charge storage devices

Jayaraman Balamurugan et al.

NANO ENERGY (2019)

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Article Chemistry, Inorganic & Nuclear

Investigation of the structural, optical and electrical properties of Ca2+ doped CuCoO2 nanosheets

Zijuan Du et al.

DALTON TRANSACTIONS (2019)

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Article Chemistry, Multidisciplinary

Assembling a double shell on a diatomite skeleton ternary complex with conductive polypyrrole for the enhancement of supercapacitors

Kailin Li et al.

CHEMICAL COMMUNICATIONS (2019)

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Article Chemistry, Multidisciplinary

Hierarchical Ni-Mo-S and Ni-Fe-S Nanosheets with Ultrahigh Energy Density for Flexible All Solid-State Supercapacitors

Jayaraman Balamurugan et al.

ADVANCED FUNCTIONAL MATERIALS (2018)

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Article Chemistry, Physical

Role of oxygen vacancies in photocatalytic water oxidation on ceria oxide: Experiment and DFT studies

Yong-Chao Zhang et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

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Review Thermodynamics

Recent advances in the synthesis and modification of carbon-based 2D materials for application in energy conversion and storage

Rajesh Kumar et al.

PROGRESS IN ENERGY AND COMBUSTION SCIENCE (2018)

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Article Chemistry, Multidisciplinary

Flexible Solid-State Asymmetric Supercapacitors Based on Nitrogen-Doped Graphene Encapsulated Ternary Metal-Nitrides with Ultralong Cycle Life

Jayaraman Balamurugan et al.

ADVANCED FUNCTIONAL MATERIALS (2018)

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Article Materials Science, Multidisciplinary

Fabrication of high-performance metal ion doped iron oxide electrode for supercapacitor applications through a novel platform

Mustafa Aghazadeh et al.

MATERIALS RESEARCH EXPRESS (2017)

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Review Chemistry, Multidisciplinary

Controlling cation segregation in perovskite-based electrodes for high electro-catalytic activity and durability

Yifeng Li et al.

CHEMICAL SOCIETY REVIEWS (2017)

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Article Chemistry, Physical

The effect of manganese vacancy in birnessite-type MnO2 on room-temperature oxidation of formaldehyde in air

Jinlong Wang et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2017)

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Article Chemistry, Physical

Enhanced photocatalytic degradation of methylene blue and methyl orange by ZnO:Eu nanoparticles

L. V. Trandafilovic et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2017)

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Article Nanoscience & Nanotechnology

Well-Ordered Oxygen-Deficient CoMoO4 and Fe2O3 Nanoplate Arrays on 3D Graphene Foam: Toward Flexible Asymmetric Supercapacitors with Enhanced Capacitive Properties

Kai Chi et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

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Article Nanoscience & Nanotechnology

Construction of Hierarchical α-MnO2 Nanowires@Ultrathin δ-MnO2 Nanosheets Core-Shell Nanostructure with Excellent Cycling Stability for High-Power Asymmetric Supercapacitor Electrodes

Zhipeng Ma et al.

ACS APPLIED MATERIALS & INTERFACES (2016)

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Article Chemistry, Physical

Facile synthesis of vanadium nitride/nitrogen-doped graphene composite as stable high performance anode materials for supercapacitors

Jayaraman Balamurugan et al.

JOURNAL OF POWER SOURCES (2016)

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Article Materials Science, Multidisciplinary

High visible light photocatalytic activity of Eu-doped MoO3 nanobelts synthesized by hydrothermal method

Anukorn Phuruangrat et al.

MATERIALS LETTERS (2016)

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Article Chemistry, Physical

Facile synthesis of 3D hierarchical N-doped graphene nanosheet/cobalt encapsulated carbon nanotubes for high energy density asymmetric supercapacitors

Jayaraman Balamurugan et al.

JOURNAL OF MATERIALS CHEMISTRY A (2016)

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Article Engineering, Environmental

Tetracycline degradation in aquatic environment by highly porous MnO2 nanosheet assembly

Prateeksha Mahamallik et al.

CHEMICAL ENGINEERING JOURNAL (2015)

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Article Electrochemistry

Cerium-doped porous K-birnessite manganese oxides microspheres as pseudocapacitor electrode material with improved electrochemical capacitance

Guiling Wang et al.

ELECTROCHIMICA ACTA (2015)

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Review Materials Science, Multidisciplinary

Engineering of MnO2-based nanocomposites for high-performance supercapacitors

Jian-Gan Wang et al.

PROGRESS IN MATERIALS SCIENCE (2015)

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Article Chemistry, Physical

Spatially Confined MnO2 Nanostructure Enabling Consecutive Reversible Charge Transfer from Mn(IV) to Mn(II) in a Mixed Pseudocapacitor-Battery Electrode

Yu-Ting Weng et al.

ADVANCED ENERGY MATERIALS (2015)

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Article Chemistry, Physical

Enhanced electrochemical performance by facile oxygen vacancies from lower valence-state doping for ramsdellite-MnO2

Chi Chen et al.

JOURNAL OF MATERIALS CHEMISTRY A (2015)

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Review Chemistry, Physical

MnO2-based nanostructures for high-performance supercapacitors

Ming Huang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2015)

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Article Nanoscience & Nanotechnology

Tremendous Effect of the Morphology of Birnessite-Type Manganese Oxide Nanostructures on Catalytic Activity

Jingtao Hou et al.

ACS APPLIED MATERIALS & INTERFACES (2014)

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Review Chemistry, Multidisciplinary

Flexible Energy-Storage Devices: Design Consideration and Recent Progress

Xianfu Wang et al.

ADVANCED MATERIALS (2014)

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Article Electrochemistry

Electrochemical fabrication of a porous network MnO2/poly(5-cyanoindole) composite and its capacitance performance

Weiqiang Zhou et al.

ELECTROCHIMICA ACTA (2014)

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Article Chemistry, Physical

Enhanced electrochemical properties of cobalt doped manganese dioxide nanowires

Byung Chul Kim et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2014)

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Article Chemistry, Physical

Synthesis and property of novel MnO2@polypyrrole coaxial nanotubes as electrode material for supercapacitors

Wei Yao et al.

JOURNAL OF POWER SOURCES (2013)

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Article Chemistry, Physical

Experimental and Computational Investigation of Effect of Sr on NO Oxidation and Oxygen Exchange for La1-xSrxCoO3 Perovskite Catalysts

Sang Ok Choi et al.

ACS CATALYSIS (2013)

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Review Chemistry, Multidisciplinary

A review of electrode materials for electrochemical supercapacitors

Guoping Wang et al.

CHEMICAL SOCIETY REVIEWS (2012)

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Review Chemistry, Multidisciplinary

Manganese oxide-based materials as electrochemical supercapacitor electrodes

Weifeng Wei et al.

CHEMICAL SOCIETY REVIEWS (2011)

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Article Chemistry, Physical

Recent advances in making nano-sized TiO2 visible-light active through rare-earth metal doping

Sonny Bingham et al.

JOURNAL OF MATERIALS CHEMISTRY (2011)

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Review Energy & Fuels

Improvement in Catalytic Performance of Carbon Nanotube-supported Metal Nanoparticles by Coverage with Silica Layers

Sakae Takenaka et al.

JOURNAL OF THE JAPAN PETROLEUM INSTITUTE (2011)

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Review Chemistry, Physical

Materials for electrochemical capacitors

Patrice Simon et al.

NATURE MATERIALS (2008)

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Oxygen-vacancy europium-doped MnO2 ultrathin nanosheets used as asymmetric supercapacitors

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