期刊
CHEMCATCHEM
卷 8, 期 1, 页码 86-96出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201500455
关键词
chirality; desymmetrization; domino reactions; kinetic resolution; organocatalysis
资金
- Ministry of Science and Technology of the Republic of China [NSC 102-2113M-003-005-MY3, MOST 103-2325-B-003-001]
This Minireview describes organocatalytic kinetic resolution (OCKR) that has evolved on the basis of using small organic catalysts through enamine/iminium ion, N-heterocyclic carbene, and hydrogen-bonding catalysis. The review includes the use of recent methodologies for which the evolution of OCKR mainly involves creating new stereogenic center(s) in functionalized products through the formation of a C-C, C-N, C-O, C-X, or C-S bond. The combination of OCKR with sequential reactions and its association with desymmetrization and dynamic kinetic resolution are also described.
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