期刊
CHEMELECTROCHEM
卷 10, 期 6, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.202201068
关键词
lithium-ion batteries; reduced graphene oxide; thin films; titanium dioxide; USER reaction
In this study, a facile strategy using ultrafast and self-expansion reduction reaction (USER) was proposed to improve the electrochemical performance of a free-standing Li-ion battery electrode composed of titanium dioxide (TiO2) by forming a composite with reduced graphene oxide (RGO). The self-expansion induced by rapid heating provided cavities/empty spaces to mitigate volume change during charge/discharge process, resulting in enhanced storage and conversion response of the system (765 mAh g(-1) at 0.05 A g(-1)) and accelerated Coulombic efficiency. Detailed electrochemical, microscopic, and structural analyses demonstrated that this internal expansion improved ionic diffusion and protected the material from volume changes during charge/discharge process. Therefore, this simple and fast strategy offers a solution to enhance the electrochemical performance of other active materials sensitive to volume expansion during lithiation/delithiation process.
In this study, a facile strategy to promote electrochemical performance of free-standing Li-ion battery electrode composed of titanium dioxide (TiO2) via composite formation with reduced graphene oxide (RGO) using ultrafast and self-expansion reduction reaction (USER) was proposed. This approach induced self-expansion through rapid heating providing abundance of cavities/empty spaces to alleviate volume change during charge/discharge process resulting in boosted storage and conversion response of the system (765 mAh g(-1) at 0.05 A g(-1)) and accelerated Coulombic efficiency. Detailed electrochemical, microscopic and structural analyses (ex-situ) of the film prove that this internal expansion delivers enhanced ionic diffusion and shielding material from volume changes during charge/discharge process. Therefore, we believe that this simple and very fast strategy offers a venue to overcome one of the main bottleneck in promotion of electrochemical performance of other active materials which are sensitive to volume expansion during lithiation/delithiation process.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据