4.7 Article

The role of additives in improving the flammability and calorific value of leather shavings and the binding of chromium compounds in ash

期刊

WASTE MANAGEMENT
卷 163, 期 -, 页码 52-60

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.wasman.2023.03.033

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Renewable energy; Biomass; Waste leather; Combustion process; Pellets; Solid fuel

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Leather processing companies are facing the challenge of increasing costs for post-production waste disposal. To address this, thermal waste disposal at the plant and utilization of generated heat in the production process are gaining popularity. Research shows that by adding a small amount of wood sawdust to leather waste, its flammability can be improved, enabling stable combustion and avoiding the formation of sinters. Furthermore, leather waste can be an attractive and safe source of energy for companies, contributing to improved waste management in a circular economy.
Leather processing companies are struggling with the problem of increasing costs of post-production waste disposal. Therefore, the issue of thermal waste disposal at the plant and the use of generated heat in the pro-duction process is becoming more and more popular. Leather waste on its own does not allow for autothermal combustion despite the sufficient higher heating value (HHV). Therefore the Authors proposed to improve the flammability of the fuel by adding a small amount of wood sawdust to leather waste and produce premixed pellets. Six such samples were incinerated in a laboratory-scale reactor, which enables the simultaneous mea-surement of characteristic temperatures, exhaust gas analysis and sample mass loss rate. Research has shown that even a small addition of sawdust enables a stable combustion process and does not cause the formation of sinters. In addition, studies of the ash showed that in the case of chromium-containing waste, a large part of it remained in the ash in the form of Cr2O3. Nevertheless, very fine ash causes the small fraction chromium to be carried with the flue gas stream, therefore controlled agglomeration of the ash structure would be advisable in the final installation. Emission analysis showed high and moderately high NOx and SO2 emissions, decreasing with the increase in the amount of sawdust addition in the sample. Research has shown that leather waste is not a burden, but can be an attractive and safe source of energy for the company, while improving waste management in a circular economy.

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