4.4 Article

Effects of additives on the mechanical and thermal properties of epoxy-based nanocomposites produced using sonication

期刊

KOREAN JOURNAL OF CHEMICAL ENGINEERING
卷 33, 期 6, 页码 1938-1941

出版社

KOREAN INSTITUTE CHEMICAL ENGINEERS
DOI: 10.1007/s11814-016-0034-5

关键词

Epoxy; Hydroxyapatite; Montmorillonite; Tellurium Dioxide; Nanocomposite

资金

  1. National Research Foundation of Korea (NRF) - Ministry of Education, Science and Technology [NRF-2015R1D1A1A01056570]

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Epoxy nanocomposites were synthesized in the presence of hydroxyapatite with the aid of an ultrasonicator. In general, as the amount of hydroxyapatite increased from 0wt% to 10wt%, the mechanical properties of the hydroxyapatite-containing nanocomposite were enhanced. The mechanical properties of the nanocomposite were significantly enhanced by the simple addition of 10 wt% of hydroxyapatite. Specifically, the storage modulus of the 10 wt% hydroxyapatite-containing nanocompsote was 3.2GPa, which is 46% higher compared to that of the pristine epoxy nanocomposite. The glass transition temperature of hydroxyapatite-containing nanocomposites generally decreased by few degrees in Celsius. To investigate the effect of additives on the mechanical properties of the epoxy-based nanocomposite, nanocomposites were synthesized using both montmorillonite and tellurium dioxide instead of hydroxyapatite. Intrestingly, both additive-based nanocomposite materials resulted in an increase in the storage modulus while the glass transition temperature decreased. These results demonstrate that the addition of few wt% of all three additives (hydroxyapatite, montmorillonite, and tellurium dioxide) can enhance the mechanical properties of epoxy-based nanocomposites.

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