Ruthenium-Catalyzed Transformation of Ethylene Glycol for Selective Hydrogen Gas Production in Water

Article Chemistry, Physical

Selective Hydrogen Production from Glycerol over Ruthenium Catalyst

Ankit Kumar et al.

Summary: This study demonstrates the efficient and selective production of hydrogen gas from glycerol using a ruthenium catalyst in water. High yields of hydrogen gas and lactic acid can be achieved under appropriate reaction conditions.

CHEMCATCHEM (2022)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Hydrogen Production from Formaldehyde and Paraformaldehyde in Water under Additive-Free Conditions: Catalytic Reactions and Mechanistic Insights

Soumyadip Patra et al.

Summary: Efficient catalytic systems based on arene-Ru(II) complexes with bis-imidazole methane-based ligands were developed for additive-free hydrogen generation from formaldehyde and paraformaldehyde in water. The presence of bis-imidazole methane ligands significantly affected the catalytic performance of the studied catalysts. Among the screened complexes, a complex with the ligand [(eta(6)-p-cymene)RuCl(L)]Cl-+(-) ([Ru]-2) showed the highest turnover number (>20,000) for hydrogen gas generation from paraformaldehyde in water.

INORGANIC CHEMISTRY (2022)

添加到收藏夹

Article Chemistry, Physical

Manganese-Catalyzed Reformation of Vicinal Glycols toα-HydroxyCarboxylic Acids with the Liberation of Hydrogen Gas

Satyadeep Waiba et al.

Summary: In this study, a sustainable catalytic pathway was developed to convert readily available feedstocks into valuable α-hydroxycarboxylic acid molecules. A bench stable metal complex was used as the catalyst, enabling the selective transformation of vicinal glycols into α-hydroxycarboxylic acids at low temperature. The protocol showed high efficiency and applicability for various types of vicinal glycols, with significant potential in the synthesis of bioactive molecules and biodegradable polymers.

ACS CATALYSIS (2022)

添加到收藏夹

Article Chemistry, Physical

Sustainable and selective hydrogen production by steam reforming of bio-based ethylene glycol: Design and development of Ni-Cu/mixed metal oxides using M (CeO2, La2O3, ZrO2)-MgO mixed oxides

Ashish D. Shejale et al.

Summary: Hydrogen production via renewable sources using ethylene glycol as a feedstock is of great interest. Mixed metal oxides supported Ni-Cu catalysts showed promising results for high purity H-2 production, with Ni-Cu/CeO2-MgO exhibiting the highest H-2 concentration and stability.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Homogeneous Reforming of Aqueous Ethylene Glycol to Glycolic Acid and Pure Hydrogen Catalyzed by Pincer-Ruthenium Complexes Capable of Metal-Ligand Cooperation

You-Quan Zou et al.

Summary: Ethylene glycol can be transformed into glycolic acid and pure hydrogen gas under homogeneous ruthenium catalysis, providing a clean and sustainable direction for production. This transformation, achieved with 0.5 mol% of catalyst, uses ethylene glycol as a renewable raw material.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Bis-Imidazole Methane Ligated Ruthenium(II) Complexes: Synthesis, Characterization, and Catalytic Activity for Hydrogen Production from Formic Acid in Water

Soumyadip Patra et al.

Summary: A series of half sandwich arene-ruthenium complexes containing bis-imidazole methane-based ligands were synthesized and tested for hydrogen production from formic acid in aqueous medium. Among the complexes investigated, Ru(II) coordinated with a 4-methoxyphenyl substituted bis-imidazole methane ligand exhibited the highest catalytic turnover and efficiency for formic acid dehydrogenation in water.

INORGANIC CHEMISTRY (2021)

添加到收藏夹

Article Energy & Fuels

Hydrogen Production via Aqueous-Phase Reforming of Ethylene Glycol over a Nickel-Iron Alloy Catalyst: Effect of Cobalt Addition

Junyu Tao et al.

ENERGY & FUELS (2020)

添加到收藏夹

Article Chemistry, Physical

Hydrogen Production from Ethylene Glycol Aqueous Phase Reforming over Ni-Al Layered Hydrotalcite-Derived Catalysts

Jianguang Zhang et al.

