4.5 Article

Ultrafast Synthesis of Mo2C-Based Catalyst by Joule Heating towards Electrocatalytic Hydrogen Evolution Reaction

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Chemistry, Physical

High-valence metal doped Co2FeAl alloy as efficient noble-metal-free electrocatalyst for alkaline hydrogen evolution reaction

Jiawei Zhang et al.

Summary: The catalytic performance of electrocatalysts for the electrochemical hydrogen evolution reaction (HER) in alkaline solutions can be improved by doping high-valence metal atoms in the alloy and optimizing its crystal structure and electronic structure through thermal annealing. The synthesized Co2FeAlMo1.5 (750 degrees C) alloy electrocatalyst demonstrates superior HER performance in alkaline media.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Chemistry, Physical

Activating molybdenum carbide via a surface sulfur modification to enhance hydrogen evolution activity

Shisheng Yuan et al.

Summary: Molybdenum carbide (Mo2C) with sulfur modification has been developed as an efficient catalyst for hydrogen evolution reaction (HER). The sulfur atoms replace a portion of the oxygen atoms on the surface of Mo2C, activating the surface and improving the HER performance. Theoretical studies suggest that the strong hydrogen bonding of Mo atoms in the oxide layer is the primary reason for impaired HER performance, and sulfur modification weakens the Mo-H bond, leading to enhanced HER activity.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Review Chemistry, Multidisciplinary

Rational Design of Transition Metal Phosphide-Based Electrocatalysts for Hydrogen Evolution

Dong Liu et al.

Summary: Developing efficient and inexpensive electrocatalysts for the hydrogen evolution reaction (HER) is crucial for the commercial viability of electrochemical clean energy technologies. Transition metal phosphides (TMPs) have been recognized as attractive HER catalytic materials due to their abundant reserves, unique structure, tunable composition, and high electronic conductivity. However, the HER activity of TMPs is still limited by various issues and performance bottlenecks. This review addresses these issues, provides explanations and solutions based on the origins of HER catalytic activity in TMPs, presents strategies to improve HER performance, and proposes critical scientific issues for constructing high-efficiency TMP-based electrocatalysts. Challenges and future directions for this research field, including the HER reaction process, catalytic mechanism research, TMP-based catalyst construction, and application expansion, are also discussed.

ADVANCED FUNCTIONAL MATERIALS (2023)

Article Chemistry, Multidisciplinary

Ultrahigh Pt-Mass-Activity Hydrogen Evolution Catalyst Electrodeposited from Bulk Pt

Luan Liu et al.

Summary: This study reports on a three-component heterostructured hydrogen evolution reaction (HER) catalyst with ultra-high Pt mass activity. The catalyst consists of hollow PtCu alloy nanospheres supported on an array of WO3 on Cu foam. By utilizing the contamination from the Pt counter electrode, the authors were able to activate low-HER-activity materials, maximizing the utilization of Pt. The resulting catalyst exhibits ultrahigh Pt mass activity, outperforming commercial Pt/C catalysts and some state-of-the-art Pt-single-atom catalysts.

ADVANCED FUNCTIONAL MATERIALS (2022)

Article Engineering, Environmental

Hybrid electrocatalyst Ag/Co/C via flash Joule heating for oxygen reduction reaction in alkaline media

Yishu Qiu et al.

Summary: In this study, Ag/Co/C hybrid electrocatalyst for oxygen reduction reaction (ORR) was successfully synthesized via radiative flash Joule heating. The hybrid catalyst exhibits higher activity and stability in alkaline media compared to commercial Pt/C due to the strong interaction between silver and cobalt.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Physical

Transition metal doped MoS2 nanosheets for electrocatalytic hydrogen evolution reaction

P. Sundara Venkatesh et al.

Summary: This study explores the effect of transition metal doping on 2D MoS2 nanosheets for the electrocatalytic hydrogen evolution reaction (HER). High-quality MoS2 nanosheets with randomly doped metal ions were synthesized using a hydrothermal method. It was found that Ni-MoS2 exhibited superior HER performance compared to Co-MoS2 and Fe-MoS2.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Chemistry, Physical

Ultrafast Joule heating synthesis of hierarchically porous graphene-based Co-N-C single-atom monoliths

Lingli Xing et al.

