期刊
ASIAN JOURNAL OF ORGANIC CHEMISTRY
卷 12, 期 6, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.202300147
关键词
Friedel-Crafts; indium; Prins; tandem cyclization; thiophenes
An indium catalyzed Prins/Friedel-Crafts tandem cyclization reaction has been developed, providing an efficient and practical method for the construction of various polycyclic indole frameworks with high diastereoselectivity and good functional group tolerance (30 examples, up to 98% yield with >95 : 5 dr). The resulting products are easily accessible for further chemical transformations.
An indium catalyzed Prins/Friedel-Crafts tandem cyclization reaction has been developed. This reaction provides an efficient and practical method to construct a variety of polycyclic indole frameworks with high diastereoselectivity and good functional group tolerance (30 examples, up to 98% yield with >95 : 5 dr). The resulting products are easily accessible for further chemical transformations.
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