CATALYSTS (2020)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Hydrogen Production from Formic Acid and Formaldehyde over Ruthenium Catalysts in Water

Soumyadip Patra et al.

INORGANIC CHEMISTRY (2020)

添加到收藏夹

Review Chemistry, Physical

Catalytic Hydrogen Production from Methane: A Review on Recent Progress and Prospect

Luning Chen et al.

CATALYSTS (2020)

添加到收藏夹

Article Engineering, Chemical

Toward Selective Dehydrogenation of Glycerol to Lactic Acid over Bimetallic Pt-Co/CeOx Catalysts

Guangyu Zhang et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Oxidant-Free Transformation of Ethylene Glycol toward Glycolic Acid in Water

Yulu Zhan et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

添加到收藏夹

Review Chemistry, Physical

A Short Overview on the Hydrogen Production Via Aqueous Phase Reforming (APR) of Cellulose, C6-C5 Sugars and Polyols

Andrea Fasolini et al.

CATALYSTS (2019)

添加到收藏夹

Article Chemistry, Physical

Evaluation of a micro-channel reactor for steam reforming of ethylene glycol: A comparative study of catalytic activity of Pt or/and Ni supported gamma-alumina catalysts

Afshin Dehghani Kiadehi et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2018)

添加到收藏夹

Article Green & Sustainable Science & Technology

Renewable hydrogen production by ethylene glycol steam reforming over Al2O3 supported Ni-Pt bimetallic nano-catalysts

Afsanehsadat Larimi et al.

RENEWABLE ENERGY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Heterogeneous Catalytic Reactor for Hydrogen Production from Formic Acid and Its Use in Polymer Electrolyte Fuel Cells

Igor Yuranov et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2018)

添加到收藏夹

Article Chemistry, Physical

Hydrogen production via steam reforming of ethylene glycol over Attapulgite supported nickel catalysts

Yishuang Wang et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2018)

添加到收藏夹

Article Chemistry, Physical

Aqueous phase reforming of ethylene glycol over bimetallic platinum-cobalt on ceria-zirconia mixed oxide

Seongho Jeon et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2017)

添加到收藏夹

Article Multidisciplinary Sciences

Low-temperature hydrogen production from water and methanol using Pt/α-MoC catalysts

Lili Lin et al.

NATURE (2017)

添加到收藏夹

Article Multidisciplinary Sciences

Homogeneously catalysed conversion of aqueous formaldehyde to H2 and carbonate

M. Trincado et al.

NATURE COMMUNICATIONS (2017)

添加到收藏夹

Article Chemistry, Physical

Catalytic Hydrogenation of Arenes in Water Over InSitu Generated Ruthenium Nanoparticles Immobilized on Carbon

Ambikesh Dhar Dwivedi et al.

CHEMCATCHEM (2017)

添加到收藏夹

Article Chemistry, Physical

Steam Reforming of Ethylene Glycol over MgAl2O4 Supported Rh, Ni, and Co Catalysts

Donghai Mei et al.

ACS CATALYSIS (2016)

添加到收藏夹

Article Chemistry, Physical

Hydrogen production from ethylene glycol reforming catalyzed by Ni and Ni-Pt hydrotalcite-derived catalysts

Deborah V. Cesar et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2016)

添加到收藏夹

Article Chemistry, Physical

Ruthenium and Formic Acid Based Tandem Catalytic Transformation of Bioderived Furans to Levulinic Acid and Diketones in Water

Ambikesh D. Dwivedi et al.

CHEMCATCHEM (2015)

添加到收藏夹

Review Green & Sustainable Science & Technology

Hydrogen: A sustainable fuel for future of the transport sector

Sonal Singh et al.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2015)

添加到收藏夹

Article Chemistry, Physical

Resolving ruthenium: XPS studies of common ruthenium materials

David J. Morgan

SURFACE AND INTERFACE ANALYSIS (2015)

添加到收藏夹

Article Engineering, Chemical

On the Efficacy of Ru/Al2O3 Catalyst for Steam Reforming of Ethylene Glycol

Ravi Sundari et al.

