Leaching of Waste Pharmaceutical Blister Package Aluminium in Sulphuric Acid Media

In this study, the leaching behaviour of aluminium from waste pharmaceutical blister packages (WPBs) is investigated in sulphuric acid media to build future strategies for aluminium recycling from this non-recycled waste fraction. The results suggest that in hydrometallurgical recycling, passivation of aluminium during leaching can be mitigated in dilute sulphuric acid solutions (0.25 M), at high temperatures (60-80 degrees C) and specifically with H2O2 addition. With this system, 100% extraction was achieved within five hours under optimized conditions (H2SO4 = 0.25 M, T = 80 degrees C, H2O2 = 1.25 vol.%). The leaching mechanism is suggested to be based on electrochemical dissolution of metallic aluminium oxidized by H+ or H2O2, followed by fast passivation by Al2O3 and consequent chemical dissolution of Al2O3 at slower kinetics. The calculated activation energy (similar to 69 kJ/mol) suggests that the leaching reaction is controlled by the chemical or electrochemical reaction step rather than diffusion. By WPB leaching, an aluminium sulphate solution could be obtained, suitable for further aluminium sulphate crystallization. This may provide a potential route for the valorisation of aluminium from a currently overlooked waste fraction of pharmaceutical blister packages.

Automated summary

This study investigates the leaching behavior of aluminium from waste pharmaceutical blister packages in sulphuric acid media in order to develop strategies for aluminium recycling. The results indicate that passivation of aluminium during leaching can be reduced by using dilute sulphuric acid solutions at high temperatures and with H2O2 addition. The leaching mechanism involves electrochemical dissolution of aluminium oxidized by H+ or H2O2, followed by fast passivation by Al2O3 and subsequent chemical dissolution of Al2O3. The calculated activation energy suggests that the leaching reaction is controlled by the chemical or electrochemical reaction step. By leaching the waste, an aluminium sulphate solution can be obtained for further valorization.