期刊
CHEMISTRYSELECT
卷 8, 期 13, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.202204776
关键词
copper catalyst; cycloalkane oxidation; Fenton-like reaction; H2O2; mild condition
The copper-catalyzed cycloalkane oxidation using H2O2 as the oxidant was studied under mild conditions. Various factors affecting the catalytic activity of different copper catalysts were elucidated, including the geometry of the copper complex and coordinated anions. The in-situ generated copper(II) complex with trigonal bipyramidal geometry showed higher yields in the cyclohexane oxidation compared to other Cu2+ species.
Copper-catalyzed cycloalkane oxidation using H2O2 as an oxidant was investigated under mild conditions. The copper catalysts studied in this work ranged from commercially-available copper(II) salts to copper(II) complexes containing polypyridyl ligands. Various factors that affected catalytic activity of copper catalysts were elucidated. It was found that geometry of the copper complex in solution and coordinated anions played important roles in catalytic activity. The copper(II) complex generated in-situ by mixing Cu(OAc)(2) and TMPA ligand (TMPA=tris(2-pyridylmethyl)amine) adopted trigonal bipyramidal geometry and was competent to catalyze cyclohexane oxidation with higher yields, compared to those of other Cu2+ species used in this work. The optimal catalytic condition was achieved using 1.0 % mol of Cu(OAc)(2)/TMPA and 10 equivalents of H2O2 with respect to cyclohexane in CH3CN at 33-35 degrees C for 3 hours, resulting in the total product yield of 44 %. Moreover, since cyclohexyl hydroperoxide was detected as a major product, the Fenton-like mechanism via one electron process was proposed as a plausible mechanism in this cycloalkane oxidation. In addition, our catalytic system was further demonstrated to be applicable for oxidation of various cycloalkane substrates with moderate yields and relatively short time.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据