期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 -, 期 -, 页码 -出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.2c06683
关键词
cellulose nanofibrils; crosslinking; packaging; gas barrier; UV-blocking
In this study, self-standing films of lignin-containing cellulose nanofibrils derived from recycled old corrugated cardboard (OCC) pulp were created. These films exhibited high gas barrier properties, complete UV-shielding ability, and reduced water vapor permeability compared to films made from bleached softwood Kraft (BSK) pulp. The addition of carboxymethyl cellulose improved the predictability of oxygen permeability values in the films. Crosslinking with trivalent aluminum ion or polyamide epichlorohydrin further decreased the oxygen permeability while enhancing the mechanical properties of the films.
Self-standing cellulose nanofibril (CNF) films are regarded as one of the promising alternatives to current petroleum-based packaging materials mostly due to their ability to form dense self-assembled structures exhibiting high gas barrier properties. Nonetheless, one of the major obstacles to the commercialization of these materials in packaging applications is the high cost of raw materials and production energy. In this study, we created self-standing films of lignin-containing cellulose nanofibrils (LCNFs) derived from a recycled old corrugated cardboard (OCC) pulp that costs less than bleached softwood Kraft (BSK) pulp and requires half as much energy for refining to obtain the same quality of material. The low zeta potential (-3.83 mV) of OCC-derived LCNFs (OCC-LCNFs) resulted in aggregation of the fibrils in aqueous suspension, leading to considerable unpredictability in oxygen permeability (OP) values (coefficient of variation 36%). The addition of 3 wt % (based on the dry weight of LCNFs) carboxymethyl cellulose lowered the coefficient of variation to 16% with an average OP of 1478 (cc.mu m/m2.atm.day) at 80% relative humidity. Because the OP was higher than that of the CNF film made from BSK-derived CNF (BSK-CNFs), we demonstrated that ionic crosslinking with trivalent aluminum ion or covalent crosslinking with polyamide epichlorohydrin decreased the OP by 30% at 23 degrees C and 80% relative humidity while also significantly enhancing the tensile strength and modulus. In addition, the presence of lignin in OCC resulted in a relatively lower water vapor permeability value in OCC-LCNF films compared to BSK-CNF films. Moreover, OCC-LCNF films showed complete UV-shielding (200-400 nm) property. Overall, this work provides a new opportunity to exploit a recycled and inexpensive source of CNFs to produce robust gas barrier materials for packaging applications.
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