期刊
CHEMCATCHEM
卷 8, 期 3, 页码 571-576出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201501069
关键词
heterogeneous catalysis; high-throughput screening; homogeneous catalysis; hydrogenation; nanoparticles
资金
- European Research Council [StG 258740]
Small (1.4nm) and very active Ru nanoparticles, stabilized in a polysiloxane matrix, were prepared and studied in hydrogenation reactions by the integration of catalysis and analysis. We used our strategy to combine catalytic activity and separation selectivity in a capillary microreactor, installed in a GC-MS instrument, to develop a fast and reliable screening tool for catalysis over Ru nanoparticles. A high conversion using a low catalyst loading of 0.3mol% and temperature and long-term stability of the catalytically active column were observed for the hydrogenation of various carbonyl compounds, which included aldehydes, ketones, and pyruvates. Additionally, we observed a high chemoselectivity for aromatic carbonyl systems. Comprehensive measurements were performed in this high-throughput experimental setup to gain important insights into the kinetics of hydrogenation reactions at the interface between heterogeneous and homogeneous catalysis.
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