Designing TM-N2O2Cx single-atom catalysts for electrocatalytic CO2 reduction

Article Chemistry, Multidisciplinary

Liquid Fluxional Ga Single Atom Catalysts for Efficient Electrochemical CO2 Reduction

Zedong Zhang et al.

Summary: Downsizing the active center of the main group element gallium to the atomic level enables efficient CO2 reduction with high selectivity and stability.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

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Article Nanoscience & Nanotechnology

Dual-Atom Metal and Nonmetal Site Catalyst on a Single Nickel Atom Supported on a Hybridized BCN Nanosheet for Electrochemical CO2 Reduction to Methane: Combining High Activity and Selectivity

Yuqin Zhang et al.

Summary: Using density functional theory calculations, this study investigated the electrocatalytic performance of a single transition metal (TM) atom embedded into a defective nanosheet for carbon dioxide reduction reaction (CO2RR). The results showed that the TM atom coordinated with nonmetal atoms could activate CO2 and stabilize key intermediates, resulting in selective CO2 reduction to hydrocarbons.

ACS APPLIED MATERIALS & INTERFACES (2022)

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Review Chemistry, Physical

Interfacial Electrolyte Effects on Electrocatalytic CO2 Reduction

Bangwei Deng et al.

Summary: This review focuses on discussing the role and effects of electrolytes on CO2RR, including their compositions and local chemical environment. In-depth investigations on the detection of intermediates during the catalytic reactions are also included. The fundamental understanding of interfacial electrolyte effects is emphasized for maximizing and balancing the catalytic performance of CO2RR.

ACS CATALYSIS (2022)

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Review Chemistry, Physical

Advances in studies of the structural effects of supported Ni catalysts for CO2 hydrogenation: from nanoparticle to single atom catalyst

Zhitao Zhang et al.

Summary: Supported Ni catalysts have great potential in CO2 hydrogenation, with products including methane, carbon monoxide, methanol, and formic acid. The electronic and geometric structures of the catalyst significantly affect the activity and selectivity of the reaction, with selectivity depending on the support. To enhance activity, stability, and tunable selectivity, structure control of the Ni catalyst is crucial.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

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Review Chemistry, Multidisciplinary

Single Atom Catalysts for Selective Methane Oxidation to Oxygenates

Pawan Kumar et al.

Summary: Direct conversion of methane to C1-2 liquid oxygenates is a promising approach to reduce global warming and transform carbon into transportable chemicals. However, current methods are energy and capital intensive. Developing catalysts that can selectively break C-H bonds of methane at mild conditions is crucial for commercialization.

ACS NANO (2022)

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Article Chemistry, Physical

Novel Insights into Sb-Cu Catalysts for Electrochemical Reduction of CO2

Juqin Zeng et al.

Summary: In this study, a SbCu2O material was synthesized via one-pot microwave-assisted solvothermal route and its catalytic performance in electrochemical reduction of CO2 was investigated. The Sb-Cu2O bimetallic catalyst exhibited high CO selectivity and good stability.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

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Article Engineering, Chemical

Single atomic Cu-Anchored 2D covalent organic framework as a nanoreactor for CO2 capture and in-situ conversion: A computational study

Ling Huang et al.

Summary: This study reports a novel single atomic Cu-anchored covalent organic framework with Kagome lattice configuration for the capture and conversion of CO2. The hex-Cu kgm-COF exhibits high CO2 adsorption capacity, selectivity, and excellent hydrogenation activity in forming CH3OH and CH4.

CHEMICAL ENGINEERING SCIENCE (2022)

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Article Chemistry, Physical

Single site catalyst with enzyme-mimic micro-environment for electroreduction of CO2

Chang Long et al.

Summary: Single site catalysts provide a unique platform for mimicking natural enzymes, but current research focuses more on preparing structural and functional models rather than considering the local chemical environment. A Co-centered porphyrinic polymer was reported, with a triazole linker forming hydrogen bonds with the CoN4 site to enhance the electrocatalytic reduction of CO2.

NANO RESEARCH (2022)

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Review Materials Science, Multidisciplinary

Emerging dual-atomic-site catalysts for electrocatalytic CO2 reduction

Na Qiu et al.

Summary: This review highlights recent advances in dual-atomic-site catalysts (DASCs) for enhancing CO2 reduction reaction (CO2RR). The classification, synthesis, and identification of DASCs are provided, as well as the catalytic applications and structure-activity relationship in CO2RR. Opportunities and challenges for future DASCs design are proposed.

SCIENCE CHINA-MATERIALS (2022)

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Article Materials Science, Multidisciplinary

Theory-oriented screening and discovery of advanced energy transformation materials in electrocatalysis

Hongyu Jing et al.

