Self-regenerative superhydrophobic metallic coatings with enhanced durability

Lotus-inspired superhydrophobic surfaces are highly sought owing to exquisite properties such as de-wetting, self-cleaning, anti-corrosion, anti-fouling. However, their use is limited due to low durability, high processing cost, and scalability issues. In the present work, we used low cost and simple flame spraying for developing self -regenerative superhydrophobic metallic coatings with high durability and corrosion resistance. The aluminum coatings were developed on low-carbon steel at optimized parameters, followed by annealing at different tem-peratures. The developed coating showed hierarchical structure with nanoscale features superimposed on microscale lamellae. The nano-sponge like morphology obtained through flame spraying after annealing trans-formed into nano-spheroid with reduced microscale porosity. The fabricated aluminum coatings inherently exhibited superhydrophilicity, which transformed to superhydrophobicity after silanization. The coatings exhibited advancing angles >150 degrees and receding angles >148 degrees with a 5 degrees sliding angle. The change in morphology with annealing showed a significant influence on wettability, adhesion, and electrochemical corrosion. The contact angles decreased slightly with annealing temperature while still in the superhydrophobic regime. The adhesion of the coatings with the water droplet increased from similar to 2 mu N to 7.3 mu N with the increase in annealing temperatures while still being less than that of the lotus leaf (18 mu N). The electrochemical corrosion resistance of the coatings showed significant improvement after annealing, which is related to the change in microporosity and formation of stable oxides as verified by x-ray photoelectron spectroscopy (XPS). The current density decreased from 0.48 mu A/cm(2) to 0.06 mu A/cm(2) due to stable passive layer formation. The coatings showed increased durability against abrasion, and impacting droplets due to improved inter-lamellar cohesion and increased adhesion with the substrate. The present work provide a low cost and facile solution for the devel-opment of superhydrophobic coatings for various applications.

Automated summary

In this study, self-regenerative superhydrophobic metallic coatings with high durability and corrosion resistance were developed using low-cost and simple flame spraying. The coatings exhibited a hierarchical structure with nanoscale features on microscale lamellae. The morphology transformed from a nano-sponge to a nano-spheroid after annealing, resulting in improved superhydrophobicity. The coatings showed increased durability, adhesion, and electrochemical corrosion resistance.