Summary: In this study, a transient heating-quenching strategy triggered by Joule heating was developed to synthesize single-atom cobalt- and nitrogen-doped graphene materials with a three-dimensional porous monolithic architecture. The resulting material exhibited high catalytic activity and durability for the hydrogen evolution reaction, showcasing the potential of this rapid and facile route for manufacturing single atom catalysts.

NANO RESEARCH (2022)

Article Multidisciplinary Sciences

Phase controlled synthesis of transition metal carbide nanocrystals by ultrafast flash Joule heating

Bing Deng et al.

Summary: Ultrafast synthesis of nanoscale carbides through flash Joule heating process allows for excellent phase control. Carbon vacancies are found to be the driving factor for the topotactic transition of carbide phases. In terms of catalytic activity, β-Mo2C shows the best hydrogen evolution capability.

NATURE COMMUNICATIONS (2022)

Article Multidisciplinary Sciences

Multi-principal elemental intermetallic nanoparticles synthesized via a disorder-to-order transition

Mingjin Cui et al.

Summary: Nanoscale multi-principal element intermetallics (MPEIs) can be synthesized as ultrasmall and stable nanoparticles through a disorder-to-order phase transition approach, offering a broad and tunable compositional space of active, high-surface area materials with potential applications.

SCIENCE ADVANCES (2022)

Article Chemistry, Multidisciplinary

Limiting the Uncoordinated N Species in M-Nx Single-Atom Catalysts toward Electrocatalytic CO2 Reduction in Broad Voltage Range

Dawei Xi et al.

Summary: Carbon-supported Ni single-atom catalysts with precisely controlled single-atom structure achieved through joule heating strategy show superior performance in electrocatalytic carbon dioxide reduction reaction, with 80% of N dopants coordinated with metal elements, thereby avoiding unfavorable N species and demonstrating unprecedented activity, selectivity, and stability.

ADVANCED MATERIALS (2022)

Article Engineering, Environmental

Electronic modulation of Pt nanoclusters through tuning the interface of Pt-SnO2 clusters for enhanced hydrogen evolution catalysis

Yuquan Lai et al.

Summary: Modulating the electronic structure of Pt nanoclusters by tuning the Pt/SnO2 interface enhances the hydrogen evolution catalytic activity. The optimized Pt/SnO2@NPC-300 catalyst exhibits high HER catalytic activity and durability in acidic solution.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Physical

Response surface optimization of syngas production from greenhouse gases via DRM over high performance Ni-W catalyst

Mohammad Yusuf et al.

Summary: The process parameters for dry reforming of methane (DRM) over Ni-W/Al2O3-MgO catalyst were optimized using response surface methodology (RSM). The optimized conditions achieved methane and carbon dioxide conversions of 87.6% and 93.3%, respectively, with a temperature of 777.29 degrees C, a CH4:CO2 ratio of 1.11, and a GHSV of 36,000 cm3gm.cat-1h-1. The formation of MWCNT during DRM prevented catalyst deactivation and maintained stable performance.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Review Chemistry, Physical

Recent Advances in Carbon-Supported Noble-Metal Electrocatalysts for Hydrogen Evolution Reaction: Syntheses, Structures, and Properties

Yuhang Liu et al.

Summary: This article provides a comprehensive review on carbon-supported noble-metal electrocatalysts for the hydrogen evolution reaction (HER). It discusses the synthetic strategies, structural analyses, and applications of these electrocatalysts, and explores the correlation between electronic structure and activity. Furthermore, it offers a perspective on the challenges and opportunities in developing highly efficient HER electrocatalysts for widespread utilization in green hydrogen production.

