4.5 Article

Preparation, crystal structure and Li ion conductivity of Li10.8Ba1.85Al3.5O12F

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SOLID STATE IONICS
卷 394, 期 -, 页码 -

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ELSEVIER
DOI: 10.1016/j.ssi.2023.116208

关键词

Lithium barium aluminum oxide fluoride; Solid state reaction synthesis; Single crystal X-ray diffraction; Crystal structure; Lithium ion conduction

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Polycrystalline ceramics of the compound Li10.8Ba1.85Al3.5O12F were synthesized by heating a mixture of Li2O, BaO, Al2O3, and LiF at 1023 K. Single crystals of this compound were obtained through a melt-solidification process. The compound exhibited a trigonal crystal structure with Li split sites and showed good stability in contact with Li metal.
Polycrystalline ceramics comprising the newly discovered compound Li10.8Ba1.85Al3.5O12F were synthesized by heating a compacted mixture of Li2O, BaO and Al2O3 together with LiF as a fluorine source at 1023 K for 6 h in an Ar atmosphere. Single crystals of this oxide were subsequently obtained from a melt-solidified sample prepared by heating and slow cooling of the compact from 1133 K. Single-crystal X-ray diffraction established that this compound had a trigonal crystal structure (a = 6.03346(10) angstrom, c =10.13780(17) angstrom, space group P-3) containing Li split sites around the (001) plane at z = 0 with approximately 1/3 occupancy and large anisotropic atomic displacement parameters. The Li ion conductivities for the samples prepared by reaction sintering at 1023 K (relative density 55%) and by sintering of a powder compact at 1123 K (relative density 87%) were determined to be 1.6(3) x 10-8 and 2.8(2) x 10-8 S center dot cm- 1 at 305 K and 3.9(2) x 10-6 and 1.0(2) x 10-5 S center dot cm- 1 at 423 K, respectively, while the activation energies for conduction of the samples was found to be 0.52(2) and 0.55(3) eV, respectively. Cyclic voltammetry data acquired using Li and Ta electrodes indicated that this compound was stable in contact with Li metal and demonstrated a Li ion transport number >99%.

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