Protection of Patinated Bronze with Long-Chain Phosphonic Acid/Organic Coating Combined System

Bronze cultural heritage in urban areas is susceptible to decay due to the significant amount of pollutants present in the air. This causes the dissolution of bronze and the patina on its surface. The efficient protection of outdoor bronze cultural heritage is still an unresolved problem. The aim of this work is to investigate 16-phosphonohexadecanoic acid as an environmentally friendly and non-toxic corrosion inhibitor for patinated bronze. The corrosion protection of sulphide-patinated bronze by phosphonic acid alone and in combination with acrylic coating Paraloid B-72 is examined. In order to achieve efficient corrosion protection, various parameters of the phosphonic acid application were studied. The efficiency of protection is examined by electrochemical impedance spectroscopy (EIS) during the immersion in simulated acid rain solution and after exposure to a corrosion chamber. It was found that the studied phosphonic acid provides corrosion protection to patinated bronze and significantly improves the protective properties of Paraloid B72. This was also confirmed by scanning electron microscopy (SEM) examination of the coating surface after exposure to a corrosive environment.

Automated summary

Bronze cultural heritage in urban areas is susceptible to decay due to pollution. This study examines the corrosion protection of patinated bronze using phosphonic acid and Paraloid B-72 coating. The efficiency of corrosion protection is studied using electrochemical impedance spectroscopy and scanning electron microscopy. The results show that phosphonic acid provides corrosion protection and improves the properties of Paraloid B-72.