期刊
ADVANCED OPTICAL MATERIALS
卷 11, 期 12, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adom.202300186
关键词
aggregation-caused quenching; aggregation-induced emission; aggregation-induced phosphorescence; room-temperature phosphorescence; thermally activated delayed fluorescence
In this study, two donor-acceptor-type TADF emitters with highly twisted conformation are synthesized. Through various experiments and analysis, it is discovered that X-aggregation supports aggregation-induced emission behavior, while H-aggregation leads to aggregation-caused quenching.
The understanding of the excited state dynamics of thermally activated delayed fluorescence (TADF) materials is crucial. In this study, two donor-acceptor-type TADF emitters with highly twisted conformation are synthesized. The emitters with subtle chemical modification of donor unit exhibit opposite aggregation luminescent behaviors: aggregation-induced emission (AIE) and aggregation-caused quenching (ACQ). Through the photophysical properties study, crystallographic analysis, and theory simulations, it is discovered that X-aggregation supports AIE behavior by restricting the intramolecular motions and preserving TADF emission via an efficient reverse intersystem crossing (RISC) process, but on the other hand, H-aggregation leads to ACQ behavior due to inhibited RISC, disabled TADF channel, and weak phosphorescence from radiative low-lying triplet state. The findings shed light on the excited-state dynamic behaviors of TADF emitters, which are dependent on aggregation.
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