4.6 Article

Diluent decomposition-assisted formation of LiF-rich solid-electrolyte interfaces enables high-energy Li-metal batteries

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Chemistry, Physical

Anion-Diluent Pairing for Stable High-Energy Li Metal Batteries

Chunnan Zhu et al.

Summary: This research reports a new method to improve the Coulombic efficiency and inhibit dendritic growth in rechargeable Li metal batteries by introducing fluorinated aromatic diluents into high-concentration electrolytes. The use of this electrolyte provides higher energy density and cycling life without compromising the performance of the battery.

ACS ENERGY LETTERS (2022)

Article Chemistry, Physical

Quantifying the apparent electron transfer number of electrolyte decomposition reactions in anode-free batteries

Ming-Yue Zhou et al.

Summary: Solid electrolyte interphase (SEI) is crucial for the stability of non-aqueous batteries. However, the quantitative understanding of electrolyte decomposition mechanism is limited. In this study, the apparent electron transfer number (ETN) is obtained as a quantitative descriptor in lithium metal batteries, providing insights into the decomposition mechanism of electrolyte components.
Article Chemistry, Applied

Regulating dissolution chemistry of nitrates in carbonate electrolyte for high-stable lithium metal batteries

Yazhen Zhu et al.

Summary: Lithium metal batteries have high energy density, but their practical application is limited due to the incompatibility of ester electrolytes. This study found that nitrates containing crystal water can be dissolved in ester electrolytes, improving the stability of the lithium anode. The method is universal and simple, and it enhances the electrochemical performance of the battery.

JOURNAL OF ENERGY CHEMISTRY (2022)

Article Multidisciplinary Sciences

Inhibiting intercrystalline reactions of anode with electrolytes for long-cycling lithium batteries

Peng Shi et al.

Summary: This study investigates the impact of grain boundary on the reactions of lithium metal anodes and proposes a heteroatom-concentrated grain boundary as a strategy to inhibit intercrystalline reactions. The scalable preparation of the grain boundary is demonstrated, leading to a significant improvement in the cycling performance of the lithium battery.

SCIENCE ADVANCES (2022)

Review Chemistry, Physical

Anode-Free Full Cells: A Pathway to High-Energy Density Lithium-Metal Batteries

Sanjay Nanda et al.

Summary: The anode-free full cell configuration is ideal for high energy density and lithium storage, but poor efficiencies of lithium plating and stripping lead to short cycle life. Recent studies have shown that advanced electrolytes and other methods can stabilize lithium deposition and improve cycle life.

ADVANCED ENERGY MATERIALS (2021)

Article Chemistry, Multidisciplinary

Fluorobenzene, A Low-Density, Economical, and Bifunctional Hydrocarbon Cosolvent for Practical Lithium Metal Batteries

Zhipeng Jiang et al.

Summary: By using fluorobenzene (FB) as a bifunctional cosolvent, a novel FB diluted highly concentrated electrolyte (FB-DHCE) is developed, enabling dendrite-free deposition of lithium with high Coulombic efficiency and prolonged cycling life for lithium metal anodes.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Chemistry, Multidisciplinary

Regulating Interfacial Chemistry in Lithium-Ion Batteries by a Weakly Solvating Electrolyte**

Yu-Xing Yao et al.

Summary: The research reveals a weakly solvating electrolyte that improves the performance of Li-ion batteries by forming unique anion-derived interfaces, demonstrating fast-charging and long-term cycling characteristics.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Designing and Demystifying the Lithium Metal Interface toward Highly Reversible Batteries

Rui Xu et al.

Summary: By regulating the strong Li+-anion coordination structures and nucleation modulation procedure in a low-polarity solvent, high-efficiency Li plating/stripping can be achieved, improving cycling efficiency and minimizing solid electrolyte interface generation. The study shows potential for building high-energy-density Li metal batteries through these targeted interfacial designs.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

Gradient Solid Electrolyte Interphase and Lithium-Ion Solvation Regulated by Bisfluoroacetamide for Stable Lithium Metal Batteries

Fang Li et al.