ADVANCED ENERGY MATERIALS (2022)

Review Chemistry, Physical

Mesoporous silica supported Ni-based catalysts for methane dry reforming: A review of recent studies

Bernard Chukwuemeka Ekeoma et al.

Summary: Dry reforming of methane (DRM) is a green alternative for utilizing greenhouse gases and producing syngas. The main limitations of DRM are catalyst sintering and coking. Recent studies have focused on Ni-based catalysts for DRM due to economic constraints on noble metal-based catalysts. Mesoporous silica (MS) supported catalysts show promise due to their high surface areas, thermal stability, and easy availability. However, research on MS as a catalyst support for DRM is still limited.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Chemistry, Multidisciplinary

Rapid Joule-Heating Synthesis for Manufacturing High-Entropy Oxides as Efficient Electrocatalysts

Han Wu et al.

Summary: High-entropy oxide (HEO) with multiple principal elements has great potential in various fields. However, the traditional heating synthesis method is not suitable for rapid screening of properties, and the current elemental combinations are highly limited. In this study, a rapid synthesis method for HEO was developed through Joule heating, and new elemental combinations of high-entropy rocksalt oxides (HERSO), high-entropy spinel oxides (HESO), and high-entropy perovskite oxide (HEPO) were successfully synthesized. The newly synthesized HERSO showed improved OER activity due to the synergy of multiple components. This research provides a broad platform for the development of high-entropy materials and catalysts.

NANO LETTERS (2022)

Article Multidisciplinary Sciences

Ultrafast self-heating synthesis of robust heterogeneous nanocarbides for high current density hydrogen evolution reaction

Chenyu Li et al.

Summary: The ultrafast self-heating synthesis method delivers robust Mo2C/MoC/CNT HER catalysts that exhibit excellent activity and stability under high current densities, meeting the demands of industrial water splitting.

NATURE COMMUNICATIONS (2022)

Review Chemistry, Multidisciplinary

2D Transition Metal Dichalcogenides-Based Electrocatalysts for Hydrogen Evolution Reaction

Aniruddha Mondal et al.

Summary: This article discusses the key parameters for improving the catalytic performance of 2D transition metal chalcogenides in electrochemical hydrogen evolution reaction processes, and summarizes the latest developments in this field, focusing on the enhancement of the electrocatalytic activity of 2D TMDs.

ADVANCED FUNCTIONAL MATERIALS (2022)

Article Chemistry, Physical

Microwave-pulse sugar-blowing assisted synthesis of 2D transition metal carbides for sustainable hydrogen evolution

Rong Hu et al.

Summary: Ultra-thin carbon-terminated two-dimensional transition metal carbides (2D TMCs) were synthesized rapidly using a microwave-pulse sugar-blowing method, which improved the electrocatalytic activity and stability of the hydrogen evolution reaction.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Article Chemistry, Physical

Interface engineering of bimetallic nitrides nanowires as a highly efficient bifunctional electrocatalyst for water splitting

Ruijie Dai et al.

Summary: In this study, nickel molybdenum nitride heterostructure nanowire arrays were successfully synthesized on nickel foam to achieve high-performance self-supporting electrodes. These electrodes exhibited low overpotentials in water splitting reactions, providing a new approach for the design of non-precious metal-based transition metal nitride catalysts.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Review Chemistry, Multidisciplinary

Advances in the Electrocatalytic Hydrogen Evolution Reaction by Metal Nanoclusters-based Materials

Junyang Ding et al.

Summary: This article reviews the methods of enhancing the activity of metal nanoclusters (MNCs) in water electrolysis and introduces the recent progress of MNCs classified with different stabilization strategies. It also identifies the current challenges and deficiencies of these MNCs in water electrolysis.
Article Nanoscience & Nanotechnology

Graphite Nanoflake-Modified Mo2C with Ameliorated Interfacial Interaction as an Electrocatalyst for Hydrogen Evolution Reaction

Fangfei Lin et al.

Summary: Graphite nanoflakes can disperse Mo2C quantum dots effectively, leading to improved performance in hydrogen evolution reaction. Mo2C quantum dots anchored to the basal planes of defective graphite nanoflakes exhibit better electrochemical performance.

