期刊
CHEMISTRYSELECT
卷 8, 期 12, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.202300309
关键词
Fluorine; Squaraine dyes; Photostability
We studied the photodegradation of non-fluorinated benzoindolenine-based SQ dyes with low photostability in solution and proposed a hypothesis to improve their photostability. The replacement of hydrogen atoms with fluorine atoms or methylation of the oxygen anions resulted in improved photostability. Furthermore, the synthesized SQ dyes with bulky fluorine-containing anions provided a higher Voc for organic photovoltaics.
We have elucidated the details of the photodegradation of non-fluorinated benzoindolenine-based SQ dyes with low photostability in solution and proposed a hypothesis to improve their photostability. Based on the results, replacing all the hydrogen atoms on the benzoindolenine ring with fluorine atoms or methylation of the oxygen anions of the non-fluorinated benzoindolenine SQ dye resulted in improvement of photostability. Furthermore, a preliminary investigation of the synthesized SQ dyes for organic photovoltaics revealed that the O-methylated SQ dye with bulky fluorine-containing anions provided a much higher V-oc than similar benzoindolenine-based SQ dyes.
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