Summary: This study focuses on the impact of bisfluoroacetamide (BFA) as an electrolyte additive on the solid electrolyte interphase (SEI) structure. By constructing a gradient SEI structure, it achieves better Li ion capture and transportation effects.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Liquid Alloy Enabled Solid-State Batteries for Conformal Electrode-Electrolyte Interfaces

Xuelin Guo et al.

Summary: Recent research has shown that using a Na-K liquid alloy electrode can address the issue of incompatibility between the solid electrolyte and metal anode in solid-state alkali-metal batteries, leading to improved battery performance.

ADVANCED FUNCTIONAL MATERIALS (2021)

Review Energy & Fuels

Moving beyond 99.9% Coulombic efficiency for lithium anodes in liquid electrolytes

Gustavo M. Hobold et al.

Summary: This review examines the trends and key descriptors of Coulombic efficiency in Li-metal batteries over the past five decades, as well as strategies to improve CE. While advancements have been made in cost and energy density of Li-ion batteries, achieving high Coulombic efficiency consistently remains a challenge.

NATURE ENERGY (2021)

Article Chemistry, Multidisciplinary

Advanced Electrolytes Enabling Safe and Stable Rechargeable Li-Metal Batteries: Progress and Prospects

Shuang-Jie Tan et al.

Summary: This article summarizes the challenges of electrolytes in rechargeable Li-metal batteries (RLBs) and proposes requirements for improving battery performance. It also reviews the achievements of liquid- and solid-state electrolytes in RLBs, analyzes their drawbacks, and offers solutions. The article outlines the development strategy of in situ gelation electrolytes and calls for more attention to battery safety research in pouch cell users.

ADVANCED FUNCTIONAL MATERIALS (2021)

Review Chemistry, Multidisciplinary

High-voltage liquid electrolytes for Li batteries: progress and perspectives

Xiulin Fan et al.

Summary: The energy density of LIBs has been increased threefold since their introduction, but the capacity of transition metal oxide cathodes is approaching its limit due to stability limitations of electrolytes. To further enhance energy density, new high-capacity and high-voltage cathode materials need to be explored, and graphite anodes may need to be replaced. One of the main challenges for future development is the development of new electrolyte compositions that can accommodate high-voltage cathodes and anodes while ensuring the stability of the batteries.

CHEMICAL SOCIETY REVIEWS (2021)

Article Chemistry, Physical

Advanced Electrolytes for Fast-Charging High-Voltage Lithium-Ion Batteries in Wide-Temperature Range

Xianhui Zhang et al.

ADVANCED ENERGY MATERIALS (2020)

Review Energy & Fuels

Advances and issues in developing salt-concentrated battery electrolytes

Yuki Yamada et al.

NATURE ENERGY (2019)

Article Chemistry, Multidisciplinary

Adiponitrile (C6H8N2): A New Bi-Functional Additive for High-Performance Li-Metal Batteries

Seon Hwa Lee et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

Editorial Material Energy & Fuels

Anode-less

Ji-Guang Zhang

NATURE ENERGY (2019)

Article Chemistry, Multidisciplinary

Nucleation and Early Stage Growth of Li Electrodeposits

Prayag Biswal et al.

NANO LETTERS (2019)

Article Chemistry, Physical

High-Efficiency Lithium-Metal Anode Enabled by Liquefied Gas Electrolytes

Yangyuchen Yang et al.

Article Chemistry, Physical

Accurate Determination of Coulombic Efficiency for Lithium Metal Anodes and Lithium Metal Batteries

Brian D. Adams et al.

ADVANCED ENERGY MATERIALS (2018)

Article Chemistry, Multidisciplinary

High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes

Shuru Chen et al.

ADVANCED MATERIALS (2018)

Article Materials Science, Multidisciplinary

A carbonate-free, sulfone-based electrolyte for high-voltage Li-ion batteries

Judith Alvarado et al.