ACS APPLIED MATERIALS & INTERFACES (2022)

Review Chemistry, Physical

Metal organic frameworks as electrocatalysts: Hydrogen evolution reactions and overall water splitting

Meena Nemiwal et al.

Summary: This review summarizes the recent advances in heterogeneous catalysis using metal organic frameworks (MOFs) as electrocatalysts for hydrogen evolution reaction (HER) and water splitting, including the enhancement of performance with composites of MOFs and bifunctional electrocatalysts derived from MOFs using different synthetic approaches.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

Review Engineering, Environmental

Recent advances in structural engineering of molybdenum disulfide for electrocatalytic hydrogen evolution reaction

Xian Zhang et al.

Summary: This review focuses on summarizing the structural engineering strategies for activating MoS2, including edge engineering and disorder engineering, and theoretical analyses are used to reveal the HER mechanism of MoS2. Additionally, the comprehensive summaries and outlook in developing MoS2 as earth-abundant HER electrocatalyst are discussed.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Materials Science, Multidisciplinary

Syngas production employing nickel on alumina-magnesia supported catalyst via dry methane reformingSynthesegasherstellung unter Verwendung von Nickel auf Aluminium-Magnesium unterstutztem Katalysator durch Trockenreformierung von Methan

M. Yusuf et al.

Summary: Nickel nano-catalysts supported on alumina-magnesia bimetallic oxide support were studied for dry methane reforming. It was found that the catalyst with 12 wt.% nickel showed the best activity and stability, achieving optimal reaction performance under certain conditions. Analysis techniques confirmed coke formation during the reaction.

MATERIALWISSENSCHAFT UND WERKSTOFFTECHNIK (2021)

Article Chemistry, Physical

Photonic Flash Synthesis of Mo2C/Graphene Electrocatalyst for the Hydrogen Evolution Reaction

Danick Reynard et al.

Summary: Molybdenum carbides (Mo2C) have been explored as alternative electrocatalysts for the hydrogen evolution reaction. A fast and simple fabrication method for Mo2C-based electrocatalysts on a carbon cloth substrate was proposed using photonic flash synthesis (PFS). The resulting material showed excellent catalytic performance and stability in acidic media.

ACS CATALYSIS (2021)

Review Chemistry, Multidisciplinary

Roadmap and Direction toward High-Performance MoS2 Hydrogen Evolution Catalysts

Yang Cao

Summary: MoS2 shows Pt-like hydrogen evolution reaction (HER) performance through strategies such as phase engineering, S vacancy, heterojunctions, and dopants. By utilizing these approaches, MoS2 has the potential to become a highly efficient HER catalyst comparable to Pt.

ACS NANO (2021)

Article Chemistry, Multidisciplinary

PtSe2/Pt Heterointerface with Reduced Coordination for Boosted Hydrogen Evolution Reaction

Zongpeng Wang et al.

Summary: Constructing PtSe2/Pt heterointerface can enhance the reaction kinetics of PtSe2, achieving near thermoneutral free energy change for hydrogen evolution reaction. The activated Pt atoms near Se vacancies strengthen the adsorption of H-. intermediate, leading to extraordinary activity even superior to Pt/C, demonstrating the potential of NMDs for HER and providing insights for constructing novel heterointerfaces.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Review Chemistry, Physical

Metal carbides as alternative electrocatalysts for energy conversion reactions

Sang Hoon Joo et al.

Summary: Metal carbides have attracted continuous interest in heterogeneous catalysis, especially as alternative electrocatalysts for Pt-group metal catalysts in renewable energy conversion reactions. Their structural design and reactivity are crucial for hydrogen-, oxygen-, and carbon-involving energy conversion reactions, with future challenges and opportunities in the field.

JOURNAL OF CATALYSIS (2021)

Article Chemistry, Physical

Highly active and stable nickel-molybdenum nitride (Ni2Mo3N) electrocatalyst for hydrogen evolution

Sang Heon Park et al.