CHEMICAL ENGINEERING COMMUNICATIONS (2015)

添加到收藏夹

Article Multidisciplinary Sciences

Selective and mild hydrogen production using water and formaldehyde

Leo E. Heim et al.

NATURE COMMUNICATIONS (2014)

添加到收藏夹

Review Chemistry, Physical

The hydrogen economy: Its history

John O'. M. Bockris

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2013)

添加到收藏夹

Article Multidisciplinary Sciences

Low-temperature aqueous-phase methanol dehydrogenation to hydrogen and carbon dioxide

Martin Nielsen et al.

NATURE (2013)

添加到收藏夹

Article Chemistry, Applied

Stability and activity of carbon nanofiber-supported catalysts in the aqueous phase reforming of ethylene glycol

T. van Haasterecht et al.

JOURNAL OF ENERGY CHEMISTRY (2013)

添加到收藏夹

Review Chemistry, Multidisciplinary

Ethylene glycol: properties, synthesis, and applications

Hairong Yue et al.

CHEMICAL SOCIETY REVIEWS (2012)

添加到收藏夹

Article Chemistry, Physical

Hydrogen production through the aqueous phase reforming of ethylene glycol over supported Pt-based bimetallic catalysts

Ho-Dong Kim et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2012)

添加到收藏夹

Article Chemistry, Multidisciplinary

Reversible hydrogen storage using CO2 and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures

Jonathan F. Hull et al.

NATURE CHEMISTRY (2012)

添加到收藏夹

Article Chemistry, Physical

Aqueous-phase reforming of ethylene glycol on Co/ZnO catalysts prepared by the coprecipitation method

Xianwen Chu et al.

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL (2011)

添加到收藏夹

Article Multidisciplinary Sciences

Efficient Dehydrogenation of Formic Acid Using an Iron Catalyst

Albert Boddien et al.

SCIENCE (2011)

添加到收藏夹

Review Chemistry, Physical

Potential importance of hydrogen as a future solution to environmental and transportation problems

Mustafa Balat

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2008)

添加到收藏夹

Article Chemistry, Physical

Techno-economic assessment of hydrogen production processes for the hydrogen economy for the short and medium term

F. Mueller-Langer et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2007)

添加到收藏夹

Review Chemistry, Multidisciplinary

Methanol steam reforming for hydrogen production

Daniel R. Palo et al.

CHEMICAL REVIEWS (2007)

添加到收藏夹

Article Chemistry, Physical

Transition to hydrogen economy in the United States: A 2006 status report

W. C. Lattin et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2007)

添加到收藏夹

Article Nuclear Science & Technology

H2-MHR pre-conceptual design summary for hydrogen production

Matt Richards et al.

NUCLEAR ENGINEERING AND TECHNOLOGY (2007)

添加到收藏夹

Review Green & Sustainable Science & Technology

On hydrogen and hydrogen energy strategies I: current status and needs

A Midilli et al.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2005)

添加到收藏夹

Article Engineering, Chemical

Depolymerization mechanism of poly(ethylene terephthalate) in supercritical methanol

M Genta et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2005)

添加到收藏夹

Article Engineering, Chemical

Kinetic analysis of the hydrogenolysis of lower polyhydric alcohols: Glycerol to glycols

DG Lahr et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2003)

添加到收藏夹

Article Multidisciplinary Sciences

Raney Ni-Sn catalyst for H2 production from biomass-derived hydrocarbons

GW Huber et al.

SCIENCE (2003)

添加到收藏夹

Article Chemistry, Physical

Aqueous-phase reforming of ethylene glycol on silica-supported metal catalysts

RR Davda et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2003)

添加到收藏夹

Article Chemistry, Physical

The hydrogen economy in the 21st century: a sustainable development scenario

L Barreto et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2003)

添加到收藏夹

Article Multidisciplinary Sciences

Hydrogen from catalytic reforming of biomass-derived hydrocarbons in liquid water

RD Cortright et al.

NATURE (2002)

添加到收藏夹

Ruthenium-Catalyzed Transformation of Ethylene Glycol for Selective Hydrogen Gas Production in Water

相关参考文献

导出引文

分享论文