期刊
COATINGS
卷 13, 期 5, 页码 -出版社
MDPI
DOI: 10.3390/coatings13050921
关键词
ZnO nanoparticles; beta-phase PVDF; ZnO@PVDF nanocomposite; piezoelectric effect; self-powered photodetector
In this study, a self-powered ultraviolet photodetector based on a p-n junction of ZnO@Polyvinylidene fluoride (PVDF) and poly [9,9-dioctylfluorene-co-N-[4-(3-methylpropyl)]-diphenylamine] (TFB) was developed by integrating an in-situ piezoelectric effect into the photoactive region. The fabricated ZnO@fiPVDF nanocomposite with strong piezoelectricity exhibited improved on/off ratio, detectivity, and response speed under 365-nm UV illumination. The device also showed stable operation over 1000 continuous on/off cycles and long-lasting photostability when exposed to UV light.
In this study, an in-situ piezoelectric effect is integrated into a photoactive region to develop a self-powered ultraviolet photodetector based on a p-n junction of ZnO@Polyvinylidene fluoride (PVDF) and poly [9,9-dioctylfluorene-co-N-[4-(3-methylpropyl)]-diphenylamine] (TFB). A ZnO@fiPVDF nanocomposite is fabricated using PVDF with the fi-phase as the polymer matrix and ZnO nanoparticles as fillers. The strong piezoelectricity of fi-PVDF can facilitate the separation and transport of photogenerated electrons in the depletion area and considerably reduce the dark current when the device is polarized with an external bias, resulting in an improvement in the on/off ratio and detectivity. Under 365-nm UV illumination, the as-fabricated device exhibits a high detectivity of 4.99 x 10(11) Jones, an excellent on/off ratio (up to 2.75 x 10(4)), and a fast response speed of 46/53 ms (rise/fall times). The device functions stably over approximately 1000 continuous on/off cycles and exhibits extremely long-lasting photostability when exposed to UV light. The findings demonstrate a promising strategy for enhancing the performance of photodetectors for industrial applications.
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