Summary: This review comprehensively outlines the latest progress of theory-guided design of advanced energy transformation materials, with a focus on the study of single atoms in various power devices and electrocatalytic conversion reactions related to energy. The electronic structure, interaction mechanism, and reaction activation path are discussed, and experimental synthesis strategies, structural recognition, and electrocatalytic performance are determined. Some viewpoints into the current issues and future design concept are also provided.

ADVANCED POWDER MATERIALS (2022)

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Review Chemistry, Applied

Single atom-based catalysts for electrochemical CO2 reduction

Qian Sun et al.

Summary: This review summarizes the fabrication, application, and characterization methods of single-atom catalysts (SACs) and molecular catalysts for CO2 electroreduction. Strategies for overcoming the issues of particle agglomeration, low metal loading, and difficulty in large-scale production of SACs, as well as the moderate activity, selectivity, and stability of molecular catalysts, are highlighted. Future directions for the development of SACs and molecular catalysts are pointed out.

CHINESE JOURNAL OF CATALYSIS (2022)

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Article Chemistry, Physical

A Mn single atom catalyst with Mn-N2O2 sites integrated into carbon nanosheets for efficient electrocatalytic CO2 reduction

Wenfei Dong et al.

Summary: The electrocatalytic reduction of CO2 using electricity produced from renewable resources is an effective strategy for reducing CO2 emissions and promoting sustainable energy development. This study successfully synthesized a low Mn-content single-atom catalyst with efficient electrocatalytic performance for the CO2 reduction reaction.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

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Article Chemistry, Physical

Efficient Electrocatalytic CO2 Reduction to C2+ Alcohols at Defect-Site-Rich Cu Surface

Zhengxiang Gu et al.

Summary: A rational strategy was demonstrated to achieve a high faradaic efficiency towards C2+ alcohols by constructing copper catalysts with stepped sites in a CO-rich environment. The defect-site-rich copper catalyst enabled the formation of C2+ alcohols with partial current densities of > 100 mA.cm(-2) and achieved a stable alcohol faradaic efficiency of around 60% during a continuous 30-hour operation.

JOULE (2021)

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Review Chemistry, Physical

Electrochemical CO2 Reduction to Ethanol with Copper-Based Catalysts

Dilan Karapinar et al.

Summary: This Review highlights the importance and challenges of electrochemical CO2 reduction for ethanol production, categorizing and evaluating the performance of copper-based catalysts to aid in the design of more efficient catalysts for selective ethanol formation.

ACS ENERGY LETTERS (2021)

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Editorial Material Chemistry, Multidisciplinary

Single-Atom Catalysts

Manoj B. Gawande et al.

SMALL (2021)

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Article Physics, Applied

Carbon‐Supported Single‐Atom Catalysts: Carbon‐Supported Single Metal Site Catalysts for Electrochemical CO 2 Reduction to CO and Beyond (Small 16/2021)

Yuanzhi Zhu et al.

Small (2021)

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Article Chemistry, Physical

Carbon nanosheets supporting Ni-N3S single-atom sites for efficient electrocatalytic CO2 reduction

Xiaoyi Zhao et al.

Summary: In this study, Ni single atoms coordinated with N and S were successfully prepared for CO2 reduction using a novel method. The resulting porous carbon nanosheets showed high CO selectivity and current density, attributed to their sheet-like morphology and rich N/S-coordinated Ni atoms.

CARBON (2021)

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Editorial Material Multidisciplinary Sciences

Stabilization of single atom catalysts

Lei Zhang et al.

SCIENCE BULLETIN (2021)

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Review Chemistry, Physical

Electrochemical CO2 reduction to ethanol: from mechanistic understanding to catalyst design

Tu N. Nguyen et al.

Summary: Electrochemical reduction of CO2 to ethanol is a promising solution for greenhouse gas mitigation and utilizing intermittent renewable energy sources. Challenges lie in low energy efficiency, inferior stability, and discouraging selectivity in current electrocatalytic systems.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Review Physics, Multidisciplinary

Design of Single Atom Catalysts

Zuran Yu et al.

Summary: This review highlights the crucial role of computational modeling based on density functional theory in studying the catalytic mechanism of single-atom catalysts. It also introduces computational methods for analyzing the electronic structures and catalytic performance of SACs, as well as the use of descriptors in their computational design. Future advances in computational methods are expected to help identify highly effective SACs for various reactions.

ADVANCES IN PHYSICS-X (2021)

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Review Chemistry, Multidisciplinary

Electrode Materials Engineering in Electrocatalytic CO2 Reduction: Energy Input and Conversion Efficiency

Rong-Bin Song et al.

