☆ 4.8 Review

Homogeneous Catalysis for the Conversion of CO2, CO, CH3OH, and CH4 to C2+Chemicals via C-C Bond Formation

ACS CATALYSIS (2023)

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Summary: The conversion of CO2 into multicarbon compounds offers the possibility to create carbon-neutral fuels or other valuable products. So far, most studies have focused on heterogeneous metallic catalysts, but the potential of molecular catalysts is still underexplored. This Minireview summarizes recent progress in the thermo- and electrochemical reductive homocoupling of CO2 mediated by molecular catalysts and discusses the use of CO homocoupling as a model for further conversion of intermediates obtained from CO2 reduction.

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The oxidative addition and migratory 1,1-insertion in the Monsanto and Cativa processes. A density functional study of the catalytic carbonylation of methanol

T Kinnunen et al.

JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM (2001)

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Article Chemistry, Inorganic & Nuclear

Reaction mechanism of the reductive elimination in the catalytic carbonylation of methanol. A density functional study

T Kinnunen et al.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2001)

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Article Chemistry, Multidisciplinary

Macrocyclic [N42-] coordinated nickel complexes as catalysts for the formation of oxalate by electrochemical reduction of carbon dioxide

M Rudolph et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)

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Article Chemistry, Multidisciplinary

Novel bimetallic group 9 metal catalysts containing P,S-chelating o-carboranyl ligand system for the carbonylation of methanol

HS Lee et al.

CHEMISTRY LETTERS (2000)

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Article Chemistry, Applied

High productivity methanol carbonylation catalysis using iridium -: The Cativa™ process for the manufacture of acetic acid

GJ Sunley et al.

CATALYSIS TODAY (2000)

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Article Chemistry, Analytical

Electrocarboxylation of arylmethyl chlorides catalyzed by cobalt 6,6′-bis(2-hydroxyphenyl)-2,2′-bipyridine

WH Chung et al.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2000)

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Article Chemistry, Inorganic & Nuclear

Density functional study of the migratory insertion step in the carbonylation of methanol catalyzed by [M(CO)2I2]- (M = Rh, Ir)

M Cheong et al.

ORGANOMETALLICS (2000)

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Article Chemistry, Multidisciplinary

Rhodium(I) complexes of unsymmetrical diphosphines: efficient and stable methanol carbonylation catalysts

CA Carraz et al.

CHEMICAL COMMUNICATIONS (2000)

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