期刊
CHEMCATCHEM
卷 7, 期 15, 页码 2370-2376出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201500308
关键词
nanostructures; nickel; oxidation; photochemistry; water chemistry
资金
- National Natural Science Foundation of China [21173105, 21172098]
- National Fundamental Scientific Talented Person Training Fund [J1103307]
Three -NiO nanocompounds of different morphology, with nanorods, nanowires, and nanoplates, were synthesized by controlling the ratio of reactants and temperature. The shape and structure of the nanocompounds were confirmed by SEM, XRD, FTIR, Raman spectroscopy, energy-dispersive X-ray spectroscopy, BET, and X-ray photoelectron spectroscopy (XPS) analysis. These compounds were examined as catalysts in photocatalytic water oxidation with [Ru(2,2-bipyridine)(3)](2+) and S2O82- as a photosensitizer and a sacrificial oxidant, respectively. All of the samples exhibit high turnover frequencies and perfect stability in slightly alkaline conditions. A characteristic peak at around E=0.95V versus Ag/AgCl assigned to a Ni3+ species was detected by cyclic voltammetry, which suggests that a high-valent nickel species may be responsible for water oxidation. The surface properties of the -NiO nanorods also remain unchanged after examination by XPS before and after the photocatalytic reaction.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据