Ascorbic acid supported Carboxymethyl cellulose stabilized silver nanoparticles as optical nanoprobe for Au3+detection in environmental sample

Heavy metals (HMs), pollution of major environmental matrices and its attendant effects on human health and the environment, continue to generate huge scientific interest, particularly in mon-itoring and detection. Herein, the optical property of carboxymethyl cellulose stabilized silver nanopar-ticles (CMC-AgNPs), supported with ascorbic acid, is exploited as a colorimetric probe for the detection of toxic Au3+ ion in solution. The as-synthesized CMC-AgNPs showed sharp absorption maximum at 403 nm, with sparkling yellow color and average particles size distribution less than 10 nm. It was further characterized using ATR-FTIR, TEM, FESEM/EDS, XRD and DLS/zeta potential analyzer. Au3+ ion detection strategy involves the addition of ascorbic acid (AA) to a pH adjusted CMC-AgNPs, followed by the analyte addition. AA would facilitate the reduction of Au3+ on CMC-AgNPs (seed), with resultant color perturbations from light yellow to yellow, orange, ruby red and purple red, under 8 min incubation, at room temperature (RT). The CMC-AgNPs could also serve as a catalyst, by promoting AA mediated reduction of Au3+, in-situ. Moreover, we propose, that the color and the absorption spectra change is attributed to the deposition of gold nanoparticles (AuNPs), on the CMC-AgNPs/AA probe, to form (CMC-Ag@Au) nanostructures, depending on the analyte concentration. Absorbance ratio (A540/A403) showed good linearity with Au3+ concentra-tion from 0.25 to 100.0 mM, and an estimated LOD of 0.061 mM. The assay was applied to Au3+ detec-tion in environmental wastewater sample, showing satisfactory real sample detection potentiality.(c) 2023 The Author(s). Published by Elsevier B.V. on behalf of King Saud University. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

Automated summary

This study utilizes the optical property of carboxymethyl cellulose stabilized silver nanoparticles (CMC-AgNPs) as a colorimetric probe for the detection of toxic Au3+ ions in solution. The synthesized CMC-AgNPs exhibit sharp absorption at 403 nm, with an average particle size of less than 10 nm. By combining CMC-AgNPs with ascorbic acid (AA) and adding Au3+ ions, the color of the solution changes from light yellow to yellow, orange, ruby red, and purple red within 8 minutes at room temperature. The color and absorption spectra change is attributed to the formation of (CMC-Ag@Au) nanostructures.