期刊
METALS
卷 13, 期 3, 页码 -出版社
MDPI
DOI: 10.3390/met13030543
关键词
electric vehicle; lithium iron phosphate; acid leaching; precipitation; solvent extraction; ionic exchange; ionic liquids; deep eutectic solvents
The exponential growth of electric and hybrid vehicles in the last five years has led to a potential waste problem with the end-of-life of their batteries. Li-ion batteries for vehicles are made from natural resources such as Li, Fe, Al, Cu, Co, Mn, and P. Among them, LiFePO4 cathode materials have demonstrated advantages in various aspects. The recycling of these batteries can be accomplished through pyrometallurgy or hydrometallurgy, with the latter being more advantageous due to its low energy consumption and CO2 emissions.
The exponential growth of electric and hybrid vehicles in the last five years forecasts a waste problem when their batteries achieve end-of-life. Li-ion batteries for vehicles have been assembled using materials from natural resources (as Li, Fe, Al, Cu Co, Mn and P). Among them, LiFePO4 cathode materials have demonstrated advantages such as charge-discharge cycles, thermal stability, surface area and raw materials availability (against Ni and Co systems). Due to the performance, LFP batteries stand out in heavy duty fleet, achieving 90% of new energy buses in China. To achieve the circular economy, the recycling of LFP batteries may be carried out by pyrometallurgy (thermal processing), hydrometallurgy (aqueous processing) or both in combination. Comparatively, hydrometallurgical processing is more advantageous due to its low energy consumption and CO2 emissions. In addition, Li may be recovered in a high-pure grade. This work is a literature review of the current alternatives for the recycling of LFP batteries by hydrometallurgy, comparing designed processes in the literature and indicating solutions towards a circular economy. The major recycling steps of hydrometallurgy routes such as pre-treatments, leaching and purification steps will be gathered and discussed in terms of efficiency and environmental impact.
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