ADVANCED MATERIALS (2020)

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Article Nanoscience & Nanotechnology

Promotion of CO2 Electrochemical Reduction via Cu Nanodendrites

Minfang Wu et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Chemistry, Multidisciplinary

Accelerating CO2 Electroreduction to CO Over Pd Single-Atom Catalyst

Qun He et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Prospects of Heterogeneous Hydroformylation with Supported Single Atom Catalysts

Jonas Amsler et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Review Chemistry, Multidisciplinary

Stability and Degradation Mechanisms of Copper-Based Catalysts for Electrochemical CO2 Reduction

Stefan Popovic et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Review Chemistry, Multidisciplinary

Chemical Synthesis of Single Atomic Site Catalysts

Shufang Ji et al.

CHEMICAL REVIEWS (2020)

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Article Chemistry, Physical

Highly efficient utilization of single atoms via constructing 3D and free-standing electrodes for CO2 reduction with ultrahigh current density

Hengpan Yang et al.

NANO ENERGY (2020)

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Review Chemistry, Multidisciplinary

Single-Atom Catalysts for Electrocatalytic Applications

Qiaoqiao Zhang et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Mesoporous PdAg Nanospheres for Stable Electrochemical CO2 Reduction to Formate

Yuan Zhou et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Single-Atom Electrocatalysts from Multivariate Metal-Organic Frameworks for Highly Selective Reduction of CO2at Low Pressures

Long Jiao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Multidisciplinary Sciences

Oxygen-Reconstituted Active Species of Single-Atom Cu Catalysts for Oxygen Reduction Reaction

Liu Yang et al.

RESEARCH (2020)

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Review Chemistry, Physical

Densely Populated Single Atom Catalysts

Jiabin Wu et al.

SMALL METHODS (2020)

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Review Chemistry, Multidisciplinary

Electrochemical CO2 Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design

Md Golam Kibria et al.

ADVANCED MATERIALS (2019)

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Review Chemistry, Multidisciplinary

Progress and Perspectives of Electrochemical CO2 Reduction on Copper in Aqueous Electrolyte

Stephanie Nitopi et al.

CHEMICAL REVIEWS (2019)

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Article Chemistry, Physical

Electrochemical CO2 Reduction: Classifying Cu Facets

Alexander Bagger et al.

ACS CATALYSIS (2019)

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Article Chemistry, Multidisciplinary

Ni Single Atom Catalysts for CO2 Activation

Marie-Mathilde Millet et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Chemistry, Physical

Electrochemical reduction of CO2 by single atom catalyst TM-TCNQ monolayers

Jin-Hang Liu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Review Chemistry, Physical

Rational catalyst and electrolyte design for CO2 electroreduction towards multicarbon products

Dunfeng Gao et al.

NATURE CATALYSIS (2019)

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Article Chemistry, Physical

Electrocatalytic reduction of CO2 by two-dimensional transition metal porphyrin sheets

Jin-Hang Liu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Article Multidisciplinary Sciences

Unveiling the high-activity origin of single-atom iron catalysts for oxygen reduction reaction

Liu Yang et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2018)

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Single-atom cobalt electrocatalysts for foldable solid-state Zn-air battery

Liu Yang et al.

NANO ENERGY (2018)

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Article Chemistry, Multidisciplinary

Efficient and Selective Electroreduction of CO2 by Single-Atom Catalyst Two-Dimensional TM-Pc Monolayers

Jin-Hang Liu et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2018)

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Article Chemistry, Physical

Insight into Electrochemical CO2 Reduction on Surface-Molecule Mediated Ag Nanoparticles

Cheonghee Kim et al.

ACS CATALYSIS (2017)

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Article Chemistry, Physical

CO2 Electroreduction Performance of Phthalocyanine Sheet with Mn Dimer: A Theoretical Study

Haoming Shen et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2017)

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Article Chemistry, Applied

Barriers of Electrochemical CO2 Reduction on Transition Metals

Chuan Shi et al.

ORGANIC PROCESS RESEARCH & DEVELOPMENT (2016)

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Article Chemistry, Physical

Electrolysis of water on (oxidized) metal surfaces

J Rossmeisl et al.

CHEMICAL PHYSICS (2005)

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Article Chemistry, Physical

Origin of the overpotential for oxygen reduction at a fuel-cell cathode

JK Norskov et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2004)

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Article Chemistry, Physical

From molecules to solids with the DMol3 approach

B Delley

JOURNAL OF CHEMICAL PHYSICS (2000)

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Designing TM-N2O2Cx single-atom catalysts for electrocatalytic CO2 reduction

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