期刊
ASIAN JOURNAL OF ORGANIC CHEMISTRY
卷 12, 期 4, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.202300050
关键词
activated carbon; anthraquinone; date stone; redox gel electrolyte; supercapacitor
Construction of eco-benign, cost effective, and high-performance supercapacitors with improved electrolytes and hierarchical porous electrodes is necessary for effective energy storage. A gel type organic redox electrolyte made of polyvinyl alcohol (PVA)-H2SO4 and an organic redox molecule, anthraquinone (PVA-H2SO4-AQ), was used to construct a symmetric supercapacitor (SSC) with a high specific capacitance and energy density. The addition of anthraquinone to the gel electrolyte significantly improved the performance of the device, suggesting a promising approach for sustainable and eco-benign energy storage materials.
Construction of eco-benign, cost effective, and high-performance supercapacitors with improved electrolytes and hierarchical porous electrodes is necessary for effective energy storage. In this study, a gel type organic redox electrolyte made of polyvinyl alcohol (PVA)-H2SO4 and an organic redox molecule, anthraquinone (PVA-H2SO4-AQ) was prepared by simple solution casting method, and was used to construct a symmetric supercapacitor (SSC) with a date stone-derived activated carbon (DSAC) having a high BET surface area (1612 m(2)/g). The DSAC was synthesized by simple carbonization method followed by activation with potassium hydroxide. The SSC exhibit a high specific capacitance of 126.5 F/g at 0.5 A/g, as well as a high energy density of 17.5 Wh/kg at a power density of 250 W/kg with high capacitance retention (87%) after 1000 GCD cycles. The present research suggests that adding anthraquinone to a PVA-H2SO4 gel electrolyte improves the performance of the fabricated device significantly as compared to using pristine PVA-H2SO4 or 1 M H2SO4 electrolytes. The research also presents a promising approach for the development of sustainable and eco-benign materials for energy storage applications. The use of date stone waste as a precursor material for activated carbon electrodes presents an opportunity for cost-effective and sustainable energy storage. Overall, the findings of this research have important implications for the future design and fabrication of high-performance and cost-effective supercapacitors.
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