Non-Thermal Plasma Incorporated with Cu-Mn/γ-Al2O3 for Mixed Benzene Series VOCs' Degradation

In this work, a coaxial dielectric barrier discharge (DBD) reactor was constructed to degrade the mixture of toluene and o-xylene, two typical benzene series. The Cu-MnO2/gamma-Al2O3 series catalysts prepared by redox and impregnation methods were filled into the plasma device to degrade VOCs synergistically and explore the degradation effect. The experimental results showed that the introduction of a Cu-doped MnO2 catalyst significantly improved the pollutants' removal efficiency and CO2 selectivity, and greatly inhibited the formation of by-products. Among them, Cu0.15Mn/gamma-Al2O3 showed the highest removal efficiency (toluene was 100% and o-xylene was 100%), and the best CO2 selectivity (92.73%). The XRD, BET, XPS and SEM results confirmed that the synergistic effect between Cu and Mn in the Cu-Mn solid solution could promote the amount and reducibility of the surface active oxygen species, which improved the catalytic performance. Finally, the toluene and o-xylene decomposition pathways in the NTP catalytic system were speculated according to the detected organic matter. This work provides a theoretical and experimental basis for the application of DBD-catalyzed hybrid benzene series VOCs.

Automated summary

A coaxial dielectric barrier discharge (DBD) reactor was used to degrade the mixture of toluene and o-xylene. Cu-MnO2/gamma-Al2O3 catalysts were used to degrade VOCs and improve the degradation efficiency. The introduction of Cu-doped MnO2 catalyst significantly improved pollutants' removal efficiency and CO2 selectivity, with Cu0.15Mn/gamma-Al2O3 showing the highest removal efficiency (100% toluene and 100% o-xylene) and the best CO2 selectivity (92.73%).