期刊
CHEMCATCHEM
卷 7, 期 17, 页码 2689-2697出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201500563
关键词
amino alcohols; heterogeneous catalysis; iron; mesoporous materials; titanium
资金
- Council of Scientific and Industrial Research (CSIR)
- Department of Science and Technology (DST), New Delhi, India
- DST
- UGC, New Delhi
- DST-SERB, New Delhi
A mesoporous TiO2-Fe2O3 mixed oxide material (MTF-1E) with nanoscale porosity and a high BET surface area was synthesized using sodium dodecyl sulfate (SDS) as a structure-directing agent. The material was characterized by powder XRD, high-resolution TEM, N-2 sorption, and NH3 temperature-programmed desorption studies. The catalyst shows an excellent regioselectivity for the ring-opening of epoxides with amines under solvent-free conditions at room temperature for the synthesis of a series of beta-amino alcohols. It also showed a very high catalytic efficiency for the synthesis of benzimidazole derivatives in water. The catalyst can be recovered easily from the reaction medium and reused six times without a significant decrease in its catalytic activity and selectivity.
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