Summary: This study introduces a nonprecious metal electrocatalyst based on bimetallic nanoscale nickel molybdenum nitride for the hydrogen evolution reaction (HER), demonstrating high activity and stability. The Ni2Mo3N/NF catalyst exhibits excellent performance in alkaline media, possibly due to the N sites in Ni2Mo3N with a N-Mo coordination number of four having a hydrogen adsorption energy close to that of Pt.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Review Chemistry, Multidisciplinary

Recent Advances in Electrocatalytic Hydrogen Evolution Using Nanoparticles

Jing Zhu et al.

CHEMICAL REVIEWS (2020)

Article Multidisciplinary Sciences

Gram-scale bottom-up flash graphene synthesis

Duy X. Luong et al.

NATURE (2020)

Article Multidisciplinary Sciences

Implanting Ni-O-VOx sites into Cu-doped Ni for low-overpotential alkaline hydrogen evolution

Yibing Li et al.

NATURE COMMUNICATIONS (2020)

Article Materials Science, Multidisciplinary

Synthesis of high purity nano-sized transition-metal carbides

Ke-Han Wu et al.

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T (2020)

Article Multidisciplinary Sciences

Direct observation of the formation and stabilization of metallic nanoparticles on carbon supports

Zhennan Huang et al.

NATURE COMMUNICATIONS (2020)

Article Nanoscience & Nanotechnology

High temperature shockwave stabilized single atoms

Yonggang Yao et al.

NATURE NANOTECHNOLOGY (2019)

Article Chemistry, Physical

Rapid synthesis of size-tunable transition metal carbide nanodots under ambient conditions

Jun Wan et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Review Chemistry, Multidisciplinary

Recent progress made in the mechanism comprehension and design of electrocatalysts for alkaline water splitting

Congling Hu et al.

ENERGY & ENVIRONMENTAL SCIENCE (2019)

Article Chemistry, Multidisciplinary

A Type of 1 nm Molybdenum Carbide Confined within Carbon Nanomesh as Highly Efficient Bifunctional Electrocatalyst

Zhihua Cheng et al.

ADVANCED FUNCTIONAL MATERIALS (2018)

Article Chemistry, Physical

N-Doped Porous Molybdenum Carbide Nanobelts as Efficient Catalysts for Hydrogen Evolution Reaction

Shengyu Jing et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

Article Chemistry, Physical

Porous carbon incorporated β-Mo2C hollow sphere: An efficient electrocatalyst for hydrogen evolution reaction

Arka Saha et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2018)

Article Multidisciplinary Sciences

Carbothermal shock synthesis of high-entropy-alloy nanoparticles

Yonggang Yao et al.

SCIENCE (2018)

Article Chemistry, Physical

Highly Efficient, Biochar-Derived Molybdenum Carbide Hydrogen Evolution Electrocatalyst

Govinda Humagain et al.

ADVANCED ENERGY MATERIALS (2018)

Article Multidisciplinary Sciences

Oxygen evolution reaction dynamics monitored by an individual nanosheet-based electronic circuit

Peiyao Wang et al.

NATURE COMMUNICATIONS (2017)

Article Chemistry, Multidisciplinary

A Nanojunction Polymer Photoelectrode for Efficient Charge Transport and Separation

Qiushi Ruan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Article Chemistry, Multidisciplinary

Atomic H-Induced Mo2C Hybrid as an Active and Stable Bifunctional Electrocatalyst

Xiujun Fan et al.

ACS NANO (2017)

Article Chemistry, Multidisciplinary

Ultrafine Molybdenum Carbide Nanoparticles Composited with Carbon as a Highly Active Hydrogen-Evolution Electrocatalyst

Ruguang Ma et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Review Chemistry, Physical

Recent advances in heterogeneous electrocatalysts for the hydrogen evolution reaction

Min Zeng et al.

JOURNAL OF MATERIALS CHEMISTRY A (2015)