MATERIALS TODAY (2018)

Article Nanoscience & Nanotechnology

Non-flammable electrolyte enables Li-metal batteries with aggressive cathode chemistries

Xiulin Fan et al.

NATURE NANOTECHNOLOGY (2018)

Article Chemistry, Multidisciplinary

Highly Fluorinated Interphases Enable High-Voltage Li-Metal Batteries

Xiulin Fan et al.

Article Chemistry, Multidisciplinary

Lithium Nitrate Solvation Chemistry in Carbonate Electrolyte Sustains High-Voltage Lithium Metal Batteries

Chong Yan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Multidisciplinary Sciences

Fluorinated solid electrolyte interphase enables highly reversible solid-state Li metal battery

Xiulin Fan et al.

SCIENCE ADVANCES (2018)

Review Electrochemistry

Review-SEI: Past, Present and Future

E. Peled et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

Nanoscale Nucleation and Growth of Electrodeposited Lithium Metal

Allen Pei et al.

NANO LETTERS (2017)

Review Nanoscience & Nanotechnology

Reviving the lithium metal anode for high-energy batteries

Dingchang Lin et al.

NATURE NANOTECHNOLOGY (2017)

Review Chemistry, Multidisciplinary

Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review

Xin-Bing Cheng et al.

CHEMICAL REVIEWS (2017)

Article Chemistry, Multidisciplinary

Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries

Xue-Qiang Zhang et al.

ADVANCED FUNCTIONAL MATERIALS (2017)

Article Chemistry, Physical

Interface Stability in Solid-State Batteries

William D. Richards et al.

CHEMISTRY OF MATERIALS (2016)

Article Chemistry, Multidisciplinary

Anode-Free Rechargeable Lithium Metal Batteries

Jiangfeng Qian et al.

ADVANCED FUNCTIONAL MATERIALS (2016)

Article Chemistry, Multidisciplinary

Transition of lithium growth mechanisms in liquid electrolytes

Peng Bai et al.

ENERGY & ENVIRONMENTAL SCIENCE (2016)

Review Chemistry, Multidisciplinary

Electrolyte additives for lithium ion battery electrodes: progress and perspectives

Atetegeb Meazah Haregewoin et al.

ENERGY & ENVIRONMENTAL SCIENCE (2016)

Article Chemistry, Physical

Fluorinated electrolyte for 4.5 V Li(Ni0.4Mn0.4Co0.2)O2/graphite Li-ion cells

Jian Xia et al.

JOURNAL OF POWER SOURCES (2016)

Article Multidisciplinary Sciences

Superconcentrated electrolytes for a high-voltage lithium-ion battery

Jianhui Wang et al.

NATURE COMMUNICATIONS (2016)

Review Nanoscience & Nanotechnology

Promise and reality of post-lithium-ion batteries with high energy densities

Jang Wook Choi et al.

NATURE REVIEWS MATERIALS (2016)

Review Chemistry, Multidisciplinary

Electrolytes and Interphases in Li-Ion Batteries and Beyond

Kang Xu

CHEMICAL REVIEWS (2014)

Article Chemistry, Physical

Stable lithium electrodeposition in liquid and nanoporous solid electrolytes

Yingying Lu et al.

NATURE MATERIALS (2014)

Article Chemistry, Multidisciplinary

Fluorinated electrolytes for 5 V lithium-ion battery chemistry

Zhengcheng Zhang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2013)

Article Thermodynamics

Thermodynamic of LiF dissolution in alkylcarbonates and some of their mixtures with water

Jennifer Jones et al.

FLUID PHASE EQUILIBRIA (2009)

Review Chemistry, Physical

A review on electrolyte additives for lithium-ion batteries

Sheng Shui Zhang

JOURNAL OF POWER SOURCES (2006)

Article Electrochemistry

The effect of interfacial deformation on electrodeposition kinetics

C Monroe et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2004)

Review Chemistry, Multidisciplinary

Nonaqueous liquid electrolytes for lithium-based rechargeable batteries

K Xu

CHEMICAL REVIEWS (2004)