4.6 Article

Recovery and Separation of Vanadium, Nickel, and Molybdenum from the Industrial Waste of a Petroleum Refinery by a Complexation Method

期刊

ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 11, 期 12, 页码 4894-4902

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.3c00388

关键词

separation; vanadium; molybdenum; nickel; complexation

向作者/读者索取更多资源

Based on the characteristics of complexation reactions, a novel method was proposed for the recovery and separation of vanadium (V), molybdenum (Mo), and nickel (Ni) from the roasting slag of carbon black byproduct. The method selectively leached V and Mo using oxalic acid as a complexing agent, followed by decomplexing and recycling of oxalic acid. Hexamethylenetetramine (HMT) was used to treat the solution containing V and Mo, resulting in the precipitation of Mo complexes. The precipitated Mo complexes were dissociated using calcium oxide, allowing for the separation and recovery of Mo and regeneration of HMT. This method provides an efficient and sustainable way to recover and separate V, Mo, and Ni from industrial waste.
Based on the characteristics of complexation reactions, a novel method for the recovery and separation of vanadium (V), molybdenum (Mo), and nickel (Ni) is proposed. This approach mainly utilizes oxalic acid and hexamethylenetetramine (HMT) as complexing agents to recover and separate V, Mo, and Ni from the roasting slag of the byproduct carbon black from petroleum refineries, which includes the above elements plus iron and calcium. According to the differences in the solubilities of the metallic oxalic acid complexes, V and Mo were selectively leached with efficiencies of 95.49% and 97.74%, respectively, while Ni, iron, and calcium remained in the residue. After decomplexing the V and Mo complexes in the leachate by adding sulfuric acid, the oxalic acid was recycled. Then, the solution containing V and Mo was treated with HMT, and 93.19% of the Mo was complexed and precipitated. Finally, the precipitated Mo complex was dissociated by the addition of calcium oxide to separate and recover Mo and HMT with a Mo recovery efficiency of 95.72%, and HMT was regenerated and used in the following cycles. As a result, the method proposed in this study is an efficient and sustainable way to recover and separate V, Mo, and Ni from the industrial waste of petroleum refineries.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据